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203
textfiles.com/science/CHEMICALS/ammonium_dichromate.txt
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203
textfiles.com/science/CHEMICALS/ammonium_dichromate.txt
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|
||||
|
||||
MSDS - AMMONIUM DICHROMATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: AMMONIUM DICHROMATE
|
||||
FORMULA: (NH4)2CR2O7
|
||||
FORMULA WT: 252.06
|
||||
CAS NO.: 07789-09-5
|
||||
NIOSH/RTECS NO.: HX7650000
|
||||
COMMON SYNONYMS: DICHROMIC ACID, DIAMMONIUM SALT; AMMONIUM BICHROMATE
|
||||
PRODUCT CODES: 0688,0690
|
||||
EFFECTIVE: 08/15/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 4 EXTREME (CANCER CAUSING)
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 3 SEVERE (OXIDIZER)
|
||||
CONTACT - 3 SEVERE (CORROSIVE)
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DANGER
|
||||
HARMFUL IF INHALED
|
||||
MAY CAUSE BURNS OR EXTERNAL ULCERS
|
||||
CAUTION: CONTAINS CHROMIUM(VI),CANCER HAZARD
|
||||
STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
USE IN CLOSED REACTION VESSELS REQUIRES STRINGENT PRECAUTIONS BECAUSE
|
||||
OF EXPLOSION HAZARD.
|
||||
KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. DO NOT
|
||||
STORE NEAR COMBUSTIBLE MATERIALS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE WATER SPRAY,
|
||||
ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH SPILL AREA WITH WATER
|
||||
SPRAY.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
AMMONIUM DICHROMATE 90-100 7789-09-5
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 170 C ( 338 F) VAPOR DENSITY(AIR=1): 8.7
|
||||
|
||||
SPECIFIC GRAVITY: 2.15 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: BRIGHT, ORANGE-RED ODORLESS CRYSTALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 1-1-1 OXY
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
IN CASES OF EXCESSIVE HEAT OR CONDITIONS OF CONFINEMENT AN EXTREME
|
||||
HAZARD EXISTS RESULTING IN POSSIBLE SPONTANEOUS VIOLENT THERMAL
|
||||
DECOMPOSITION.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
NITROGEN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.05 MG/M3 ( PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 0.5 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: YES IARC: YES Z LIST: YES OSHA REG: YES
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS.
|
||||
EXCESSIVE INHALATION OF DUST IS IRRITATING AND MAY BE SEVERELY DAMAGING
|
||||
TO RESPIRATORY PASSAGES AND/OR LUNGS.
|
||||
INGESTION MAY BE HARMFUL TO THE KIDNEYS, LIVER, AND GASTRO-INTESTINAL
|
||||
TRACT.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS, COMBUSTIBLE MATERIALS
|
||||
|
||||
DECOMPOSITION PRODUCTS: AMMONIA
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D002, D003 (CORROSIVE, REACTIVE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: A RESPIRATOR WITH DUST/MIST FILTER IS RECOMMENDED.
|
||||
IF AIRBORNE CONCENTRATION EXCEEDS CAPACITY OF
|
||||
RESPIRATOR, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
|
||||
AND COMBUSTIBLE MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME AMMONIUM DICHROMATE
|
||||
HAZARD CLASS OXIDIZER
|
||||
UN/NA UN1439
|
||||
LABELS OXIDIZER
|
||||
REPORTABLE QUANTITY 1000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME AMMONIUM DICHROMATE
|
||||
HAZARD CLASS 5.1
|
||||
UN/NA UN1439
|
||||
LABELS OXIDIZING AGENT
|
||||
|
||||
195
textfiles.com/science/CHEMICALS/ammonium_nitrate.txt
Normal file
195
textfiles.com/science/CHEMICALS/ammonium_nitrate.txt
Normal file
@@ -0,0 +1,195 @@
|
||||
|
||||
MSDS - AMMONIUM NITRATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: AMMONIUM NITRATE
|
||||
FORMULA: NH4NO3
|
||||
FORMULA WT: 80.04
|
||||
CAS NO.: 06484-52-2
|
||||
NIOSH/RTECS NO.: BR9050000
|
||||
COMMON SYNONYMS: AMMONIUM(I)NITRATE; NITRIC ACID, AMMONIUM SALT
|
||||
PRODUCT CODES: 0729,0731
|
||||
EFFECTIVE: 10/09/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 3 SEVERE (OXIDIZER)
|
||||
CONTACT - 2 MODERATE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DANGER
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF SWALLOWED
|
||||
STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE
|
||||
KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. DO NOT
|
||||
STORE NEAR COMBUSTIBLE MATERIALS. AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING. IN CASE
|
||||
OF FIRE, SOAK WITH WATER. IN CASE OF SPILL, SWEEP UP AND REMOVE. FLUSH SPILL
|
||||
AREA WITH WATER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
AMMONIUM NITRATE 90-100 6484-52-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 210 C ( 410 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 170 C ( 338 F) VAPOR DENSITY(AIR=1): 2.8
|
||||
|
||||
SPECIFIC GRAVITY: 1.73 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: ODORLESS, TRANSPARENT CRYSTALS OR WHITE GRANULES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 0-0-3 OXY
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
NOTE: DECOMPOSES AT BOILING POINT.
|
||||
STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
AMMONIA, NITROGEN OXIDES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST INHALATION MAY CAUSE TIGHTNESS AND PAIN IN CHEST, COUGHING, AND
|
||||
DIFFICULTY IN BREATHING.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING, GASTROINTESTINAL
|
||||
IRRITATION, UNCONSCIOUSNESS, CONVULSIONS.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, SHOCK, FLAME
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS, COMBUSTIBLE MATERIALS,
|
||||
STRONG ACIDS, ORGANIC MATERIALS,
|
||||
CHEMICALLY ACTIVE METALS
|
||||
|
||||
DECOMPOSITION PRODUCTS: AMMONIA, OXIDES OF NITROGEN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, UNIFORM, BUTYL
|
||||
RUBBER GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
|
||||
AND COMBUSTIBLE MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME AMMONIUM NITRATE, NO ORGANIC COATING
|
||||
HAZARD CLASS OXIDIZER
|
||||
UN/NA UN1942
|
||||
LABELS OXIDIZER
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME AMMONIUM NITRATE FERTILIZERS, N.O.S. (AMMONIUM NITRATE)
|
||||
HAZARD CLASS 5.1
|
||||
UN/NA UN1942
|
||||
LABELS OXIDIZING AGENT
|
||||
|
||||
151
textfiles.com/science/CHEMICALS/ammonium_oxalate.txt
Normal file
151
textfiles.com/science/CHEMICALS/ammonium_oxalate.txt
Normal file
@@ -0,0 +1,151 @@
|
||||
|
||||
MSDS - Ammonium Oxalate Monohydrate
|
||||
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: WHITE CRYSTALS OR GRANULES. ODORLESS.
|
||||
Boiling Point: N/A
|
||||
Melting Point: 158F,70C
|
||||
Vapor Pressure (MM Hg/70 F): N/A
|
||||
Vapor Density (Air=1): N/A
|
||||
Specific Gravity: 1.50
|
||||
Evaporation Rate And Ref: N/A
|
||||
Solubility In Water: APPRECIABLE (>10%)
|
||||
Percent Volatiles By Volume: 0
|
||||
pH: 6.4
|
||||
Magnetism (Milligauss): N/P
|
||||
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: N/A
|
||||
Flash Point Method: N/P
|
||||
Lower Explosive Limit: N/A
|
||||
Upper Explosive Limit: N/A
|
||||
Extinguishing Media: USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
|
||||
FIRE.
|
||||
Special Fire Fighting Proc: FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE
|
||||
EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
|
||||
OPERATED IN POSITIVE PRESSURE MODE.
|
||||
Unusual Fire And Expl Hazrds: NONE
|
||||
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): NONE DOCUMENTED
|
||||
Materials To Avoid: STRONG ACIDS.
|
||||
Hazardous Decomp Products: AMMONIA, CARBON MONOXIDE, CARBON DIOXIDE.
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): NOT APPLICABLE
|
||||
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: UNKNOWN
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: YES
|
||||
Route Of Entry - Ingestion: YES
|
||||
Health Haz Acute And Chronic: INHALATION: IRRITATION OF UPPER RESPIRATORY
|
||||
TRACT. SKIN: SEVERE IRRITATION OR BURNS. EYES: SEVERE IRRITATION OR BURNS.
|
||||
INGESTION: HARMFUL AND MAY BE FATAL.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NOT APPLICABLE
|
||||
Signs/Symptoms Of Overexp: BURNS OF THE SKIN AND EYES. NAUSEA, VOMITING,
|
||||
GASTROINTESTINAL IRRITATION, BURNS TO THE MOUTH AND THROAT UPON INGESTION.
|
||||
Med Cond Aggravated By Exp: NONE IDENTIFIED
|
||||
Emergency/First Aid Proc: INGESTION: CALL A PHYSICIAN. DO NOT INDUCE
|
||||
VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INHALATION: REMOVE TO
|
||||
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. SKIN: IMMEDIATELY
|
||||
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
|
||||
CONTAMINATED CLOTHING AND SHOES. EYES: IMMEDIATELY FLUSH WITH PLENTY OF
|
||||
WATER FOR AT LEAST 15 MINUTES.
|
||||
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: WEAR SELF-CONTAINED BREATHING APPARATUS AND
|
||||
FULL PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO
|
||||
CLEAN, DRY CONTAINER AND COVER; REMOVE REOM AREA. FLUSH SPILL AREA WITH
|
||||
WATER.
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
|
||||
STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
|
||||
Precautions-Handling/Storing: KEEP CONTAINER TIGHTLY CLOSED. STORE IN
|
||||
CORROSION-PROOF AREA.
|
||||
Other Precautions: NONE
|
||||
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST.
|
||||
Ventilation: NORMAL MECHANICAL VENTILATION.
|
||||
Protective Gloves: RUBBER GLOVES.
|
||||
Eye Protection: SAFETY GOGGLES.
|
||||
Other Protective Equipment: UNIFORM OR APRON.
|
||||
Work Hygienic Practices: WASH HANDS AFTER HANDLING THIS MATERIAL.
|
||||
Suppl. Safety & Health Data: NONE
|
||||
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 91311
|
||||
DOT PSN Code: LCW
|
||||
DOT Proper Shipping Name: OXALATES
|
||||
DOT Class: 6.1
|
||||
DOT ID Number: UN2449
|
||||
DOT Pack Group: III
|
||||
DOT Label: KEEP AWAY FROM FOOD
|
||||
IMO PSN Code: LBF
|
||||
IMO Proper Shipping Name: OXALATES
|
||||
IMO Regulations Page Number: 6216
|
||||
IMO UN Number: 2449
|
||||
IMO UN Class: 6.1
|
||||
IMO Subsidiary Risk Label: -
|
||||
IATA PSN Code: UKJ
|
||||
IATA UN ID Number: 2811
|
||||
IATA Proper Shipping Name: POISONOUS SOLID, N.O.S.
|
||||
IATA UN Class: 6.1
|
||||
IATA Label: KEEP AWAY FROM FOOD
|
||||
AFI PSN Code: UKJ
|
||||
AFI Prop. Shipping Name: POISONOUS SOLIDS, N.O.S.
|
||||
AFI Class: 6.1
|
||||
AFI ID Number: UN2811
|
||||
AFI Pack Group: III
|
||||
AFI Label: KEEP AWAY FROM FOOD
|
||||
AFI Basic Pac Ref: 10-13
|
||||
Additional Trans Data: NONE
|
||||
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 07NOV91
|
||||
Label Date: 07NOV91
|
||||
Label Status: M
|
||||
Common Name: AMMONIUM OXALATE
|
||||
Chronic Hazard: NO
|
||||
Signal Word: DANGER!
|
||||
Acute Health Hazard-Severe: X
|
||||
Contact Hazard-Severe: X
|
||||
Fire Hazard-None: X
|
||||
Reactivity Hazard-Slight: X
|
||||
Special Hazard Precautions: INHALATION: IRRITATION OF UPPER RESPIRATORY
|
||||
TRACT. SKIN: SEVERE IRRITATION OR BURNS. EYES: SEVERE IRRITATION OR BURNS.
|
||||
INGESTION: HARMFUL AND MAY BE FATAL. KEEP CONTAINER TIGHTLY CLOSED. STORE
|
||||
IN CORROSION-PROOF AREA. FIRST AID: INGESTION: CALL A PHYSICIAN. DO NOT
|
||||
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
|
||||
REMOVING CONTAMINATED CLOTHING AND SHOES. EYES: IMMEDIATELY FLUSH WITH
|
||||
PLENTY OF WATER FOR AT LEAST 15 MINUTES.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
165
textfiles.com/science/CHEMICALS/ammonium_perchlorate.txt
Normal file
165
textfiles.com/science/CHEMICALS/ammonium_perchlorate.txt
Normal file
@@ -0,0 +1,165 @@
|
||||
|
||||
MSDS - AMMONIUM PERCHLORATE
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: AMMONIUM PERCHLORATE
|
||||
Ingredient Sequence Number: 01
|
||||
Percent: 99.5MIN
|
||||
NIOSH (RTECS) Number: SC7520000
|
||||
CAS Number: 7790-98-9
|
||||
OSHA PEL: NOT ESTABLISHED
|
||||
ACGIH TLV: NOT ESTABLISHED
|
||||
Other Recommended Limit: 5MG/CUM,AS RESP DUST
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: ODORLESS WHITE GRANULAR CRYSTALS.
|
||||
Melting Point: 842F/450C
|
||||
Specific Gravity: 1.95
|
||||
Decomposition Temperature: >150F,>66C
|
||||
Solubility In Water: APPRECIABLE
|
||||
Magnetism (Milligauss): N/P
|
||||
Corrosion Rate (IPY): UNKNOWN
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point Method: N/P
|
||||
Extinguishing Media: WATER SPRAY, FOAM.
|
||||
Special Fire Fighting Proc: USE NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED
|
||||
AREA.
|
||||
Unusual Fire And Expl Hazrds: COOL W/WATER FOR LARGE FIRE IN STORAGE AREA,
|
||||
USE UNMANNED HOSE HOLDER OR WITHDRAW & LET BURN! SEE SUP
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: NO
|
||||
Cond To Avoid (Stability): STABLE BELOW 150 F.DECOMP OR EXPLODES AT HIGHER
|
||||
TEMP.
|
||||
Materials To Avoid: COMBUSTIBLES,OXIDIZERS CREATE EXTREME FIRE/EXPL
|
||||
HAZARD.
|
||||
Hazardous Decomp Products: VAPORS OF CHLORINE,HYDROGEN CHLORIDES,
|
||||
AMMONIA,OXIDES OF NITROGEN.
|
||||
Hazardous Poly Occur: NO
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: 4200 MG/KG(RAT) & 1900MG/KG (RABBIT)
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: YES
|
||||
Route Of Entry - Ingestion: YES
|
||||
Health Haz Acute And Chronic: ACUTE:MILD IRRITANT TO THE SKIN,EYES,MUCOUS
|
||||
MEMBRANES,RESPIRATORY OR G.I. TRACT,REDNESS OF EYES AND SKIN. CHRONIC:SKIN,
|
||||
G.I. OR RESPIRATORY DISORDERS.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: PER MSDS DATA.
|
||||
Signs/Symptoms Of Overexp: EYE:IRRT,REDNESS.SKIN:IRRT,REDNESS.INHL:URT
|
||||
IRRT.INGEST: GI TRACT IRRT,DIARR.
|
||||
Med Cond Aggravated By Exp: PRE-EXISTING CONDITIONS MAY BE WORSEN.
|
||||
Emergency/First Aid Proc: INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR;
|
||||
IF BRTHNG DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN: WASH
|
||||
W/SOAP&WATER. RMV CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT UNTIL VOMIT
|
||||
IS CLEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: SCOOP UP OR ABSORB WITH NONCOMBUSTIBLE
|
||||
ABSORBENT(VERMICULITE).
|
||||
Waste Disposal Method: EPA HAZWASTE D001. DISPOSE AS HAZWASTE IAW ALL LAWS
|
||||
& REGS.
|
||||
Precautions-Handling/Storing: DO NOT ALLOW CONTACT W/COMBUSTIBLE
|
||||
MATERIALS.STORE IN ORIGINAL CLOSED CONTAINERS.HANDLE CONTAINERS CAREFULLY.
|
||||
AVOID INHL DUST & EYE/SKN CONTACT.
|
||||
Other Precautions: PROVIDE WATER FILLED JUMP TANK OR SAFETY SHOWER.WASH
|
||||
CONTAM CLOTHING PROMPTLY
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR FOR DUST IF
|
||||
ABOVE PEL/TLV.
|
||||
Ventilation: LOCAL OR GENERAL AS REQD.
|
||||
Protective Gloves: IMPERVIOUS
|
||||
Eye Protection: SAFETY GLASSES OR GOGGLES
|
||||
Other Protective Equipment: WEAR PROTECTIVE CLOTHING, RUBBER BOOTS. DO NOT
|
||||
WEAR LEATHER.
|
||||
Work Hygienic Practices: AVOID CONTACT WITH EYES AND SKIN;DO NOT BREATHE
|
||||
DUST/MIST;KEEP FROM CONTACT WITH CLOTHING & OTHER COMBUSTIBLE MATERIAL.
|
||||
Suppl. Safety & Health Data: .
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 87075
|
||||
DOT PSN Code: ASD
|
||||
DOT Proper Shipping Name: AMMONIUM PERCHLORATE
|
||||
DOT Class: 5.1
|
||||
DOT ID Number: UN1442
|
||||
DOT Pack Group: II
|
||||
DOT Label: OXIDIZER
|
||||
IMO PSN Code: AZZ
|
||||
IMO Proper Shipping Name: AMMONIUM PERCHLORATE
|
||||
IMO Regulations Page Number: 5126
|
||||
IMO UN Number: 1442
|
||||
IMO UN Class: 5.1
|
||||
IMO Subsidiary Risk Label: -
|
||||
IATA PSN Code: BQC
|
||||
IATA UN ID Number: 1442
|
||||
IATA Proper Shipping Name: AMMONIUM PERCHLORATE
|
||||
IATA UN Class: 5.1
|
||||
IATA Label: OXIDIZER
|
||||
AFI PSN Code: BQC
|
||||
AFI Prop. Shipping Name: AMMONIUM PERCHLORATE
|
||||
AFI Class: 5.1
|
||||
AFI ID Number: UN1442
|
||||
AFI Pack Group: II
|
||||
AFI Label: OXIDIZER
|
||||
AFI Special Prov: A9
|
||||
AFI Basic Pac Ref: 9-10
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
Disposal Data Review Date: 88229
|
||||
Rec # For This Disp Entry: 01
|
||||
Tot Disp Entries Per NSN: 002
|
||||
Landfill Ban Item: YES
|
||||
Disposal Supplemental Data: MSDS DTD JUN85.FIRE(CONT):EVACUATE AREA,DENY
|
||||
ENTRY.USE SCBA PP MODE, FULL PROTECTIVE CLOTHING. IN CASE OF ACCIDENTAL
|
||||
EXPOSURE OR DISCHARGE, CONSULT HEALTH AND SAFETY FILE FOR PRECAUTIONS.
|
||||
1st EPA Haz Wst Code New: D001
|
||||
1st EPA Haz Wst Name New: IGNITIBLE
|
||||
1st EPA Haz Wst Char New: IGNITABILITY
|
||||
1st EPA Acute Hazard New: NO
|
||||
2nd EPA Haz Wst Code New: D003
|
||||
2nd EPA Haz Wst Name New: REACTIVE
|
||||
2nd EPA Haz Wst Char New: REACTIVITY
|
||||
2nd EPA Acute Hazard New: NO
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 10JAN91
|
||||
Label Date: 01JUN85
|
||||
MFR Label Number: UNKNOWN
|
||||
Label Status: M
|
||||
Common Name: AMMONIUM PERCHLORATE
|
||||
Chronic Hazard: YES
|
||||
Signal Word: DANGER!
|
||||
Acute Health Hazard-Slight: X
|
||||
Contact Hazard-Slight: X
|
||||
Fire Hazard-None: X
|
||||
Reactivity Hazard-Severe: X
|
||||
Special Hazard Precautions: ACUTE-MINOR IRRITANT TO EYE,SKIN,RESPIRATORY &
|
||||
GI TRACT.CHRONIC-SKIN,GI OR RESPIRATORY DISORDERS.STORAGE-DANGER!STRONG
|
||||
OXIDIZER-CONTACT WITH COMBUSTIBLE OR OXIDIZABLE MATERIAL CONSTITUTES AN
|
||||
EXTREME FIRE & EXPLOSION HAZARD.CONTAMINATED CLOTHING & ORGANIC METERIALS
|
||||
ARE DANGEROUSLY FLAMMABLE.ALWAYS HAVE A WATER FILLED JUMP TANK OR DELUGE
|
||||
SHOWER NEARBY.IF YOUR CLOTHING CATCHES FIRE,DON'T USE A FIRE BLANKET.USE
|
||||
THE JUMP TANK OR DELUGE SHOWER.DON'T WEAR LEATHER MATERIALS.STORE
|
||||
CONTAINERS TIGHTLY CLOSED.FIRST AID-CALL A DOCTOR.EYE:FLUSH W/WATER FOR 15
|
||||
INDUCE VOMITING.GIVE WATER.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
198
textfiles.com/science/CHEMICALS/ammonium_permanganate.txt
Normal file
198
textfiles.com/science/CHEMICALS/ammonium_permanganate.txt
Normal file
@@ -0,0 +1,198 @@
|
||||
|
||||
Common Name: AMMONIUM PERMANGANATE
|
||||
CAS Number: 13446-10-1
|
||||
DOT Number: NA 9190
|
||||
------------------------------------------------------------
|
||||
Substance number: 0110
|
||||
Date: February 1988
|
||||
------------------------------------------------------------
|
||||
HAZARD SUMMARY
|
||||
* Ammonium Permanganate can affect you when breathed in.
|
||||
* Exposure to Ammonium Permanganate can cause irritation of the
|
||||
eyes, nose, throat and lungs. * Contact can irritate the skin
|
||||
and eyes.
|
||||
* Ammonium Permanganate is a HIGHLY REACTIVE CHEMICAL and is a
|
||||
DANGEROUS EXPLOSION HAZARD.
|
||||
|
||||
|
||||
IDENTIFICATION
|
||||
Ammonium Permanganate is a violet-brown or dark purple,
|
||||
crystalline (sugar or sand-like) solid.
|
||||
|
||||
|
||||
REASON FOR CITATION
|
||||
* Ammonium Permanganate is on the Hazardous Substance List
|
||||
because it is cited by DOT. * This chemical is on the Special
|
||||
Health Hazard Substance List because it is REACTIVE.
|
||||
|
||||
|
||||
HOW TO DETERMINE IF YOU ARE BEING EXPOSED
|
||||
* Exposure to hazardous substances should be routinely evaluated.
|
||||
This may include collecting personal and area air samples. You
|
||||
can obtain copies of sampling results from your employer. You
|
||||
have a legal right to this information under OSHA 1910.20. * If
|
||||
you think you are experiencing any work-related health problems,
|
||||
see a doctor trained to recognize occupational diseases. Take
|
||||
this Fact Sheet with you.
|
||||
|
||||
|
||||
WORKPLACE EXPOSURE LIMITS
|
||||
No occupational exposure limits have been established for
|
||||
Ammonium Permanganate. This does not mean that this substance is
|
||||
not harmful. Safe work practices should always be followed.
|
||||
|
||||
|
||||
WAYS OF REDUCING EXPOSURE
|
||||
* Where possible, enclose operations and use local exhaust
|
||||
ventilation at the site of chemical release. If local exhaust
|
||||
ventilation or enclosure is not used, respirators should be worn.
|
||||
* Wear protective work clothing.
|
||||
* Wash thoroughly immediately after exposure to Ammonium
|
||||
Permanganate. * Post hazard and warning information in the work
|
||||
area. In addition, as part of an ongoing education and training
|
||||
effort, communicate all information on the health and safety
|
||||
hazards of Ammonium Permanganate to potentially exposed workers.
|
||||
|
||||
|
||||
HEALTH HAZARD INFORMATION
|
||||
|
||||
Acute Health Effects
|
||||
The following acute (short-term) health effects may occur
|
||||
immediately or shortly after exposure to Ammonium Permanganate:
|
||||
|
||||
* Ammonium Permanganate can irritate the eyes, nose, throat and
|
||||
lungs. * Contact can cause eye and skin irritation.
|
||||
|
||||
Chronic Health Effects
|
||||
The following chronic (long-term) health effects can occur at
|
||||
some time after exposure to Ammonium Permanganate and can last
|
||||
for months or years:
|
||||
|
||||
Cancer Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Ammonium Permanganate has not been
|
||||
tested for its ability to cause cancer in animals.
|
||||
|
||||
Reproductive Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Ammonium Permanganate has not been
|
||||
tested for ts ability to adversely affect reproduction.
|
||||
|
||||
Other Long-Term Effects
|
||||
* Very irritating substances may affect the lungs. It is not
|
||||
known whether Ammonium Permanganate can cause lung damage.
|
||||
|
||||
|
||||
MEDICAL
|
||||
|
||||
Medical Testing
|
||||
There is no special test for this chemical. However, if illness
|
||||
occurs or overexposure is suspected, medical attention is
|
||||
recommended.
|
||||
|
||||
Any evaluation should include a careful history of past and
|
||||
present symptoms with an exam. Medical tests that look for
|
||||
damage already done are not a substitute for controlling
|
||||
exposure.
|
||||
Request copies of your medical testing. You have a legal right
|
||||
to this information under OSHA 1910.20.
|
||||
|
||||
|
||||
WORKPLACE CONTROLS AND PRACTICES
|
||||
Unless a less toxic chemical can be substituted for a hazardous
|
||||
substance, ENGINEERING CONTROLS are the most effective way of
|
||||
reducing exposure. The best protection is to enclose operations
|
||||
and/or provide local exhaust ventilation at the site of chemical
|
||||
release. Isolating operations can also reduce exposure. Using
|
||||
respirators or protective equipment is less effective than the
|
||||
controls mentioned above, but is sometimes necessary.
|
||||
|
||||
In evaluating the controls present in your workplace, consider:
|
||||
(1) how hazardous the substance is, (2) how much of the substance
|
||||
is released into the workplace and (3) whether harmful skin or
|
||||
eye contact could occur. Special controls should be in place for
|
||||
highly toxic chemicals or when significant skin, eye, or
|
||||
breathing exposures are possible.
|
||||
|
||||
In addition, the following controls are recommended:
|
||||
|
||||
* Before entering a confined space where Ammonium Permanganate
|
||||
may be present, check to make sure that an explosive
|
||||
concentration does not exist.
|
||||
|
||||
Good WORK PRACTICES can help to reduce hazardous exposures. The
|
||||
following work practices are recommended:
|
||||
|
||||
* Workers whose clothing has been contaminated by Ammonium
|
||||
Permanganate should change into clean clothing promptly. *
|
||||
Contaminated work clothes should be laundered by individuals who
|
||||
have been informed of the hazards of exposure to Ammonium
|
||||
Permanganate. * On skin contact with Ammonium Permanganate,
|
||||
immediately wash or shower to remove the chemical. * Do not eat,
|
||||
smoke, or drink where Ammonium Permanganate is handled,
|
||||
processed, or stored, since the chemical can be swallowed. Wash
|
||||
hands carefully before eating or smoking. * Use a vacuum or a wet
|
||||
method to reduce dust during clean-up. Do not dry sweep.
|
||||
|
||||
FIRE HAZARDS
|
||||
|
||||
* Ammonium Permanganate may explode at temperatures above 140oF.
|
||||
* POISONOUS GASES ARE PRODUCED IN FIRE, including Nitrogen Oxides
|
||||
and Ammonia. * Use dry chemical, CO2, water spray, or foam
|
||||
extinguishers. * CONTAINERS MAY EXPLODE IN FIRE.
|
||||
* Use water spray to keep fire-exposed containers cool.
|
||||
* If employees are expected to fight fires, they must be trained
|
||||
and equipped as stated in OSHA 1910.156.
|
||||
|
||||
|
||||
SPILLS AND EMERGENCIES
|
||||
|
||||
If Ammonium Permanganate is spilled, take the following steps:
|
||||
* Restrict persons not wearing protective equipment from area of
|
||||
spill until clean-up is complete. * Collect powdered material in
|
||||
the most convenient and safe manner and deposit in sealed
|
||||
containers. * Keep Ammonium Permanganate out of a confined space,
|
||||
such as a sewer, because of the possibility of an explosion,
|
||||
unless the sewer is designed to prevent the build-up of explosive
|
||||
concentrations. * It may be necessary to contain and dispose of
|
||||
|
||||
Ammonium Permanganate as a HAZARDOUS WASTE. Contact your
|
||||
Department of Environmental Protection (DEP) or your regional
|
||||
office of the federal Environmental Protection Agency (EPA) for
|
||||
specific recommendations.
|
||||
|
||||
|
||||
HANDLING AND STORAGE
|
||||
|
||||
* Prior to working with Ammonium Permanganate you should be
|
||||
trained on its proper handling and storage. * Ammonium
|
||||
Permanganate must be stored to avoid contact with Heat, Friction,
|
||||
Organic and OXIDIZABLE MATERIAL, FUELS, and COMBUSTIBLES since
|
||||
violent reactions occur. * Always store Ammonium Permanganate at
|
||||
temperatures below 140 degrees F (60 degrees C). * Protect
|
||||
containers from shock as Ammonium Permanganate may explode.
|
||||
|
||||
|
||||
FIRST AID
|
||||
|
||||
Eye Contact
|
||||
* Immediately flush with large amounts of water for at least 15
|
||||
minutes, occasionally lifting upper and lower lids.
|
||||
|
||||
Skin Contact
|
||||
* Quickly remove contaminated clothing. Immediately wash
|
||||
contaminated skin with large amounts of water.
|
||||
|
||||
Breathing
|
||||
* Remove the person from exposure.
|
||||
|
||||
|
||||
PHYSICAL DATA
|
||||
|
||||
Water Solubility: Soluble
|
||||
|
||||
|
||||
CHEMICAL NAME
|
||||
|
||||
Permanganic Acid, Ammonium Salt
|
||||
|
||||
173
textfiles.com/science/CHEMICALS/ammonium_picrate.txt
Normal file
173
textfiles.com/science/CHEMICALS/ammonium_picrate.txt
Normal file
@@ -0,0 +1,173 @@
|
||||
|
||||
MSDS - AMMONIUM PICRATE
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: AMMONIUM PICRATE (SARA III)
|
||||
Ingredient Sequence Number: 01
|
||||
Percent: >90
|
||||
NIOSH (RTECS) Number: BS3855000
|
||||
CAS Number: 131-74-8
|
||||
OSHA PEL: NOT ESTABLISHED
|
||||
ACGIH TLV: NOT ESTABLISHED
|
||||
Other Recommended Limit: NONE RECOMMENDED
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: WATER (CONTAMINANT)
|
||||
Ingredient Sequence Number: 02
|
||||
Percent: >10
|
||||
NIOSH (RTECS) Number: ZC0110000
|
||||
CAS Number: 7732-18-5
|
||||
OSHA PEL: NOT ESTABLISHED
|
||||
ACGIH TLV: NOT ESTABLISHED
|
||||
Other Recommended Limit: NONE RECOMMENDED
|
||||
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: CRYSTALS;YELLOW;ODOR NOT REPORTED
|
||||
Boiling Point: 793F,423C
|
||||
Melting Point: DECOMPOSES
|
||||
Specific Gravity: 1.7
|
||||
Solubility In Water: SLIGHT
|
||||
Magnetism (Milligauss): N/P
|
||||
Report for NIIN: 00D002973
|
||||
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point Method: N/P
|
||||
Extinguishing Media: DRY CHEMICAL,SAND,WATER SPRAY OR FOAM.
|
||||
Special Fire Fighting Proc: SUBSTANCE DOES NOT BURN READILY ITSELF.USE
|
||||
FLOODING QUANTITIES OF WATER AS A FOG AND TO COOL FIRE EXPOSED CONTAINERS.
|
||||
SPRAY WATER FROM AS FAR AWAY AS POSSIBLE.
|
||||
Unusual Fire And Expl Hazrds: DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT
|
||||
OR FLAME.
|
||||
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: NO
|
||||
Cond To Avoid (Stability): EXPLOSION HAZARD WHEN EXPOSED TO SHOCK,HEAT,
|
||||
FLAMES(ESP.WHEN CONTAMINATED WITH METALS).
|
||||
Materials To Avoid: METAL PICRATES(EXPLODES),METALS(EXPLODES AT 572F),
|
||||
REDUCING MATERIALS(VIGOROUS REACTION).
|
||||
Hazardous Decomp Products: AMMONIA FUMES(CORROSIVE),OXIDES OF NITROGEN AND
|
||||
CARBON(TOXIC).
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): NONE
|
||||
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NOT REPORTED
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: YES
|
||||
Route Of Entry - Ingestion: YES
|
||||
Health Haz Acute And Chronic: INHAL:IRRITANT.SKIN:IRRITANT/SENSITIZER.ITEM
|
||||
IS DERMALLY ABSORBED,POSSIBLY TO TOXIC LEVELS.EYES:ITTITATION.INGEST:TOXIC.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: AMMONIUM PICRATE HAS NO CARCINOGENICITY
|
||||
STATUS.
|
||||
Signs/Symptoms Of Overexp: INHAL:MUCUOUS MEMBRANE IRRITATION,RHINITIS.
|
||||
SKIN:SENSITIZATION DERMATITIS.ABSORPTION(THROUGH INHAL OR INGEST)CAUSES
|
||||
NAUSEA,VOMITING,DIARRHEA,ABDOM.PAIN,YELLOWING OF SKIN,SKIN ERUPTIONS,
|
||||
STUPOR,CONVULSIONS,DEATH.EYES:CONJUNCTIVITIS(FROM ACUTE AND CHRONIC
|
||||
EXPOSURE).
|
||||
Med Cond Aggravated By Exp: NOT REPORTED.
|
||||
Emergency/First Aid Proc: INHAL:REMOVE FROM EXPOSURE.SUPPORT
|
||||
BREATHING.CALL PHYSICIAN;TREAT SYMPTOMATICALLY.SKIN:REMOVE CONTAMINATED
|
||||
CLOTHING AND SHOES;WASH WITH SOAP(OR MILD DETERGENT) FOR 15-20 MINUTES.CALL
|
||||
PHYSICIAN.EYE:WASH WITH WATER OR NORMAL SALINE FOR 15-20 MINUTES.CALL
|
||||
PHYSICIAN.INGEST:INDUCE VOMITING(IF CONSCIOUS);KEEP HEAD BELOW HIPS.GET
|
||||
PROPMT MEDICAL HELP.
|
||||
Report for NIIN: 00D002973
|
||||
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: SHUT OF IGNITION SOURCES.DO NOT TOUCH SPILL.
|
||||
SMALL SPILL:FLUSH AREA WITH WATER.LARGE SPILL:WET DOWN WITH WATER AND DIKE
|
||||
FOR LATER DISPOSAL.REPORTABLE QUANTITY=10 POUNDS.
|
||||
Neutralizing Agent: NOT KNOWN.
|
||||
Waste Disposal Method: NOT SPECIFIED BY MANUFACTURER.FOLLOW FEDERAL,STATE
|
||||
AND LOCAL REGULATIONS.
|
||||
Precautions-Handling/Storing: THIS MATERIAL EXPLODES EASILY WHEN DRY FROM
|
||||
HEAT OR SHOCK.
|
||||
Other Precautions: NONE.
|
||||
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: BY INCREASING LEVELS:1-A DUST AND MIST
|
||||
RESPIRATOR+FULL FACEPIECE.2-AIR-PURIFYING FULL FACEPIECE RESPIRATOR+HEPA
|
||||
FILTER.3-POWERED AIR-PURIFYING RESP.+HEPA FILTER.4-TYPE C,AIR SUPPLIED
|
||||
RESP.4-SCBA IN POSITIVE PRESSURE MODE.
|
||||
Ventilation: PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION.
|
||||
MECHANICALS SHOULD BE EXPLOSION-PROOF.
|
||||
Protective Gloves: CHEMICALLY RESISTANT.
|
||||
Eye Protection: SPLASH AND DUST RESISTANT GOGGLES.
|
||||
Other Protective Equipment: USE IMPERVIOUS CLOTHING TO PREVENT SKIN
|
||||
CONTACT.AN EYE WASH STATION AND QUICK DRENCH SHOWER SHOULD BE AVAILABLE.
|
||||
Work Hygienic Practices: USE PRUDENT HYGENIC AND SANITARY PRACTICES.WASH
|
||||
HANDS.KEEP FOOD AOUT OF THE WORK AREA.
|
||||
Suppl. Safety & Health Data: NONE.
|
||||
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 93061
|
||||
DOT PSN Code: AST
|
||||
DOT Proper Shipping Name: AMMONIUM PICRATE
|
||||
DOT Class: 1.1D
|
||||
DOT ID Number: UN0004
|
||||
DOT Pack Group: II
|
||||
DOT Label: EXPLOSIVE 1.1D
|
||||
IMO PSN Code: BAL
|
||||
IMO Proper Shipping Name: AMMONIUM PICRATE
|
||||
IMO Regulations Page Number: 1104
|
||||
IMO UN Number: 0004
|
||||
IMO UN Class: 1.1 D
|
||||
IMO Subsidiary Risk Label: -
|
||||
IATA PSN Code: BQR
|
||||
IATA UN ID Number: 0004
|
||||
IATA UN Class: 1.1D
|
||||
Report for NIIN: 00D002973
|
||||
AFI Prop. Shipping Name: UNDER REVIEW
|
||||
Additional Trans Data: REPORTABLE QUANTITY=10 LBS.MFR SUGGESTS DOT-
|
||||
EXPLOSIVE A;UN 0004.
|
||||
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 02MAR93
|
||||
MFR Label Number: UNKNOWN
|
||||
Label Status: F
|
||||
Common Name: AMMONIUM PICRATE
|
||||
Chronic Hazard: YES
|
||||
Signal Word: DANGER!
|
||||
Acute Health Hazard-Severe: X
|
||||
Report for NIIN: 00D002973
|
||||
Contact Hazard-Severe: X
|
||||
Fire Hazard-Severe: X
|
||||
Reactivity Hazard-Severe: X
|
||||
Special Hazard Precautions: INHAL:IRRITANT.SKIN:IRRITANT/SENSITIZER.ITEM
|
||||
IS DERMALLY ABSORBED,POSSIBLY TO TOXIC LEVELS.EYES:IRRITATION.INGEST:TOXIC.
|
||||
INHAL:REMOVE FROM EXPOSURE.SUPPORT BREATHING.CALL PHYSICIAN;TREAT
|
||||
SYMPTOMATICALLY.SKIN:REMOVE CONTAMINATED CLOTHING AND SHOES;WASH WITH
|
||||
SOAP(OR MILD DETERGENT) FOR 15-20 MINUTES.CALL PHYSICIAN.EYE:WASH WITH
|
||||
WATER OR NORMAL SALINE FOR 15-20 MINUTES.CALL PHYSICIAN.INGEST:INDUCE
|
||||
VOMITING(IF CONSCIOUS);KEEP HEAD BELOW HIPS.GET PROPMT MEDICAL HELP.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
169
textfiles.com/science/CHEMICALS/anthracene.txt
Normal file
169
textfiles.com/science/CHEMICALS/anthracene.txt
Normal file
@@ -0,0 +1,169 @@
|
||||
|
||||
MSDS - ANTHRACENE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: ANTHRACENE
|
||||
FORMULA: C14H10
|
||||
FORMULA WT: 178.24
|
||||
CAS NO.: 00120-12-7
|
||||
NIOSH/RTECS NO.: CA9350000
|
||||
PRODUCT CODES: B490
|
||||
EFFECTIVE: 03/11/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 342 C ( 648 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 214 C ( 417 F) VAPOR DENSITY(AIR=1): 6.2
|
||||
|
||||
SPECIFIC GRAVITY: 1.25 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: OFF-WHITE TO PALE GREEN-YELLOW CRYSTALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: 121 C ( 250 F) NFPA 704M RATING: 0-1-
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - .6 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
TOXICITY: LD50 (IPR-MOUSE)(MG/KG) - 430
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY BE IRRITATING TO EYES, NOSE, THROAT, OR LUNGS.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, FLUORINE
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME ANTHRACENE
|
||||
HAZARD CLASS ORM-E
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
181
textfiles.com/science/CHEMICALS/antimony.txt
Normal file
181
textfiles.com/science/CHEMICALS/antimony.txt
Normal file
@@ -0,0 +1,181 @@
|
||||
|
||||
MSDS - ANTIMONY
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: ANTIMONY
|
||||
FORMULA: SB
|
||||
FORMULA WT: 121.75
|
||||
CAS NO.: 07440-36-0
|
||||
NIOSH/RTECS NO.: CC4025000
|
||||
COMMON SYNONYMS: STIBIUM, C.I. 77050
|
||||
PRODUCT CODES: 0848
|
||||
EFFECTIVE: 08/27/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (POISON)
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 2 MODERATE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
MAY BE FATAL IF INHALED
|
||||
CAUSES IRRITATION
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
ANTIMONY 90-100 7440-36-0
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 1635 C ( 2975 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 630 C ( 1166 F) VAPOR DENSITY(AIR=1): 4.2
|
||||
|
||||
SPECIFIC GRAVITY: 6.68 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: SILVER-WHITE, HARD, BRITTLE METAL.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.5 MG/M3 ( PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 0.5 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION MAY BE HARMFUL OR FATAL.
|
||||
PROLONGED EXPOSURE MAY CAUSE DERMATITIS.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
|
||||
NOTE: PRODUCT IS A SOLID MASS; HOWEVER, WARNINGS ARE BASED ON INHALATION
|
||||
DUST, MIST OR FUME EMISSIONS THAT ARE POSSIBLE DURING MANUFACTURING OR
|
||||
CHEMICAL REACTIONS.
|
||||
|
||||
TARGET ORGANS
|
||||
RESPIRATORY SYSTEM, CARDIOVASCULAR SYSTEM, EYES, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, LIGHT
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG ACIDS, HALOGEN ACIDS,
|
||||
CHLORINE, FLUORINE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 1 PPM, A DUST/MIST RESPIRATOR IS
|
||||
RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED
|
||||
BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
KEEP PRODUCT OUT OF LIGHT.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME ANTIMONY, POWDER
|
||||
HAZARD CLASS ORM-E
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME ANTIMONY, POWDER
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN2871
|
||||
LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS
|
||||
|
||||
117
textfiles.com/science/CHEMICALS/antimony_trisulfide.txt
Normal file
117
textfiles.com/science/CHEMICALS/antimony_trisulfide.txt
Normal file
@@ -0,0 +1,117 @@
|
||||
|
||||
MSDS - ANTIMONY SULFIDE
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: ANTIMONY TRISULFIDE;(ANTIMONY SULFIDE) (MFR CAS# 12627-52-0)
|
||||
Ingredient Sequence Number: 01
|
||||
Percent: 97.5
|
||||
NIOSH (RTECS) Number: CC9450000
|
||||
CAS Number: 1345-04-6
|
||||
OSHA PEL: 0.5 MG/M3 (SB)
|
||||
ACGIH TLV: 0.5 MG/M3 (SB)
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: ODORLESS BLACK POWDER OR GRAY, LUSTROUS, CRYSTALS. *
|
||||
Boiling Point: 60.0F,15.6C *
|
||||
Melting Point: N/K *
|
||||
Vapor Pressure (MM Hg/70 F): N/K *
|
||||
Vapor Density (Air=1): N/K *
|
||||
Specific Gravity: 4.64 *
|
||||
Decomposition Temperature: N/K *
|
||||
Evaporation Rate And Ref: N/K *
|
||||
Solubility In Water: INSOLUBLE *
|
||||
Percent Volatiles By Volume: 0 *
|
||||
pH: N/K *
|
||||
Corrosion Rate (IPY): N/K *
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: NONE *
|
||||
Flash Point Method: N/P *
|
||||
Lower Explosive Limit: N/A *
|
||||
Upper Explosive Limit: N/A *
|
||||
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). *
|
||||
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL
|
||||
PROTECTIVE EQUIPMENT (FP N). *
|
||||
Unusual Fire And Expl Hazrds: NONE. *
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES *
|
||||
Cond To Avoid (Stability): HIGH TEMPERATURES, MODERATE EXPLOSION AND FIRE
|
||||
CONTACT WITH STRONG OXIDIZERS. *
|
||||
Materials To Avoid: WITH STRONG ACIDS, MAY GIVE OFF H2S. *
|
||||
Hazardous Decomp Products: TOXIC FUMES OF OXIDES OF SULFUR AND ANTIMONY. *
|
||||
Hazardous Poly Occur: NO *
|
||||
Conditions To Avoid (Poly): NOT RELEVANT. *
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Route Of Entry - Inhalation: YES *
|
||||
Route Of Entry - Skin: YES *
|
||||
Route Of Entry - Ingestion: YES *
|
||||
Health Haz Acute And Chronic: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Carcinogenicity - NTP: NO *
|
||||
Carcinogenicity - IARC: NO *
|
||||
Carcinogenicity - OSHA: NO *
|
||||
Explanation Carcinogenicity: NOT RELEVANT. *
|
||||
Signs/Symptoms Of Overexp: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Emergency/First Aid Proc: INGEST: IF SWALLOWED, INDUCE VOMIT. SEE PHYS.
|
||||
EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN. SKIN: WASH WITH SOAP AND WATER.
|
||||
INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG.(GIVE O2/ARTF RESP) (FP N) . *
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: SWEEP OR VACUUM UP. *
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Waste Disposal Method: BURY MATERIAL IN HAZARDOUS LANDFILL - FOLLOW ALL
|
||||
LOCAL, STATE AND FEDERAL REGULATIONS. *
|
||||
Precautions-Handling/Storing: NORMAL HANDLING AND STORAGE. *
|
||||
Other Precautions: NONE SPECIFIED BY MANUFACTURER. *
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: USE NIOSH/MSHSA APPROVED DUST MASK. *
|
||||
Ventilation: LOCAL EXHAUST: NORMAL. *
|
||||
Protective Gloves: IMPERVIOUS GLOVES (FP N). *
|
||||
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N). *
|
||||
Other Protective Equipment: PROTECTIVE RUBBER GLOVES. *
|
||||
Work Hygienic Practices: NORMAL HANDLING AND STORAGE. *
|
||||
Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER. *
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 92065
|
||||
DOT PSN Code: ZZZ
|
||||
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
IMO PSN Code: ZZZ
|
||||
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
|
||||
IATA PSN Code: ZZZ
|
||||
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
AFI PSN Code: ZZZ
|
||||
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
Additional Trans Data: NOT REGULATED FOR TRANSPORTATION
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 06SEP91
|
||||
Label Date: 26AUG91
|
||||
Label Status: M
|
||||
Common Name: ANTIMONY SULFIDE
|
||||
Chronic Hazard: NO
|
||||
Signal Word: CAUTION!
|
||||
Acute Health Hazard-Slight: X
|
||||
Contact Hazard-None: X
|
||||
Fire Hazard-None: X
|
||||
Reactivity Hazard-None: X
|
||||
|
||||
188
textfiles.com/science/CHEMICALS/arsenic_oxide.txt
Normal file
188
textfiles.com/science/CHEMICALS/arsenic_oxide.txt
Normal file
@@ -0,0 +1,188 @@
|
||||
|
||||
MSDS - ARSENIC TRIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: ARSENIC TRIOXIDE
|
||||
FORMULA: AS2O3
|
||||
FORMULA WT: 197.84
|
||||
CAS NO.: 1327-53-3
|
||||
NIOSH/RTECS NO.: CG3325000
|
||||
COMMON SYNONYMS: ARSENIC OXIDE; ARSENIC(III)OXIDE; ARSENOUS TRIOXIDE;
|
||||
ARSENOUS ACID
|
||||
PRODUCT CODES: 0062,0061
|
||||
EFFECTIVE: 08/15/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 4 EXTREME (CANCER CAUSING)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
CAUSES IRRITATION
|
||||
MAY BE FATAL IF SWALLOWED
|
||||
HARMFUL IF INHALED OR ABSORBED THROUGH SKIN
|
||||
CAUTION: CONTAINS INORGANIC ARSENIC, CANCER HAZARD
|
||||
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
ARSENIC TRIOXIDE 90-100 1327-53-3
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 457 C ( 855 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 315 C ( 599 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 3.87 EVAPORATION RATE: N/A (H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): SLIGHT (0.1 TO 1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE ODORLESS POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THIS SUBSTANCE IS LISTED AS ACGIH SUSPECT HUMAN CARCINOGEN, NTP HUMAN
|
||||
CARCINOGEN, AND IARC HUMAN CARCINOGEN (GROUP 1).
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.2 MG/M3 ( PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 0.5 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 15.1
|
||||
|
||||
CARCINOGENICITY: NTP: YES IARC: YES Z LIST: YES OSHA REG: YES
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INGESTION IS HARMFUL AND MAY BE FATAL.
|
||||
INHALATION OF VAPORS MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS,
|
||||
DROWSINESS, IRRITATION OF RESPIRATORY TRACT, AND LOSS OF CONSCIOUSNESS.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, PARALYSIS.
|
||||
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
LIVER, KIDNEYS, SKIN, LUNGS, LYMPHATIC SYSTEM
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, ABSORPTION, EYE CONTACT, SKIN CONTACT, INGESTION
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, CHEMICALLY ACTIVE METALS,
|
||||
ALUMINUM
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: P012 (ACUTE HAZARDOUS WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A DUST/MIST RESPIRATOR IS
|
||||
RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF
|
||||
RESPIRATOR, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME ARSENIC TRIOXIDE, SOLID
|
||||
HAZARD CLASS POISON B
|
||||
UN/NA UN1561
|
||||
LABELS POISON
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME ARSENIC TRIOXIDE
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1561
|
||||
LABELS POISON
|
||||
|
||||
64
textfiles.com/science/CHEMICALS/asphaltum.txt
Normal file
64
textfiles.com/science/CHEMICALS/asphaltum.txt
Normal file
@@ -0,0 +1,64 @@
|
||||
|
||||
MSDS - ASPHALTUM
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: NON-HAZARDOUS FOR INGREDIENTS
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: 1000314NH
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point Method: N/P
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Report for NIIN: 00F033053
|
||||
Hazardous Poly Occur: NO
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
Route Of Entry - Inhalation: NO
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: NO
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NONE
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: CLEAN UP W/CLOTH OR PAPER TOWELS.
|
||||
Waste Disposal Method: DISPOSE AS NORMAL HOUSEHOLD TRASH
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Report for NIIN: 00F033053
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 24FEB94
|
||||
Label Date: 18FEB94
|
||||
Label Status: F
|
||||
Common Name: 2765 ASPHALTUM
|
||||
Report for NIIN: 00F033053
|
||||
Chronic Hazard: NO
|
||||
Signal Word: NONE
|
||||
Acute Health Hazard-None: X
|
||||
Contact Hazard-None: X
|
||||
Fire Hazard-None: X
|
||||
Reactivity Hazard-None: X
|
||||
|
||||
182
textfiles.com/science/CHEMICALS/auramine_o.txt
Normal file
182
textfiles.com/science/CHEMICALS/auramine_o.txt
Normal file
@@ -0,0 +1,182 @@
|
||||
|
||||
MSDS - AURAMINE O
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: AURAMINE O
|
||||
FORMULA: C17H21N3 HCL
|
||||
FORMULA WT: 303.84
|
||||
CAS NO.: 02465-27-2
|
||||
NIOSH/RTECS NO.: BY3675000
|
||||
COMMON SYNONYMS: BASIC YELLOW 2;
|
||||
ANILINE,4,4'-(IMIDOCARBONYL)BIS(N,N-DIMETHYL;HYDROCHLORIDE)
|
||||
PRODUCT CODES: B604
|
||||
EFFECTIVE: 01/22/87
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 4 EXTREME (CANCER CAUSING)
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
HARMFUL IF INHALED
|
||||
CAUTION: CANCER HAZARD
|
||||
EXCEPTIONAL HEALTH HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
AURAMINE O 90-100 2465-27-2
|
||||
AURAMINE O 90-100 2465-27-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 267 C ( 513 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: N/A EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): SLIGHT (0.1 TO 1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: YELLOW POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
NITROGEN OXIDES, HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THIS SUBSTANCE IS LISTED AS AN NTP HUMAN CARCINOGEN AND AND IARC HUMAN
|
||||
CARCINOGEN (GROUP 1).
|
||||
|
||||
TOXICITY: LD50 (ORAL-MOUSE)(MG/KG) - 480
|
||||
LD50 (SKIN-MOUSE) (G/KG) - 0.3
|
||||
|
||||
CARCINOGENICITY: NTP: YES IARC: YES Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
DUST MAY CAUSE HEADACHE, COUGHING, DIZZINESS OR DIFFICULT BREATHING.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN, HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: U014 (TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: A RESPIRATOR WITH DUST/MIST FILTER IS RECOMMENDED.
|
||||
IF AIRBORNE CONCENTRATION EXCEEDS CAPACITY OF
|
||||
RESPIRATOR, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME AURAMINE
|
||||
HAZARD CLASS ORM-E
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 1 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
184
textfiles.com/science/CHEMICALS/barium_carbonate.txt
Normal file
184
textfiles.com/science/CHEMICALS/barium_carbonate.txt
Normal file
@@ -0,0 +1,184 @@
|
||||
|
||||
MSDS - BARIUM CARBONATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: BARIUM CARBONATE
|
||||
FORMULA: BACO3
|
||||
FORMULA WT: 197.35
|
||||
CAS NO.: 513-77-9
|
||||
NIOSH/RTECS NO.: CQ8750000
|
||||
PRODUCT CODES: 5181,0952,0950,5313,5095,5142
|
||||
EFFECTIVE: 05/12/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
CAUSES IRRITATION
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1300 C ( 2372 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 4.28 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
|
||||
APPEARANCE & ODOR: WHITE TO CREAM-COLORED POWDER WITHOUT AN ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 630
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
INGESTION MAY CAUSE NAUSEA AND VOMITING.
|
||||
INGESTION MAY CAUSE GASTROINTESTINAL PAIN.
|
||||
CHRONIC EFFECTS OF BARIUM COMPOUNDS MAY INCLUDE BRONCHIAL IRRITATION,
|
||||
DEGENERATION OF CENTRAL NERVOUS SYSTEM, AND DAMAGE TO SPLEEN,
|
||||
LIVER, AND BONE MARROW.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNT OF MILK, MILK OF MAGNESIA,
|
||||
OR WHITES OF EGGS BEATEN WITH WATER. INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D005 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME BARIUM COMPOUNDS, N.O.S. (BARIUM CARBONATE)
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1564
|
||||
LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS
|
||||
|
||||
152
textfiles.com/science/CHEMICALS/barium_chlorate.txt
Normal file
152
textfiles.com/science/CHEMICALS/barium_chlorate.txt
Normal file
@@ -0,0 +1,152 @@
|
||||
|
||||
MSDS- BARIUM CHLORATE
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: CHLORIC ACID, BARIUM SALT; (BARIUM CHLORATE)
|
||||
Ingredient Sequence Number: 01
|
||||
Percent: 100
|
||||
NIOSH (RTECS) Number: FN9770000
|
||||
CAS Number: 13477-00-4
|
||||
OSHA PEL: 0.5MG/M3(AS BA)(MFR)
|
||||
ACGIH TLV: 0.5MG/M3(AS BA)(MFR)
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: BARIUM CHLORATE
|
||||
Ingredient Sequence Number: 02
|
||||
SUPDAT: HEART STOPPAGE.
|
||||
NIOSH (RTECS) Number: 9999999ZZ
|
||||
OSHA PEL: NOT APPLICABLE
|
||||
ACGIH TLV: NOT APPLICABLE
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: SPILL PROC:HAZARDS, & ARE FRICTION & SHOCK SENSITIVE.
|
||||
Ingredient Sequence Number: 03
|
||||
NIOSH (RTECS) Number: 9999999ZZ
|
||||
OSHA PEL: NOT APPLICABLE
|
||||
ACGIH TLV: NOT APPLICABLE
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: COLORLESS CRYSTAL, WHITE POWDER.
|
||||
Melting Point: 777F,414C
|
||||
Vapor Pressure (MM Hg/70 F): N/A
|
||||
Specific Gravity: 3.18
|
||||
Evaporation Rate And Ref: NOT APPLICABLE
|
||||
Solubility In Water: SOLUBLE
|
||||
Percent Volatiles By Volume: N/A
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: NOT APPLICABLE
|
||||
Flash Point Method: N/P
|
||||
Extinguishing Media: USE DRY CHEMICAL, CO*2.
|
||||
Special Fire Fighting Proc: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
|
||||
EQUIPMENT (FP N).
|
||||
Unusual Fire And Expl Hazrds: POWERFUL OXIDIZER; CAN INITIATE/ACCELERATE
|
||||
COMBUST. USED IN EXPLO INDUSTRY. HEAT, FRICTION, SHOCK & REDUCING MATLS CAN
|
||||
EXPLODE BARIUM CHLORATE. SMALL (SUPDAT)
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: NO
|
||||
Cond To Avoid (Stability): HEAT.
|
||||
Materials To Avoid: AL, AS, C, CHARCOAL, CU, MNO*2, METAL SULFIDES,
|
||||
S*4N*4, ORGANIC MATTER, P, S, REDUCING MATLS.
|
||||
Hazardous Decomp Products: BAO, CL.
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): HEAT, FRICTION, SHOCK, IMPURITIES &
|
||||
INCOMPATIBLE MATERIALS.
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: YES
|
||||
Health Haz Acute And Chronic: INHAL:ACUTE POIS BY INHAL HAS PROGRESSIVE
|
||||
SYMPS OF IRRIT OF NOSE & EYES, MUSCULAR TWITCHING, TENDENCY TO FATG, ABDOM
|
||||
CRAMPS, COLD SWEAT, SLOW HEART RATE & DEATH FROM HEART STOPPING. IRRIT TO
|
||||
MUC MEMBS. SKIN/EYE:IRRITATING. CAUSES WATERING & BURNING SENSATION IN EYES
|
||||
W/INFLAMM OF EYELIDS. PRLNG CONT OF (EFTS OF OVEREXP)
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NOT RELEVANT
|
||||
Signs/Symptoms Of Overexp: HLTH HAZ:DUSTS W/MOIST SKIN CAUSES ULCERATION.
|
||||
OTHER:CHLORATES PRDCE METHEMOGLOBIN IN BLOOD & DESTROYS RED BLOOD CELLS,
|
||||
LEADING TO IRRIT OF KIDNEYS & MAY DMG HEART MUSCLE. ACUTE POIS THRU INGEST
|
||||
HAS PROGRESSIVE SYMPS OF DISAGREEABLE TASTE, MUSCULAR TWITCHING, NAUS &
|
||||
VOMIT, STOM PAINS & DIARR, ANXIETY, SLOW (SUPP DATA)
|
||||
Med Cond Aggravated By Exp: RESPIRATORY DISORDERS.
|
||||
Emergency/First Aid Proc: INGEST:ADMINISTER IPERAC FOLLOWED BY CUP OF
|
||||
WATER TO INDUCE VOMITING. AFTER VOMITING, ADMINISTER 1 T OF MAGNESIUM
|
||||
SULFATE & 8 OZ WATER TO DRINK. SEEK MED ATTN IMMED. INHAL:REMOVE VICTIM TO
|
||||
FRESH AIR; ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. SEEK MED ATTN.
|
||||
FLUSH W/LUKEWARM WATER FOR AT LST 15 MINS & SEEK MED ATTN.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
|
||||
CLTHG. ISOLATE AREA WHERE SPILL OCCURRED & INSURE PROPER VENT IS AVAIL.
|
||||
VACUUM UP SPILL USING HIGH EFFICIENCY UNIT & PLACE IN CNTNR FOR PROPER
|
||||
DISP. TAKE CARE NOT TO RAISE DUST. SPILLS ARE EXTREME EXPLO (ING 3)
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: DISPOSE OF I/A/W APPLICABLE FEDERAL, STATE & LOCAL
|
||||
REGULATIONS.
|
||||
Precautions-Handling/Storing: SHOULD HAVE ISOLATED STORAGE IN A COOL,
|
||||
VENTILATED PLACE AWAY FROM ACUTE FIRE HAZARDS. STORE IN TIGHTLY CLOSED
|
||||
CONTAINERS IN A COOL, DRY PLACE.
|
||||
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: WEAR NIOSH/MSHA APPROVED DUST-MIST-FUME CARTRIDGE
|
||||
RESPIRATOR.
|
||||
Ventilation: ALWAYS MAINTAIN EXPOS BELOW PELS. LOC EXHST:MAINTAIN BELOW
|
||||
TLV FOR BA. MECH(GEN):REC. HANDLE IN CONTROLLED, INERT ATM.
|
||||
Protective Gloves: NEOPRENE GLOVES.
|
||||
Eye Protection: ANSI APRV CHEMICAL SAFETY GOGGLES (FP N)
|
||||
Other Protective Equipment: WEAR PROTECTIVE CLOTHING TO PREVENT
|
||||
CONTAMINATION OF SKIN & CLOTHES.
|
||||
Work Hygienic Practices: WASH HANDS & FACE THOROUGHLY AFTER HANDLING &
|
||||
BEFORE MEALS.
|
||||
Suppl. Safety & Health Data: EXPLO HAZ:IMPURITIES CAN GREATLY INCR
|
||||
SENSITIVITY OF EXPLO. EFTS OF OVEREXP:HEART RATE, CONVLS, BLUISH FACE &
|
||||
LIPS, STATE OF SHOCK (WEAK & RAPID PULSE, COLD SWEAT, PALE COMPLEXION, LT
|
||||
HEAD, COLD HANDS & FEET), PARAL OF LOWER LIMBS SPREADING TO UPPER LIMBS,
|
||||
DFCLTY IN BRTHG, DEATH BY RESP PARAL, RESP FAILURE/ (ING 2)
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 29SEP93
|
||||
Label Date: 16SEP93
|
||||
Label Status: M
|
||||
Common Name: BARIUM CHLORATE
|
||||
Chronic Hazard: YES
|
||||
Signal Word: DANGER!
|
||||
Acute Health Hazard-Severe: X
|
||||
Contact Hazard-Moderate: X
|
||||
Fire Hazard-None: X
|
||||
Reactivity Hazard-None: X
|
||||
Special Hazard Precautions: POISON! OXIDIZER! ISOLATED STORAGE IN COOL,
|
||||
VENTILATED PLACE AWAY FROM FIRE HAZARDS. ACUTE:INHAL:ACUTE POISONING BY
|
||||
INHALATION HAS PROGRESSIVE SYMPTOMS OF IRRITATION OF NOSE & EYES, MUSCULAR
|
||||
TWITCHING, TENDENCY TO FATIGUE, ABDOMINAL CRAMPS, COLD SWEAT, SLOW HEART
|
||||
IRRITATING. CAUSES WATERING & BURNING SENSATION IN EYES W/INFLAMMATION OF
|
||||
EYELIDS. PROLONGED CONTACT OF DUSTS W/MOIST SKIN CAUSES ULCERATION.
|
||||
CHRONIC:CHLORATES PRODUCE METHEMOGLOBIN IN BLOOD & DESTROY RED BLOOD CELLS,
|
||||
LEADING TO IRRITATION OF KIDNEYS & MAY DAMAGE HEART MUSCLE.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
178
textfiles.com/science/CHEMICALS/barium_chloride.txt
Normal file
178
textfiles.com/science/CHEMICALS/barium_chloride.txt
Normal file
@@ -0,0 +1,178 @@
|
||||
|
||||
MSDS - BARIUM CHLORIDE, ANHYDROUS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: BARIUM CHLORIDE, ANHYDROUS
|
||||
FORMULA: BACL2
|
||||
FORMULA WT: 208.25
|
||||
CAS NO.: 10361-37-2
|
||||
NIOSH/RTECS NO.: CQ8750000
|
||||
COMMON SYNONYMS: BARIUM DICHLORIDE
|
||||
PRODUCT CODES: 0980
|
||||
EFFECTIVE: 10/21/85
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (POISON)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
MAY BE FATAL IF SWALLOWED
|
||||
CAUSES IRRITATION
|
||||
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
BARIUM CHLORIDE, ANHYDROUS 90-100 10361-37-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 1560 C ( 2840 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 963 C ( 1765 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 3.10 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: FINE, WHITE, CRYSTALLINE OR GRANULAR POWDER, WITH NO ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.5 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 118
|
||||
LD50 (SCU-RAT)(MG/KG) - 178
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 54
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INGESTION MAY BE FATAL.
|
||||
CHRONIC EFFECTS OF BARIUM COMPOUNDS MAY INCLUDE BRONCHIAL IRRITATION,
|
||||
DEGENERATION OF CENTRAL NERVOUS SYSTEM, AND DAMAGE TO SPLEEN,
|
||||
LIVER, AND BONE MARROW.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D005 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 3 PPM, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A
|
||||
SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME BARIUM COMPOUNDS, N.O.S. (BARIUM CHLORIDE, ANHYDROUS)
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1564
|
||||
LABELS POISON
|
||||
|
||||
140
textfiles.com/science/CHEMICALS/barium_chromate.txt
Normal file
140
textfiles.com/science/CHEMICALS/barium_chromate.txt
Normal file
@@ -0,0 +1,140 @@
|
||||
|
||||
MSDS - BARIUM CHROMATE
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: BARIUM CHROMATE (VI) (BACRO*4)
|
||||
ELEMENTAL CHROMIUM. PEL/TLV AS CHROMATES: 0.1 (ING 2)
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: CQ8760000
|
||||
CAS Number: 10294-40-3
|
||||
OSHA PEL: 0.5 MG/M3 (BA)
|
||||
ACGIH TLV: 0.5 MG/M3 (BA)
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: ING 1: MG/M3 PEL; 0.05 MG/M3 TLV; 0.001 MG/M3 C.
|
||||
Ingredient Sequence Number: 02
|
||||
NIOSH (RTECS) Number: 9999999ZZ
|
||||
OSHA PEL: NOT APPLICABLE
|
||||
ACGIH TLV: NOT APPLICABLE
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: YELLOW POWDER - NO ODOR.
|
||||
Boiling Point: DECOMPOSES
|
||||
Melting Point: DECOMPOSES
|
||||
Vapor Pressure (MM Hg/70 F): NEGLIGIBLE
|
||||
Vapor Density (Air=1): N/A
|
||||
Specific Gravity: 4.5 (H*2O=1)
|
||||
Evaporation Rate And Ref: NOT APPLICABLE
|
||||
Solubility In Water: INSOLUBLE
|
||||
Report for NIIN: 00N012831
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: NOT APPLICABLE
|
||||
Flash Point Method: N/P
|
||||
Lower Explosive Limit: NON-FLAMM
|
||||
Upper Explosive Limit: NON-FLAMM
|
||||
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE OR WATER SPRAY. FOR
|
||||
LARGE FIRES - FOG.
|
||||
Special Fire Fighting Proc: IN STORAGE AREA - USE UNMANNED HOSE HOLDER AND
|
||||
WITHDRAW FROM AREA UNTIL FIRE IS OUT. WEAR NIOSH/MSHA APPROVED SCBA AND
|
||||
FULL PROTECTIVE EQUIPMENT (FP N).
|
||||
Unusual Fire And Expl Hazrds: NOT APPLICABLE
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
|
||||
Materials To Avoid: REDUCING AGENTS MAY REACT VIGOROUSLY.
|
||||
Hazardous Decomp Products: NONE SPECIFIED BY MANUFACTURER.
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): NOT RELEVANT
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: NO
|
||||
Health Haz Acute And Chronic: WORKERS MAY EXPERIENCE AN INCREASED
|
||||
INCIDENCE OF LUNG CANCER. POISONING MAY AFFECT THE BLOOD, CNS, LIVER AND
|
||||
KIDNEYS. BARIUM COMPOUNDS ARE SKIN, EYE AND MUCOUS MEMBRANE IRRITANTS.
|
||||
Carcinogenicity - NTP: YES
|
||||
Carcinogenicity - IARC: YES
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: BARIUM CHROMATE (VI):IARC MONOGRAPHS,
|
||||
SUPPLEMENT, VOL 49, PG 49, 1990: GROUP 1. NTP 7TH ANNUAL REPORT ON (SUPP
|
||||
DATA)
|
||||
Signs/Symptoms Of Overexp: VOMITING, VIOLENT DIARRHEA, ABDOMINAL PAIN,
|
||||
DIFFICULTY IN BREATHING, SLOW PULSE AND IRREGULAR HEARTBEAT. MAY CAUSE
|
||||
BLEEDING AND ULCERATION OF NASAL SEPTUM. SORE THROAT, COUGHING AND POSSIBLE
|
||||
LIVER DAMAGE. SKIN RASHES, LARGE DOSES MAY CAUSE CARDIAC AND RESPIRATORY
|
||||
FAILURE AND HEMORRHAGES IN THE GI TRACT AND KIDNEYS.
|
||||
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
|
||||
Emergency/First Aid Proc: INHAL: REMOVE FROM EXPOSURE AREA. SKIN: REMOVE
|
||||
CONTAMINATED CLOTHING AND SHOES. WASH AFFECTED AREA WITH SOAP AND WATER.
|
||||
EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN. GET MEDICAL
|
||||
ATTENTION. INGEST: MEDICAL PERSONNEL SHOULD REMOVE CHROMATES BY GASTRIC
|
||||
LAVAGE.
|
||||
Report for NIIN: 00N012831
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: KEEP COMBUSTIBLES AWAY FROM SPILLED
|
||||
MATERIAL. SHOVEL MATERIAL INTO CLEAN DRY CONTAINER AND COVER. MOVE
|
||||
CONTAINERS FROM SPILL AREA.
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: CONTAMINATED RESIDUE AND SWEEPINGS ARE CONSIDERED A
|
||||
TOXIC WASTE. MUST BE DISPOSED OF IN A LICENSED TOXIC WASTE DUMP. DISPOSAL
|
||||
MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS (FP N).
|
||||
Precautions-Handling/Storing: KEEP AWAY FROM COMBUSTIBLES. STORE IN DRY
|
||||
AREA. KEEP CONTAINERS CLOSED.
|
||||
Other Precautions: KEEP AWAY FROM REDUCING AGENTS.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: NIOSH/MSHA APPROVED HIGH EFFICIENCY PARTICULATE
|
||||
RESPIRATOR WITH FULL FACE PIECE.
|
||||
Ventilation: LOCAL EXHAUST: SUFFICIENT TO ELIMINATE DUSTS.
|
||||
Protective Gloves: IMPERVIOUS GLOVES (FP N).
|
||||
Eye Protection: ANSI APPRVD CHEM WORKER GOGGLES (FP N).
|
||||
Other Protective Equipment: IMPERVIOUS CLOTHING AND EQUIPMENT TO PREVENT
|
||||
ANY POSSIBILITY OF SKIN CONTACT WITH SUBSTANCE.
|
||||
Work Hygienic Practices: WASH CLOTHING BEFORE REUSE. WORKERS SHOULD TAKE
|
||||
HOT SHOWERS AFTER WORK IS FINISHED.
|
||||
Suppl. Safety & Health Data: CARCIN: CARCINOGENS, 1992: KNOWN TO BE
|
||||
CARCINOGENIC.
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Report for NIIN: 00N012831
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 19AUG93
|
||||
Label Date: 05AUG93
|
||||
Label Status: M
|
||||
Common Name: BARIUM CHROMATE
|
||||
Chronic Hazard: YES
|
||||
Signal Word: DANGER!
|
||||
Acute Health Hazard-Severe: X
|
||||
Contact Hazard-Slight: X
|
||||
Report for NIIN: 00N012831
|
||||
Fire Hazard-None: X
|
||||
Reactivity Hazard-None: X
|
||||
Special Hazard Precautions: KEEP AWAY FROM COMBUSTIBLES. STORE IN A DRY
|
||||
AREA. ACUTE: IRRITATION OF SKIN, EYES AND MUCOUS MEMBRANES. AVOID BREATHING
|
||||
DUST. DO NOT INGEST. CHRONIC: BARIUM CHROMATE IS A CARCINOGEN. WORKERS MAY
|
||||
EXPERIENCE AN INCREASED INCIDENCE OF LUNG CANCER.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
194
textfiles.com/science/CHEMICALS/barium_nitrate.txt
Normal file
194
textfiles.com/science/CHEMICALS/barium_nitrate.txt
Normal file
@@ -0,0 +1,194 @@
|
||||
|
||||
MSDS - BARIUM NITRATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: BARIUM NITRATE
|
||||
FORMULA: BA(NO3)2
|
||||
FORMULA WT: 261.35
|
||||
CAS NO.: 10022-31-8
|
||||
NIOSH/RTECS NO.: CQ9625000
|
||||
COMMON SYNONYMS: BARIUM(II)NITRATE; BARIUM DINITRATE
|
||||
PRODUCT CODES: 1018
|
||||
EFFECTIVE: 10/11/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (LIFE)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 3 SEVERE (OXIDIZER)
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
EXCEPTIONAL HEALTH HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE
|
||||
MAY BE FATAL IF SWALLOWED
|
||||
KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. DO NOT
|
||||
STORE NEAR COMBUSTIBLE MATERIALS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING. IN CASE
|
||||
OF FIRE, SOAK WITH WATER. IN CASE OF SPILL, SWEEP UP AND REMOVE. FLUSH SPILL
|
||||
AREA WITH WATER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
BARIUM NITRATE 90-100 10022-31-8
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 592 C ( 1098 F) VAPOR DENSITY(AIR=1): 9.0
|
||||
|
||||
SPECIFIC GRAVITY: 3.24 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: CRYSTALS OR CRYSTALLINE POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 0-0-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
NITROGEN OXIDES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.5 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 355
|
||||
LD50 (IV-MOUSE) (MG/KG) - 8.5
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CHRONIC EFFECTS OF BARIUM COMPOUNDS MAY INCLUDE BRONCHIAL IRRITATION,
|
||||
DEGENERATION OF CENTRAL NERVOUS SYSTEM, AND DAMAGE TO SPLEEN,
|
||||
LIVER, AND BONE MARROW.
|
||||
DUST MAY IRRITATE NOSE AND THROAT.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: COMBUSTIBLE MATERIALS, STRONG REDUCING AGENTS
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D003 (REACTIVE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A DUST/MIST RESPIRATOR IS
|
||||
RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF
|
||||
RESPIRATOR, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, BUTYL RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
|
||||
AND COMBUSTIBLE MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME BARIUM NITRATE
|
||||
HAZARD CLASS OXIDIZER
|
||||
UN/NA UN1446
|
||||
LABELS OXIDIZER
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME BARIUM NITRATE
|
||||
HAZARD CLASS 5.1, 6.1
|
||||
UN/NA UN1446
|
||||
LABELS OXIDIZING AGENT, POISON
|
||||
|
||||
166
textfiles.com/science/CHEMICALS/barium_sulfate.txt
Normal file
166
textfiles.com/science/CHEMICALS/barium_sulfate.txt
Normal file
@@ -0,0 +1,166 @@
|
||||
|
||||
MSDS - BARIUM SULFATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: BARIUM SULFATE
|
||||
FORMULA: BASO4
|
||||
FORMULA WT: 233.40
|
||||
CAS NO.: 07727-43-7
|
||||
NIOSH/RTECS NO.: CR0600000
|
||||
COMMON SYNONYMS: BARITE
|
||||
PRODUCT CODES: 1030,1040
|
||||
EFFECTIVE: 03/11/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 0 NONE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1580 C ( 2876 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 4.25 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: HEAVY WHITE POWDER WITHOUT AN ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
SULFUR DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
NO EFFECTS OF OVEREXPOSURE WERE DOCUMENTED.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: ALUMINUM, PHOSPHORUS
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF SULFUR
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D005 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
241
textfiles.com/science/CHEMICALS/bentonite.txt
Normal file
241
textfiles.com/science/CHEMICALS/bentonite.txt
Normal file
@@ -0,0 +1,241 @@
|
||||
|
||||
MSDS - Bentonite clay
|
||||
|
||||
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
|
||||
|
||||
+------------+------------------------------------+---------+-----------+
|
||||
| CAS# | Chemical Name | % | EINECS# |
|
||||
|------------|------------------------------------|---------|-----------|
|
||||
| 1318-93-0|K-10 Bentonite clay | |unlisted |
|
||||
+------------+------------------------------------+---------+-----------+
|
||||
|
||||
**** SECTION 3 - HAZARDS IDENTIFICATION ****
|
||||
|
||||
EMERGENCY OVERVIEW
|
||||
Appearance: not available.
|
||||
|
||||
|
||||
|
||||
Target Organs: None.
|
||||
|
||||
Potential Health Effects
|
||||
The toxicological properties of this material have not been
|
||||
investigated. Use appropriate procedures to prevent opportunities
|
||||
for direct contact with the skin or eyes and to prevent inhalation.
|
||||
|
||||
**** SECTION 4 - FIRST AID MEASURES ****
|
||||
|
||||
Eyes:
|
||||
Immediately flush eyes with plenty of water for at least 15 minutes,
|
||||
occasionally lifting the upper and lower lids.
|
||||
Skin:
|
||||
Flush skin with plenty of soap and water for at least 15 minutes
|
||||
while removing contaminated clothing and shoes.
|
||||
Ingestion:
|
||||
DO NOT induce vomiting. Allow the victim to rinse his mouth and then
|
||||
to drink 2-4 cupfuls of water, and seek medical advice.
|
||||
Inhalation:
|
||||
Remove from exposure to fresh air immediately.
|
||||
Notes to Physician:
|
||||
Treat symptomatically.
|
||||
No specific antidote exists.
|
||||
|
||||
**** SECTION 5 - FIRE FIGHTING MEASURES ****
|
||||
|
||||
General Information:
|
||||
As in any fire, wear a self-contained breathing apparatus in
|
||||
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
|
||||
protective gear. During a fire, irritating and highly toxic gases
|
||||
may be generated by thermal decomposition or combustion.
|
||||
Extinguishing Media:
|
||||
Use agent most appropriate to extinguish fire.
|
||||
Autoignition Temperature: Not available.
|
||||
Flash Point: Not available.
|
||||
NFPA Rating: Not published.
|
||||
Explosion Limits, Lower: Not available.
|
||||
Upper: Not available.
|
||||
|
||||
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
|
||||
|
||||
General Information: Use proper personal protective equipment as indicated
|
||||
in Section 8.
|
||||
Spills/Leaks:
|
||||
Clean up spills immediately, observing precautions in the Protective
|
||||
Equipment section. Sweep up, then place into a suitable container for
|
||||
disposal.
|
||||
|
||||
**** SECTION 7 - HANDLING and STORAGE ****
|
||||
|
||||
Handling:
|
||||
Wash thoroughly after handling. Remove contaminated clothing and
|
||||
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
|
||||
ingestion and inhalation.
|
||||
Storage:
|
||||
Store in a cool, dry place. Keep container closed when not in use.
|
||||
|
||||
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
|
||||
|
||||
Engineering Controls:
|
||||
Use adequate general or local exhaust ventilation to keep airborne
|
||||
concentrations below the permissible exposure limits. Use process
|
||||
enclosure, local exhaust ventilation, or other engineering controls
|
||||
to control airborne levels.
|
||||
|
||||
Exposure Limits
|
||||
+--------------------+-------------------+-------------------+-----------------+
|
||||
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|
||||
|--------------------|-------------------|-------------------|-----------------|
|
||||
| K-10 Bentonite clay|none listed |none listed |none listed |
|
||||
+--------------------+-------------------+-------------------+-----------------+
|
||||
|
||||
OSHA Vacated PELs:
|
||||
K-10 Bentonite clay:
|
||||
No OSHA Vacated PELs are listed for this chemical.
|
||||
|
||||
Personal Protective Equipment
|
||||
|
||||
Eyes:
|
||||
Wear safety glasses and chemical goggles if splashing
|
||||
is possible.
|
||||
Skin:
|
||||
Wear appropriate protective gloves and clothing to
|
||||
prevent skin exposure.
|
||||
Clothing:
|
||||
Wear appropriate protective clothing to minimize
|
||||
contact with skin.
|
||||
Respirators:
|
||||
Wear a NIOSH/MSHA-approved (or equivalent)
|
||||
full-facepiece airline respirator in the positive
|
||||
pressure mode with emergency escape provisions.
|
||||
|
||||
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
|
||||
|
||||
Physical State: Not available.
|
||||
Appearance: Not available.
|
||||
Odor: None reported.
|
||||
pH: Not available.
|
||||
Vapor Pressure: Not available.
|
||||
Vapor Density: Not available.
|
||||
Evaporation Rate: Not available.
|
||||
Viscosity: Not available.
|
||||
Boiling Point: Not available.
|
||||
Freezing/Melting Point: Not available.
|
||||
Decomposition Temperature: Not available.
|
||||
Solubility: Not available.
|
||||
Specific Gravity/Density: Not available.
|
||||
Molecular Formula: Not available.
|
||||
Molecular Weight: Not available.
|
||||
|
||||
**** SECTION 10 - STABILITY AND REACTIVITY ****
|
||||
|
||||
Chemical Stability:
|
||||
Stable under normal temperatures and pressures.
|
||||
Conditions to Avoid:
|
||||
Incompatible materials, strong oxidants.
|
||||
Incompatibilities with Other Materials:
|
||||
Not available.
|
||||
Hazardous Decomposition Products:
|
||||
Irritating and toxic fumes and gases.
|
||||
Hazardous Polymerization: Has not been reported.
|
||||
|
||||
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
|
||||
|
||||
RTECS#:
|
||||
CAS# 1318-93-0 unlisted.
|
||||
LD50/LC50:
|
||||
Not available.
|
||||
Carcinogenicity:
|
||||
K-10 Bentonite clay -
|
||||
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
|
||||
|
||||
**** SECTION 12 - ECOLOGICAL INFORMATION ****
|
||||
|
||||
Ecotoxicity:
|
||||
Not available.
|
||||
|
||||
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
|
||||
|
||||
Dispose of in a manner consistent with federal, state, and local regulations.
|
||||
RCRA D-Series Maximum Concentration of Contaminants: Not listed.
|
||||
RCRA D-Series Chronic Toxicity Reference Levels: Not listed.
|
||||
RCRA F-Series: Not listed.
|
||||
RCRA P-Series: Not listed.
|
||||
RCRA U-Series: Not listed.
|
||||
Not listed as a material banned from land disposal according to RCRA.
|
||||
|
||||
**** SECTION 14 - TRANSPORT INFORMATION ****
|
||||
|
||||
US DOT
|
||||
No information available
|
||||
IMO
|
||||
Not regulated as a hazardous material.
|
||||
IATA
|
||||
Not regulated as a hazardous material.
|
||||
RID/ADR
|
||||
Not regulated as a hazardous material.
|
||||
Canadian TDG
|
||||
No information available.
|
||||
|
||||
**** SECTION 15 - REGULATORY INFORMATION ****
|
||||
|
||||
A. Federal
|
||||
TSCA
|
||||
CAS# 1318-93-0 is not listed on the TSCA inventory.
|
||||
It is for research and development use only.
|
||||
Health & Safety Reporting List
|
||||
None of the chemicals are on the Health & Safety Reporting List.
|
||||
Chemical Test Rules
|
||||
None of the chemicals in this product are under a Chemical Test Rule.
|
||||
Section 12b
|
||||
None of the chemicals are listed under TSCA Section 12b.
|
||||
TSCA Significant New Use Rule
|
||||
None of the chemicals in this material have a SNUR under TSCA.
|
||||
CERCLA/SARA
|
||||
Section 302 (RQ)
|
||||
None of the chemicals in this material have an RQ.
|
||||
Section 302 (TPQ)
|
||||
None of the chemicals in this product have a TPQ.
|
||||
Section 313
|
||||
No chemicals are reportable under Section 313.
|
||||
Clean Air Act:
|
||||
This material does not contain any hazardous air pollutants.
|
||||
This material does not contain any Class 1 Ozone depletors.
|
||||
This material does not contain any Class 2 Ozone depletors.
|
||||
Clean Water Act:
|
||||
None of the chemicals in this product are listed as Hazardous
|
||||
Substances under the CWA.
|
||||
None of the chemicals in this product are listed as Priority
|
||||
Pollutants under the CWA.
|
||||
None of the chemicals in this product are listed as Toxic Pollutants
|
||||
under the CWA.
|
||||
OSHA:
|
||||
None of the chemicals in this product are considered highly hazardous
|
||||
by OSHA.
|
||||
B. State
|
||||
Not present on state lists from CA, PA, MN, MA, FL, or NJ.
|
||||
California No Significant Risk Level:
|
||||
None of the chemicals in this product are listed.
|
||||
C. International
|
||||
Canada
|
||||
None of the chemicals in this product are listed on the DSL/NDSL list.
|
||||
CAS# 1318-93-0 is not listed on Canada's Ingredient Disclosure List.
|
||||
European Labeling in Accordance with EC Directives
|
||||
Hazard Symbols: Not available.
|
||||
Risk Phrases:
|
||||
Safety Phrases:
|
||||
Exposure Limits:
|
||||
OEL-AUSTRALIA:TWA 50 ppm (150 mg/m3);Skin. OEL-AUSTRIA:TWA 100 ppm (30
|
||||
0 mg/m3). OEL-BELGIUM:STEL 50 ppm (152 mg/m3);Skin. OEL-CZECHOSLOVAKIA
|
||||
:TWA 100 mg/m3;STEL 200 mg/m3. OEL-DENMARK:STEL 50 ppm (150 mg/m3);Ski
|
||||
n. OEL-FINLAND:TWA 50 ppm (150 mg/m3);STEL 75 ppm (225 mg/m3);Skin. OE
|
||||
L-FRANCE:STEL 50 ppm (150 mg/m3). OEL-GERMANY:TWA 100 ppm (300 mg/m3)
|
||||
|
||||
150 mg/m3);Skin. OEL-JAPAN:STEL 50 ppm (150 mg/m3);Skin. OEL-THE NETHE
|
||||
RLANDS:TWA 50 ppm (150 mg/m3);Skin. OEL-THE PHILIPPINES:TWA 100 ppm (3
|
||||
00 mg/m3). OEL-RUSSIA:STEL 50 ppm (10 mg/m3). OEL-SWEDEN:TWA 15 ppm (4
|
||||
5 mg/m3);STEL 30 ppm (90 mg/m3);Skin. OEL-SWITZERLAND:TWA 50 ppm (150
|
||||
mg/m3);STEL 100 ppm;Skin. OEL-TURKEY:TWA 100 ppm (300 mg/m3). OEL-UNIT
|
||||
ED KINGDOM:TWA 50 ppm (150 mg/m3);STEL 50 ppm;Skin. OEL IN BULGARIA, C
|
||||
OLOMBIA, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE,
|
||||
VIETNAM check ACGI TLV
|
||||
|
||||
180
textfiles.com/science/CHEMICALS/benzoic_acid.txt
Normal file
180
textfiles.com/science/CHEMICALS/benzoic_acid.txt
Normal file
@@ -0,0 +1,180 @@
|
||||
|
||||
MSDS - Benzoic Acid
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: BENZOIC ACID
|
||||
FORMULA: C6H5COOH
|
||||
FORMULA WT: 122.12
|
||||
CAS NO.: 65-85-0
|
||||
NIOSH/RTECS NO.: DG0875000
|
||||
PRODUCT CODES: 5077,0080,0077,0076
|
||||
EFFECTIVE: 03/20/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY BE HARMFUL IF SWALLOWED
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 249 C ( 480 F) VAPOR PRESSURE(MM HG): <1
|
||||
|
||||
MELTING POINT: 122 C ( 252 F) VAPOR DENSITY(AIR=1): 4.2
|
||||
|
||||
SPECIFIC GRAVITY: 1.32 EVAPORATION RATE: <1
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): SLIGHT (0.1 TO 1 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE CRYSTALS WITH A FAINT, PLEASANT ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: 121 C ( 250 F) NFPA 704M RATING: 2-1-
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
(WATER MAY BE INEFFECTIVE.)
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 2350
|
||||
LD50 (ORAL-MOUSE)(MG/KG) - 2370
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 1460
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE OR BURN MUCOUS MEMBRANES.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION.
|
||||
INGESTION MAY CAUSE NAUSEA AND VOMITING.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, MOISTURE
|
||||
|
||||
INCOMPATIBLES: STRONG BASES, STRONG OXIDIZING AGENTS, ALKALIES
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME BENZOIC ACID
|
||||
HAZARD CLASS ORM-E
|
||||
UN/NA NA9094
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
148
textfiles.com/science/CHEMICALS/bht.txt
Normal file
148
textfiles.com/science/CHEMICALS/bht.txt
Normal file
@@ -0,0 +1,148 @@
|
||||
|
||||
MSDS - BHT
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: P-CRESOL, 2,6-DI-TERT-BUTYL-; (4-METHYL-2,6-DI-TERT-BUTYL-PHENOL)
|
||||
Ingredient Sequence Number: 01
|
||||
Percent: >99
|
||||
NIOSH (RTECS) Number: GO7875000
|
||||
CAS Number: 128-37-0
|
||||
OSHA PEL: 10 MG/M3 (MFR)
|
||||
ACGIH TLV: 10 MG/M3 (MFR)
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: WHITE GRANULAR, FAINT ODOR.
|
||||
Boiling Point: 509F,265C
|
||||
Melting Point: 157F,69C
|
||||
Vapor Pressure (MM Hg/70 F): N/A
|
||||
Vapor Density (Air=1): 7.6
|
||||
Specific Gravity: 0.899 (H*20=1)
|
||||
Evaporation Rate And Ref: NOT APPLICABLE
|
||||
Solubility In Water: INSOLUBLE
|
||||
Percent Volatiles By Volume: N/A
|
||||
Magnetism (Milligauss): N/P
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: >260F,>127C
|
||||
Flash Point Method: COC
|
||||
Lower Explosive Limit: N/A
|
||||
Upper Explosive Limit: N/A
|
||||
Extinguishing Media: FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER.
|
||||
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL
|
||||
PROTECTIVE EQUIPMENT (FP N). MOVE EXPOSED CONTAINERS FROM FIRE AREA IF
|
||||
POSS. USE WATER TO KEEP FIRE EXPOSED CNTNRS COOL.
|
||||
Unusual Fire And Expl Hazrds: CONTACT WITH STRONG OXIDIZERS MAY CAUSE
|
||||
FIRE. CLOSED CONTAINERS MAY EXPLODE DUE TO PRESSURE BUILDUP WHEN EXPOSED TO
|
||||
EXTREME HEAT.
|
||||
Report for NIIN: 00N033724
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): NOT APPLICABLE.
|
||||
Materials To Avoid: OXIDIZING AGENTS, STRONG ACIDS.
|
||||
Hazardous Decomp Products: CO*2, CO.
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): NOT RELEVANT
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: YES
|
||||
Health Haz Acute And Chronic: ACUTE: INHALATION: CAN CAUSE IRRITATION OF
|
||||
NASAL AND RESPIRATORY PASSAGES. EYES: CONTACT MAY CAUSE SEVERE IRRITATION
|
||||
OR BURNS. SKIN: PROLONGED CONTACT MAY CAUSE SKIN IRRITATION. INGESTION: IF
|
||||
LARGE QUANTITIES, MAY CAUSE DIARRHEA, RESPIRATORY DEPRESSION, TREMORS,
|
||||
CHRONIC PULMONARY EDEMA OR CONJECTION (EFTS OF OVEREXP)
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NOT RELEVANT
|
||||
Signs/Symptoms Of Overexp: HLTH HAZ: AND HEMORRAGE. CHRONIC: STUDIES
|
||||
INDICATE SOME EFFECT ON NEWBORN IN LABORATORY ANIMALS SO MATERIAL IS AN
|
||||
EXPERIMENTAL TERATOGEN. LIMITED ANIMAL EXPERIMENTS SUGGEST LIMITED
|
||||
TOXICITY.
|
||||
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
|
||||
Emergency/First Aid Proc: INHAL: REMOVE VICTIM FROM EXPOS, RESTORE BRTHG
|
||||
IF NEC, & CONT PHYS IMMED. EYE: FLUSH WITH COPIOUS AMTS OF H*2O FOR AT
|
||||
LEAST 15 MIN. CONT AN OPHTHALMOLOGIST/PHYS IMMED. SKIN: WASH AFFECTED AREA
|
||||
W/SOAP & H*2O FOR 15 MIN. IF IRRIT OCCURS CONT PHYS. INGEST: IF VICTIM IS
|
||||
CONSCIOUS, IMMED GIVE 2-4 GLASSES OF H*2O. INDUCE VOMIT BY TOUCHING FINGER
|
||||
TO BACK OF THROAT. CONT PHYS/POIS CNTRL CENTER IMMED.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: PROVIDE VENTILATION AND REMOVE ANY HEAT OR
|
||||
FLAME. SWEEP UP WITH A MINIMUM OF DUSTING OR VACUUM WITH A FILTERED OUTLET
|
||||
VACUUMING SYSTEM. PUT RESULTING WASTE INTO A REMOVABLE HEAD STEEL DRUM.
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: FOR DISPOSAL, CONTRACT WITH A LICENSED CHEMICAL
|
||||
WASTE DISPOSAL AGENCY. DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO
|
||||
FEDERAL, STATE, AND LOCAL REGULATIONS. DISPOSE OF IN ACCORDANCE WITH
|
||||
FEDERAL, STATE AND LOCAL REGULATIONS (FP N).
|
||||
Precautions-Handling/Storing: STORE IN COOL, DRY, WELL VENTILATED STORAGE
|
||||
AREA. DO NOT STORE NEAR OXIDIZING AGENTS OR STRONG ACIDS.
|
||||
Other Precautions: DO NOT STORE NEAR FOOD PRODUCTS. WASH HANDS THOROUGHLY
|
||||
BEFORE EATING, DRIKING, OR USING REST ROOM.
|
||||
Report for NIIN: 00N033724
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: NIOSH/MSHA APPROVED DUST/MIST/ORGANIC VAPOR
|
||||
RESPIRATOR IF CONCENTRATIONS EXCEED ACCEPTABLE LIMITS OR IRRITATION OCCURS.
|
||||
Ventilation: LOCAL EXHAUST RECOMMENDED.
|
||||
Protective Gloves: NEOPRENE OR RUBBER GLOVES.
|
||||
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
|
||||
Other Protective Equipment: SAFETY SHOWER, EYE WASH STATION.
|
||||
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
|
||||
Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER.
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 93040
|
||||
DOT PSN Code: ZZZ
|
||||
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
IMO PSN Code: ZZZ
|
||||
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
|
||||
IATA PSN Code: ZZZ
|
||||
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
AFI PSN Code: ZZZ
|
||||
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
Additional Trans Data: NOT REGULATED FOR TRANSPORTATION
|
||||
Report for NIIN: 00N033724
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 08SEP92
|
||||
Label Date: 20AUG92
|
||||
Label Status: M
|
||||
Common Name: CAO-3 BHT
|
||||
Chronic Hazard: YES
|
||||
Signal Word: WARNING!
|
||||
Acute Health Hazard-Slight: X
|
||||
Contact Hazard-Moderate: X
|
||||
Fire Hazard-Slight: X
|
||||
Reactivity Hazard-None: X
|
||||
Special Hazard Precautions: STORE IN COOL, DRY, WELL VENTILATED STORAGE
|
||||
CONTACT MAY CAUSE SEVERE IRRITATION OR BURNS. SKIN: PROLONGED CONTACT MAY
|
||||
Report for NIIN: 00N033724
|
||||
CAUSE SKIN IRRITATION. INGESTION: IF LARGE QUANTITIES, MAY CAUSE DIARRHEA,
|
||||
RESPIRATORY DEPRESSION, TREMORS, CHRONIC PULMONARY EDEMA OR CONJECTION AND
|
||||
HEMORRAGE. CHRONIC: STUDIES INDICATE SOME EFFECT ON NEWBORN IN LABORATORY
|
||||
ANIMALS SO MATERIAL IS AN EXPERIMENTAL TERATOGEN. LIMITED ANIMAL
|
||||
EXPERIMENTS SUGGEST LIMITED TOXICITY.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
182
textfiles.com/science/CHEMICALS/boric_acid.txt
Normal file
182
textfiles.com/science/CHEMICALS/boric_acid.txt
Normal file
@@ -0,0 +1,182 @@
|
||||
|
||||
MSDS - BORIC ACID
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: BORIC ACID
|
||||
FORMULA: H3BO3
|
||||
FORMULA WT: 61.83
|
||||
CAS NO.: 10043-35-3
|
||||
NIOSH/RTECS NO.: ED4550000
|
||||
COMMON SYNONYMS: BORACIC ACID; ORTHOBORIC ACID; BOROFAX
|
||||
PRODUCT CODES: 0084,5168,0090,0091,9820
|
||||
EFFECTIVE: 10/03/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 2 MODERATE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF SWALLOWED OR ABSORBED THROUGH SKIN
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
BORIC ACID 90-100 10043-35-3
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): 15
|
||||
|
||||
MELTING POINT: 171 C ( 340 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 1.44 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: COLORLESS, ODORLESS SOLID.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
OXIDES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 2660
|
||||
LD50 (SCU-RAT)(MG/KG) - 1400
|
||||
LD50 (IV-RAT) (MG/KG) - 1330
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INGESTION IS HARMFUL AND MAY BE FATAL.
|
||||
DUST INHALATION MAY CAUSE TIGHTNESS AND PAIN IN CHEST, COUGHING, AND
|
||||
DIFFICULTY IN BREATHING.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
PROLONGED EXPOSURE MAY CAUSE DERMATITIS.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
DAMAGED SKIN
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INGESTION, INHALATION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE, HEAT
|
||||
|
||||
INCOMPATIBLES: POTASSIUM METAL, WATER, STRONG BASES
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, UNIFORM, RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
187
textfiles.com/science/CHEMICALS/calcium_carbide.txt
Normal file
187
textfiles.com/science/CHEMICALS/calcium_carbide.txt
Normal file
@@ -0,0 +1,187 @@
|
||||
|
||||
MSDS - CALCIUM CARBIDE, ANHYDROUS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CALCIUM CARBIDE, ANHYDROUS
|
||||
FORMULA: CAC2
|
||||
FORMULA WT: 64.10
|
||||
CAS NO.: 00075-20-7
|
||||
NIOSH/RTECS NO.: EV9400000
|
||||
PRODUCT CODES: E284
|
||||
EFFECTIVE: 10/22/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 4 EXTREME (FLAMMABLE)
|
||||
REACTIVITY - 3 SEVERE (WATER REACTIVE)
|
||||
CONTACT - 2 MODERATE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DANGER
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF INHALED
|
||||
CONTACT WITH WATER LIBERATES FLAMMABLE ACETYLENE GAS.
|
||||
KEEP FROM ANY POSSIBLE CONTACT WITH WATER. KEEP AWAY FROM HEAT, SPARKS,
|
||||
FLAME. AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
DO NOT USE WATER. USE DRY SAND, EARTH OR SODA ASH. IN CASE OF SPILL,
|
||||
SWEEP UP AND CAREFULLY REMOVE.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
CALCIUM CARBIDE, ANHYDROUS 90-100 75-20-7
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 2300 C ( 4172 F) VAPOR DENSITY(AIR=1): 2.2
|
||||
|
||||
SPECIFIC GRAVITY: 2.22 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): DECOMPOSES % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: GRAYISH-BLACK SOLID WITH GARLIC-LIKE ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 1-4-2 W
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE DRY CHEMICAL OR CARBON DIOXIDE. DO NOT USE WATER.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL; DO NOT GET WATER INSIDE
|
||||
CONTAINERS.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
REACTS VIOLENTLY WITH WATER LIBERATING AND IGNITING HYDROGEN.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: UNSTABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE
|
||||
|
||||
INCOMPATIBLES: WATER, COMBUSTIBLE MATERIALS, STRONG OXIDIZING AGENTS,
|
||||
HYDROGEN CHLORIDE, MAGNESIUM
|
||||
|
||||
DECOMPOSITION PRODUCTS: PHOSPHINE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING, OR FLAMES IN AREA. DO NOT
|
||||
USE WATER.
|
||||
WITH CLEAN SHOVEL, PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER.
|
||||
MOVE CONTAINER(S) FROM SPILL AREA.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001, D003 (IGNITABLE, REACTIVE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, UNIFORM, RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
ISOLATE FROM INCOMPATIBLE MATERIALS.
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
|
||||
AWAY FROM HEAT, SPARKS, OR FLAME.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CALCIUM CARBIDE
|
||||
HAZARD CLASS FLAMMABLE SOLID
|
||||
UN/NA UN1402
|
||||
LABELS FLAMMABLE SOLID, DANGEROUS WHEN WET
|
||||
REPORTABLE QUANTITY 10 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CALCIUM CARBIDE
|
||||
HAZARD CLASS 4.3
|
||||
UN/NA UN1402
|
||||
LABELS DANGEROUS WHEN WET
|
||||
|
||||
176
textfiles.com/science/CHEMICALS/calcium_carbonate.txt
Normal file
176
textfiles.com/science/CHEMICALS/calcium_carbonate.txt
Normal file
@@ -0,0 +1,176 @@
|
||||
|
||||
MSDS - CALCIUM CARBONATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CALCIUM CARBONATE
|
||||
FORMULA: CACO3
|
||||
FORMULA WT: 100.09
|
||||
CAS NO.: 471-34-1
|
||||
NIOSH/RTECS NO.: EV9580000
|
||||
COMMON SYNONYMS: LIMESTONE; MARBLE; CALCITE; CHALK; CARBONIC ACID, CALCIUM
|
||||
SALT
|
||||
PRODUCT CODES: 5178,4485,5152,1294,1301,1300,4918,1288
|
||||
EFFECTIVE: 10/22/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 0 NONE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
MAY BE HARMFUL IF SWALLOWED
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
CALCIUM CARBONATE 90-100 471-34-1
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 825 C ( 1517 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.83 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: GRAY GRANULAR STONES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
OXIDES, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE NOSE AND THROAT.
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
CONTACT CAN CAUSE EYE IRRITATION.
|
||||
INGESTION MAY CAUSE GASTROINTESTINAL PAIN.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS, FLUORINE, ALUM, AMMONIUM SALTS
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: A RESPIRATOR WITH DUST/MIST FILTER IS RECOMMENDED.
|
||||
IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
160
textfiles.com/science/CHEMICALS/calcium_chloride.txt
Normal file
160
textfiles.com/science/CHEMICALS/calcium_chloride.txt
Normal file
@@ -0,0 +1,160 @@
|
||||
|
||||
MSDS - CALCIUM CHLORIDE, ANHYDROUS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CALCIUM CHLORIDE, ANHYDROUS
|
||||
FORMULA: CACL2
|
||||
FORMULA WT: 110.99
|
||||
CAS NO.: 10043-52-4
|
||||
NIOSH/RTECS NO.: EV9800000
|
||||
PRODUCT CODES: 1311
|
||||
EFFECTIVE: 09/26/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 2 MODERATE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
STORAGE: KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
CALCIUM CHLORIDE 90-100 10043-52-4
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 772 C ( 1422 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.15 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE GRANULES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 1000
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 280
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS.
|
||||
INGESTION MAY CAUSE NAUSEA AND VOMITING.
|
||||
DUST MAY IRRITATE NOSE AND THROAT.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE
|
||||
|
||||
INCOMPATIBLES: MOST COMMON METALS, WATER
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, UNIFORM, RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
179
textfiles.com/science/CHEMICALS/calcium_fluoride.txt
Normal file
179
textfiles.com/science/CHEMICALS/calcium_fluoride.txt
Normal file
@@ -0,0 +1,179 @@
|
||||
|
||||
MSDS - CALCIUM FLUORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CALCIUM FLUORIDE
|
||||
FORMULA: CAF2
|
||||
FORMULA WT: 78.08
|
||||
CAS NO.: 7789-75-5
|
||||
NIOSH/RTECS NO.: EW1760000
|
||||
COMMON SYNONYMS: FLUORITE; FLUORSPAR
|
||||
PRODUCT CODES: 1354
|
||||
EFFECTIVE: 09/02/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES IRRITATION
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
CALCIUM FLUORIDE 90-100 7789-75-5
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 2500 C ( 4532 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1403 C ( 2557 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 3.18 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: ODORLESS, WHITE POWDER OR CUBIC CRYSTALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN FLUORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 2.5 MG/M3 ( PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 2.5 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 4250
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 2775
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
INGESTION MAY CAUSE GASTROINTESTINAL PAIN.
|
||||
INGESTION IS HARMFUL AND MAY BE FATAL.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN, RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, KIDNEYS
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN FLUORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
169
textfiles.com/science/CHEMICALS/calcium_oxalate.txt
Normal file
169
textfiles.com/science/CHEMICALS/calcium_oxalate.txt
Normal file
@@ -0,0 +1,169 @@
|
||||
|
||||
MSDS - CALCIUM OXALATE
|
||||
|
||||
SECTION I. IDENTIFICATION
|
||||
|
||||
- Chemical Name: Calcium Oxalate
|
||||
- Synonym(s): Ethanedioic Acid Calcium Salt
|
||||
- Formula: C2CaO4.H2O
|
||||
===============================================================================
|
||||
|
||||
SECTION II. PRODUCT AND COMPONENT HAZARD DATA
|
||||
|
||||
A. Weight
|
||||
COMPONENT(S): Percent TLV(R) Accession No. CAS Reg. No.
|
||||
|
||||
Calcium Oxalate GT 98 --- 435753 5794-28-5
|
||||
|
||||
B. PRECAUTIONARY LABEL STATEMENT(S):
|
||||
|
||||
LOW HEALTH HAZARD FOR USUAL INDUSTRIAL HANDLING
|
||||
===============================================================================
|
||||
|
||||
SECTION III. PHYSICAL DATA
|
||||
|
||||
- Appearance and Odor: Colorless crystals; odorless
|
||||
- Melting Point: 200 C (392 F)
|
||||
- Vapor Pressure: Negligible
|
||||
- Evaporation Rate (n-butyl acetate = 1): Negligible
|
||||
- Vapor Density (Air = 1): Not Applicable
|
||||
- Volatile Fraction by Weight: Negligible
|
||||
- Specific Gravity (H2O = 1): 2.2
|
||||
- Solubility in Water (by Weight): Negligible
|
||||
===============================================================================
|
||||
|
||||
SECTION IV. FIRE AND EXPLOSION HAZARD DATA
|
||||
|
||||
- Extinguishing Media: Water spray; Dry chemical; CO2
|
||||
- Special Fire Fighting Procedures: None known
|
||||
- Unusual Fire and Explosion Hazards: None known
|
||||
===============================================================================
|
||||
|
||||
SECTION V. REACTIVITY DATA
|
||||
|
||||
- Stability: Stable
|
||||
- Incompatibility: Strong oxidizers
|
||||
- Hazardous Decomposition Products:
|
||||
As with any other organic material, combustion will produce
|
||||
carbon dioxide and probably carbon monoxide.
|
||||
- Hazardous Polymerization: Will not occur.
|
||||
===============================================================================
|
||||
|
||||
SECTION VI. TOXICITY AND HEALTH HAZARD DATA
|
||||
|
||||
A. EXPOSURE LIMITS: Not established
|
||||
|
||||
B. EXPOSURE EFFECTS:
|
||||
|
||||
Inhalation: Low hazard for usual industrial handling.
|
||||
|
||||
Eyes: No specific hazard known.
|
||||
However, any material that contacts the eye may be
|
||||
irritating.
|
||||
|
||||
Skin: Low hazard for usual industrial handling.
|
||||
|
||||
C. FIRST AID:
|
||||
|
||||
Eyes: Immediately flush eyes with plenty of water.
|
||||
|
||||
Skin: Flush skin with plenty of water.
|
||||
|
||||
D. TOXICITY DATA
|
||||
|
||||
Eye Irritation: Calcium oxalate is a very inert insoluble solid
|
||||
having no injurious effect on contact with the eye.(1)
|
||||
|
||||
Other: The mean lethal oral dose for an adult is felt to be from 15
|
||||
- 30 g, with death resulting from acute kidney failure within a few
|
||||
hours.(2)
|
||||
===============================================================================
|
||||
|
||||
SECTION VII. VENTILATION AND PERSONAL PROTECTION
|
||||
|
||||
A. VENTILATION:
|
||||
|
||||
Good general ventilation should be sufficient.
|
||||
|
||||
B. SKIN AND EYE PROTECTION:
|
||||
|
||||
Safety glasses should be worn in any type of industrial
|
||||
chemical handling.
|
||||
===============================================================================
|
||||
|
||||
SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS
|
||||
|
||||
Keep from contact with oxidizing materials.
|
||||
===============================================================================
|
||||
|
||||
SECTION IX. SPILL, LEAK, AND DISPOSAL PROCEDURES
|
||||
|
||||
Sweep material onto paper and place in fiber carton.
|
||||
Package appropriately for safe feed to an incinerator or
|
||||
dissolve in compatible waste solvents prior to incineration.
|
||||
Dispose by incineration or contract with licensed chemical
|
||||
waste disposal agency.
|
||||
Discharge, treatment, or disposal may be subject to federal,
|
||||
state, or local laws.
|
||||
===============================================================================
|
||||
|
||||
SECTION X. ENVIRONMENTAL EFFECTS DATA
|
||||
|
||||
A. SUMMARY:
|
||||
This chemical has not been tested for environmental effects.
|
||||
Some published data are available for oxalic acid and oxalate
|
||||
anion, and these data have been used to provide the following
|
||||
estimate of environmental impact:
|
||||
|
||||
This chemical has a moderate biological oxygen demand and it
|
||||
may cause oxygen depletion in aquatic systems. It is expected
|
||||
to have a low potential to affect aquatic organisms. The
|
||||
organic portion of this chemical is readily biodegradable and
|
||||
is not likely to bioconcentrate. When diluted with water, this
|
||||
chemical released directly or indirectly into the environment
|
||||
is not expected to have a significant impact.
|
||||
|
||||
Calcium oxalate is practically insoluble in water and acetic
|
||||
acid.6,7 The data below are for oxalic acid and/or sodium
|
||||
oxalate.
|
||||
B. OXYGEN DEMAND DATA: (Oxalic acid)(3)
|
||||
ThOD: 1.8 g/g
|
||||
COD: 0.18 g/g
|
||||
BOD5: 0.14 g/g
|
||||
BOD20: 0.16 g/g
|
||||
C. ACUTE AQUATIC EFFECTS:
|
||||
Goldfish; Period of survival: 0.4 - 0.5 hr, 1000 ppm (pH 2.6);
|
||||
4 days, 200 ppm (pH 5.3)(3)
|
||||
96-hour LC50; Mosquito Fish: 1350 mg/L (Sodium oxalate)(5)
|
||||
96-hour LCo; Water flea: 95 mg/L (Oxalic acid)(4)
|
||||
48-hour Immobilization; Water Flea: 214 mg/L (sodium oxalate)
|
||||
===============================================================================
|
||||
|
||||
SECTION XII. REFERENCES
|
||||
|
||||
1. Grant, W. M. Toxicology of the Eye, Charles C. Thomas, Publ.
|
||||
Springfield, Ill. 974.
|
||||
|
||||
2. Gosselin, R. E., et. al., Clinical Toxicology of Commercial
|
||||
Products, 4th, 1976.
|
||||
|
||||
3. Verschueren, K., Handbook of Environmental Data on Organic
|
||||
Chemicals, Second Edition, Van Nostrand Reinhold Company, New
|
||||
York, N.Y., 1983.
|
||||
|
||||
4. Battelle's Columbus Laboratories, Water Quality Critical Data
|
||||
Book - Vol. 3 - Effects of Chemicals on Aquatic Life - Selected
|
||||
Data from the Literature Through 1968, for the U.S.
|
||||
Environmental Protection Agency, Project No. 18050 GWV,
|
||||
Contract No. 68-01-0007, May 1971.
|
||||
|
||||
5. McKee, J.E. and Wolf, H.W., Eds., "Water Quality Criteria,"
|
||||
State of California, Publication No. 3-A, 1963.
|
||||
|
||||
6. Weast, R.C. "Handbook of Chemistry and Physics", CRC Press Ed.
|
||||
CRC Handbook, Boca Raton, FL, 1981-2.
|
||||
|
||||
7. Windholz, M. "The Merck Index - Ninth Edition" Merck and Co.,
|
||||
Ruhway NJ, 1976.
|
||||
|
||||
|
||||
195
textfiles.com/science/CHEMICALS/calcium_phosphide.txt
Normal file
195
textfiles.com/science/CHEMICALS/calcium_phosphide.txt
Normal file
@@ -0,0 +1,195 @@
|
||||
|
||||
Common Name: CALCIUM PHOSPHIDE
|
||||
|
||||
CAS Number: 1305-99-3
|
||||
DOT Number: UN 1360
|
||||
------------------------------------------------------------
|
||||
Substance number: 0329
|
||||
Date: 8/1/87 Revision:
|
||||
------------------------------------------------------------
|
||||
HAZARD SUMMARY
|
||||
* Calcium Phosphide can affect you when breathed in.
|
||||
* Phosphine gas is a highly toxic gas released when Calcium
|
||||
Phosphide is wet or has contacted moisture. Consult the NJ DOH
|
||||
Hazardous Substance Fact Sheet on Phosphine. * Calcium Phosphide
|
||||
is a DANGEROUS FIRE and EXPLOSION HAZARD.
|
||||
|
||||
|
||||
IDENTIFICATION
|
||||
Calcium Phosphide is a reddish-brown crystalline (sugar or sand-
|
||||
like) or a grey granular solid. It is used to kill rodents and
|
||||
in explosives and fireworks.
|
||||
|
||||
REASON FOR CITATION
|
||||
* Calcium Phosphide is on the Hazardous Substance List because it
|
||||
is cited by DOT.
|
||||
|
||||
|
||||
HOW TO DETERMINE IF YOU ARE BEING EXPOSED
|
||||
* Exposure to hazardous substances should be routinely evaluated.
|
||||
This may include collecting personal and area air samples. You
|
||||
can obtain copies of sampling results from your employer. You
|
||||
have a legal right to this information under OSHA 1910.20. * If
|
||||
you think you are experiencing any work-related health problems,
|
||||
see a doctor trained to recognize occupational diseases. Take
|
||||
this Fact Sheet with you.
|
||||
|
||||
|
||||
WORKPLACE EXPOSURE LIMITS
|
||||
No occupational exposure limits have been established for Calcium
|
||||
Phosphide. This does not mean that this substance is not
|
||||
harmful. Safe work practices should always be followed.
|
||||
|
||||
|
||||
WAYS OF REDUCING EXPOSURE
|
||||
* Where possible, enclose operations and use local exhaust
|
||||
ventilation at the site of chemical release. If local exhaust
|
||||
ventilation or enclosure is not used, respirators should be worn.
|
||||
* Wear protective work clothing.
|
||||
* Dry brush or vacuum material thoroughly from skin immediately
|
||||
after exposure to Calcium Phosphide and follow with large amounts
|
||||
of water. * Post hazard and warning information in the work area.
|
||||
In addition, as part of an ongoing education and training effort,
|
||||
communicate all information on the health and safety hazards of
|
||||
Calcium Phosphide to potentially exposed workers.
|
||||
|
||||
|
||||
HEALTH HAZARD INFORMATION
|
||||
|
||||
Acute Health Effects
|
||||
The following acute (short-term) health effects may occur
|
||||
immediately or shortly after exposure to Calcium Phosphide:
|
||||
|
||||
* Exposure to Calcium Phosphide that has contacted moisture can
|
||||
expose you to Phosphine gas which is highly toxic and dangerous.
|
||||
consult the NJ DOH Hazardous Substance Fact Sheet on phosphine.
|
||||
|
||||
Chronic Health Effects
|
||||
The following chronic (long-term) health effects can occur at
|
||||
some time after exposure to Calcium Phosphide and can last for
|
||||
months or years:
|
||||
|
||||
Cancer Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Calcium Phosphide has not been
|
||||
tested for its ability to cause cancer in animals.
|
||||
|
||||
Reproductive Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Calcium Phosphide has not been
|
||||
tested for its ability to adversely affect reproduction.
|
||||
|
||||
Other Long-Term Effects
|
||||
* No chronic (long-term) health effects are known at this time.
|
||||
|
||||
|
||||
MEDICAL
|
||||
|
||||
Medical Testing
|
||||
There is no special test for this chemical. However, if illness
|
||||
occurs or overexposure is suspected, medical attention is
|
||||
recommended.
|
||||
|
||||
Any evaluation should include a careful history of past and
|
||||
present symptoms with an exam. Medical tests that look for
|
||||
damage already done are not a substitute for controlling
|
||||
exposure.
|
||||
|
||||
Request copies of your medical testing. You have a legal right
|
||||
to this information under OSHA 1910.20.
|
||||
|
||||
|
||||
WORKPLACE CONTROLS AND PRACTICES
|
||||
|
||||
Unless a less toxic chemical can be substituted for a hazardous
|
||||
substance, ENGINEERING CONTROLS are the most effective way of
|
||||
reducing exposure. The best protection is to enclose operations
|
||||
and/or provide local exhaust ventilation at the site of chemical
|
||||
release. Isolating operations can also reduce exposure. Using
|
||||
respirators or protective equipment is less effective than the
|
||||
controls mentioned above, but is sometimes necessary.
|
||||
|
||||
In evaluating the controls present in your workplace, consider:
|
||||
(1) how hazardous the substance is, (2) how much of the substance
|
||||
is released into the workplace and (3) whether harmful skin or
|
||||
eye contact could occur. Special controls should be in place for
|
||||
highly toxic chemicals or when significant skin, eye, or
|
||||
breathing exposures are possible.
|
||||
|
||||
Good WORK PRACTICES can help to reduce hazardous exposures. The
|
||||
following work practices are recommended:
|
||||
|
||||
* Workers whose clothing has been contaminated by Calcium
|
||||
Phosphide should change into clean clothing promptly. *
|
||||
Contaminated work clothes should be laundered by individuals who
|
||||
have been informed of the hazards of exposure to Calcium
|
||||
Phosphide. * On skin contact with Calcium Phosphide, immediately
|
||||
wash or shower to remove the chemical. At the end of the
|
||||
workshift, wash any areas of the body that may have contacted
|
||||
Calcium Phosphide, whether or not known skin contact has
|
||||
occurred. * Do not eat, smoke, or drink where Calcium Phosphide
|
||||
is handled, processed, or stored, since the chemical can be
|
||||
swallowed. Wash hands carefully before eating or smoking. * Use
|
||||
a vacuum to reduce dust during clean-up. Do not dry sweep.
|
||||
|
||||
FIRE HAZARDS
|
||||
|
||||
* Calcium Phosphide releases highly flammable Phosphine gas on
|
||||
contact with moisture. * DO NOT USE WATER OR FOAM EXTINGUISHERS.
|
||||
* Use dry chemical, soda ash, or lime extinguishers.
|
||||
* If employees are expected to fight fires, they must be trained
|
||||
and equipped as stated in OSHA 1910.156.
|
||||
|
||||
|
||||
SPILLS AND EMERGENCIES
|
||||
|
||||
If Calcium Phosphide is spilled, take the following steps:
|
||||
|
||||
* Restrict persons not wearing protective equipment from area of
|
||||
spill until clean-up is complete. * Remove all ignition sources.
|
||||
* Ventilate area of spill.
|
||||
* Collect powdered material in the most convenient and safe
|
||||
manner and deposit in sealed containers. * It may be necessary to
|
||||
contain and dispose of Calcium Phosphide as a HAZARDOUS WASTE.
|
||||
Contact your state Department of Environmental Protection (DEP)
|
||||
or your regional office of the federal Environmental Protection
|
||||
Agency (EPA) for specific recommendations.
|
||||
|
||||
|
||||
HANDLING AND STORAGE
|
||||
|
||||
* Prior to working with Calcium Phosphide you should be trained
|
||||
on its proper handling and storage. * Store in tightly closed
|
||||
containers in a cool, well-ventilated area away from STRONG
|
||||
OXIDIZERS (such as CHLORINE, BROMINE and FLUORINE), STRONG ACIDS
|
||||
(such as HYDROCHLORIC, SULFURIC and NITRIC), OXYGEN, SULFUR or
|
||||
MOISTURE since violent reactions occur. * Sources of ignition,
|
||||
such as smoking and open flames, are prohibited where Calcium
|
||||
Phosphide is handled, used, or stored. * Use only nonsparking
|
||||
tools and equipment, especially when opening and closing
|
||||
containers of Calcium Phosphide. * Wherever Calcium Phosphide is
|
||||
used, handled, manufactured, or stored, use explosion-proof
|
||||
electrical equipment and fittings. * Do not store large amounts
|
||||
of this material in a room protected by WATER sprinkler systems.
|
||||
* Protect containers against physical damage.
|
||||
|
||||
|
||||
FIRST AID
|
||||
|
||||
Eye Contact
|
||||
* Immediately flush with large amounts of water, after quickly
|
||||
wiping excess Calcium Phosphide from face with dry cloth.
|
||||
Continue without stopping for at least 30 minutes, occasionally
|
||||
lifting upper and lower lids. Seek medical attention immediately.
|
||||
|
||||
Skin Contact
|
||||
* Remove contaminated clothing. Remove Calcium Phosphide from
|
||||
skin with a dry cloth. Wash with soap and water, rinsing with
|
||||
large amounts of water.
|
||||
|
||||
Breathing
|
||||
* Remove the person from exposure.
|
||||
* Begin rescue breathing if breathing has stopped and CPR if
|
||||
heart action has stopped. * Transfer promptly to a medical
|
||||
facility.
|
||||
|
||||
85
textfiles.com/science/CHEMICALS/calcium_resinate.txt
Normal file
85
textfiles.com/science/CHEMICALS/calcium_resinate.txt
Normal file
@@ -0,0 +1,85 @@
|
||||
|
||||
MSDS - CALCIUM RESINATE
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: CALCIUM RESINATE
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: EW3970000
|
||||
CAS Number: 9007-13-0
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: CADMIUM BROMIDE, TETRAHYDRATE
|
||||
Ingredient Sequence Number: 02
|
||||
Percent: 6MIN
|
||||
NIOSH (RTECS) Number: 1000288CB
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Magnetism (Milligauss): N/P
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point Method: N/P
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: N/P
|
||||
Hazardous Poly Occur: N/P
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
Route Of Entry - Inhalation: N/P
|
||||
Route Of Entry - Skin: N/P
|
||||
Route Of Entry - Ingestion: N/P
|
||||
Carcinogenicity - NTP: N/P
|
||||
Carcinogenicity - IARC: N/P
|
||||
Carcinogenicity - OSHA: N/P
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 79327
|
||||
DOT PSN Code: CRV
|
||||
DOT Proper Shipping Name: CALCIUM RESINATE
|
||||
DOT Class: 4.1
|
||||
DOT ID Number: UN1313
|
||||
DOT Pack Group: III
|
||||
DOT Label: FLAMMABLE SOLID
|
||||
IMO PSN Code: DLV
|
||||
IMO Proper Shipping Name: CALCIUM RESINATE
|
||||
IMO Regulations Page Number: 4132
|
||||
IMO UN Number: 1313
|
||||
IMO UN Class: 4.1
|
||||
IMO Subsidiary Risk Label: -
|
||||
IATA PSN Code: FAT
|
||||
IATA UN ID Number: 1313
|
||||
IATA Proper Shipping Name: CALCIUM RESINATE
|
||||
IATA UN Class: 4.1
|
||||
IATA Label: FLAMMABLE SOLID
|
||||
AFI PSN Code: FAT
|
||||
AFI Prop. Shipping Name: CALCIUM RESINATE
|
||||
AFI Class: 4.1
|
||||
AFI ID Number: UN1313
|
||||
AFI Pack Group: III
|
||||
AFI Label: FLAMMABLE SOLID
|
||||
AFI Special Prov: A1,A19
|
||||
AFI Basic Pac Ref: 8-7
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Label Status: G
|
||||
Common Name: MIL-C-20470,CALCIUM RESINATE
|
||||
Chronic Hazard: N/P
|
||||
|
||||
211
textfiles.com/science/CHEMICALS/calcium_silicide.txt
Normal file
211
textfiles.com/science/CHEMICALS/calcium_silicide.txt
Normal file
@@ -0,0 +1,211 @@
|
||||
ELKEM METALS -- CALCIUM-SILICON ALLOYS, HYPERCAL ALLOY
|
||||
MATERIAL SAFETY DATA SHEET
|
||||
FSC: 3439
|
||||
NIIN: 00N044298
|
||||
Manufacturer's CAGE: 1DS52
|
||||
Part No. Indicator: A
|
||||
Part Number/Trade Name: CALCIUM-SILICON ALLOYS, HYPERCAL ALLOY
|
||||
===========================================================================
|
||||
General Information
|
||||
===========================================================================
|
||||
Company's Name: ELKEM METALS CO *
|
||||
Company's P. O. Box: 1344 *
|
||||
Company's City: NIAGARA FALLS *
|
||||
Company's State: NY *
|
||||
Company's Country: US *
|
||||
Company's Zip Code: 14302 *
|
||||
Company's Emerg Ph #: 716-286-7548;800-424-9300(CHEMTREC) *
|
||||
Company's Info Ph #: 716-286-7548 *
|
||||
Safety Data Action Code: C
|
||||
Record No. For Safety Entry: 001
|
||||
Tot Safety Entries This Stk#: 001
|
||||
Status: SMJ *
|
||||
Date MSDS Prepared: 01DEC85 *
|
||||
Safety Data Review Date: 18OCT95 *
|
||||
MSDS Serial Number: BTLTX
|
||||
Hazard Characteristic Code: N1 *
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: CALCIUM
|
||||
Ingredient Sequence Number: 01
|
||||
Percent: 10-32
|
||||
NIOSH (RTECS) Number: EV8040000
|
||||
CAS Number: 7440-70-2
|
||||
OSHA PEL: N/K (FP N)
|
||||
ACGIH TLV: N/K (FP N)
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: SILICON
|
||||
Ingredient Sequence Number: 02
|
||||
Percent: 38-65
|
||||
NIOSH (RTECS) Number: VW0400000
|
||||
CAS Number: 7440-21-3
|
||||
OSHA PEL: 10 MG/M3 TDUST
|
||||
ACGIH TLV: 10 MG/M3 TDUST
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: BARIUM
|
||||
Ingredient Sequence Number: 03
|
||||
Percent: 0-18
|
||||
NIOSH (RTECS) Number: CQ8370000
|
||||
CAS Number: 7440-39-3
|
||||
OSHA PEL: 0.5 MG/M3
|
||||
ACGIH TLV: 0.5 MG/M3
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: ALUMINUM
|
||||
Ingredient Sequence Number: 04
|
||||
Percent: 1-21
|
||||
NIOSH (RTECS) Number: BD0330000
|
||||
CAS Number: 7429-90-5
|
||||
OSHA PEL: 15MG/M3 DUST;5 FUME
|
||||
ACGIH TLV: 10MG/M3 DUST
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: CHROMIUM
|
||||
Ingredient Sequence Number: 05
|
||||
Percent: <0.5
|
||||
NIOSH (RTECS) Number: GB4200000
|
||||
CAS Number: 7440-47-3
|
||||
OSHA PEL: 1 MG/M3
|
||||
ACGIH TLV: 0.5 MG/M3
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: NICKEL
|
||||
Ingredient Sequence Number: 06
|
||||
Percent: <0.5
|
||||
NIOSH (RTECS) Number: QR5950000
|
||||
CAS Number: 7440-02-0
|
||||
OSHA PEL: 1 MG/M3
|
||||
ACGIH TLV: 1 MG/M3
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: EXPLAN OF CARCIN: TO MAN, VOL 49, PG 257, 1990: GRP 2B. NTP
|
||||
6TH ANNUAL RPT ON CARCIN, 1991: ANTIC TO BE CARCIN.
|
||||
Ingredient Sequence Number: 07
|
||||
NIOSH (RTECS) Number: 9999999ZZ
|
||||
OSHA PEL: NOT APPLICABLE
|
||||
ACGIH TLV: NOT APPLICABLE
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: GREY METALLIC, ODORLESS *
|
||||
Boiling Point: N/K *
|
||||
Melting Point: SUPP DATA *
|
||||
Vapor Pressure (MM Hg/70 F): N/K *
|
||||
Vapor Density (Air=1): N/K *
|
||||
Specific Gravity: 2.0-2.5 *
|
||||
Decomposition Temperature: N/K *
|
||||
Evaporation Rate And Ref: N/K *
|
||||
Solubility In Water: INSOLUBLE *
|
||||
Percent Volatiles By Volume: N/K *
|
||||
pH: N/K *
|
||||
Corrosion Rate (IPY): N/K *
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: N/K *
|
||||
Flash Point Method: N/P *
|
||||
Lower Explosive Limit: N/K *
|
||||
Upper Explosive Limit: N/K *
|
||||
Extinguishing Media: CLASS D FIRES: USE DRY CHEM, DRY SAND/CARBON DIOXIDE
|
||||
TO SMOTHER FIRE. FIRE MAY ALSO BE ISOLATED & ALLOWED TO (SUPP DATA) *
|
||||
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL
|
||||
PROTECTIVE EQUIPMENT (FP N). *
|
||||
Unusual Fire And Expl Hazrds: BASED UPON COMBUSTIBILITY TESTS, FINE MATL
|
||||
IS CONSIDERED VERY ACTIVE. CONCS OF ALLOY DUST, WHEN SUSPENDED IN AIR, CAN
|
||||
BE IGNITED, PROPAGATE FLAME (SUPP DATA) *
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES *
|
||||
Cond To Avoid (Stability): PRLNGD CONT W/MOISTURE DURING STOR.VENT SHOULD
|
||||
BE SUPPLIED IN AREAS OF EXTENDED STOR.AVOID GENERATION OF AIRBORNE DUSTS. *
|
||||
Materials To Avoid: MOISTURE, ACIDS. *
|
||||
Hazardous Decomp Products: SM AMTS OF ARSINE, PHOSPHINE, & HYDROGEN MAY
|
||||
EVOLVE IF MOISTURE IS PRESENT. RXN W/ACIDS CAN PRDCE SILANES (SUPP DATA) *
|
||||
Hazardous Poly Occur: NO *
|
||||
Conditions To Avoid (Poly): NOT RELEVANT *
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Route Of Entry - Inhalation: YES *
|
||||
Route Of Entry - Skin: NO *
|
||||
Route Of Entry - Ingestion: NO *
|
||||
Health Haz Acute And Chronic: ACUTE: ALLOYS ARE OF LOW TOXICITY IN LUMP
|
||||
FORM AND NO RESIDUAL INJURY IS EXPECTED. HIGH CONCENTRATION OF METALLIC
|
||||
DUST MAY CAUSE SOME IRRITATION TO EYE, NOSE AND THROAT. CHRONIC: NO
|
||||
RESIDUAL INJURY IS EXPECTED. *
|
||||
Carcinogenicity - NTP: NO *
|
||||
Carcinogenicity - IARC: YES *
|
||||
Carcinogenicity - OSHA: NO *
|
||||
Explanation Carcinogenicity: CHROMIUM: IARC MONOGRAPHS, VOL 49, PG 49,
|
||||
1990:GRP 1. NTP 6TH ANNUAL RPT ON CARCINS, 1991: KNOWN TO BE CARCIN.
|
||||
(SUPDAT) *
|
||||
Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS. *
|
||||
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Emergency/First Aid Proc: INHAL: REMOVE FROM DUSTY AREA TO FRESH AIR.
|
||||
SKIN: NO HAZARD ASSOCIATED W/SKIN CONTACT. FLUSH WITH COPIOUS AMOUNTS OF
|
||||
WATER. CALL MD (FP N). EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES TO BE
|
||||
SURE THAT NO PARTICLES REMAIN IN EYE. INGEST: CALL MD IMMED (FP N). *
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: AVOID USING COMPRESSED AIR TO MANEUVER
|
||||
SPILLS/LEAKS OF FINE MATERIAL. FINE MATERIAL SHOULD BE SWEPT UP/VACUUMED.
|
||||
NO PROBLEM IS ASSOCIATED WITH SPILLS/LEAKS OF LUMP MATERIAL. KEEP WET
|
||||
MATERIAL SEPARATED FROM DRY MATERIAL. *
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Waste Disposal Method: AVOID REPACKING WET MATERIAL IN SEALED CONTAINERS.
|
||||
DISPOSE OF I/A/W APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. *
|
||||
Precautions-Handling/Storing: EXCLUDE CONT W/MOISTURE & ACIDS AS MUCH AS
|
||||
POSS. CALCIUM-SILICON ALLOYS SHOULD BE KEPT AWAY FROM SPARKS, HEAT & OPEN
|
||||
FLAMES IN A WELL VENTD AREA. *
|
||||
Other Precautions: MILLING: SPECIAL PREC, SUCH AS USE OF INERT ATMOSPHERE,
|
||||
SHOULD BE USED WHEN SIZING TO MINUS 8 MESH. MINIMIZE AND CONTROL DUSTY
|
||||
OPERATIONS. GRINDING WET MATL MAY BE HAZ DUE TO THE POSSIBILITY OF HYDROGEN
|
||||
EVOLUTION. *
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: IN DUSTY AREAS, USE NIOSH/MSHA APPROVED SCHEDULE
|
||||
21C RESPIRATOR. *
|
||||
Ventilation: LOCAL FOR DUSTY AREAS. PROVIDE VENTILATION DURING STORAGE OR
|
||||
HANDLING OF MOIST MATERIAL. *
|
||||
Protective Gloves: IMPERVIOUS GLOVES (FP N). *
|
||||
Eye Protection: ANSI APVD CHEMICAL SAFETY GOGGLES (FP N) *
|
||||
Other Protective Equipment: AS WITH OTHER METAL DUSTS AVOID CONTAMINATION
|
||||
OF WORK CLOTHING. *
|
||||
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. *
|
||||
Suppl. Safety & Health Data: MP:>1292F,>700C. EXTING MEDIA: BURN ITSELF
|
||||
OUT. DO NOT DISTURB METAL WHILE EXTING FIRE. EXPLO HAZ: READILY, GENERATE
|
||||
IARC MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEM (ING 7) *
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Label Status: G
|
||||
Common Name: CALCIUM-SILICON ALLOYS, HYPERCAL ALLOY
|
||||
Special Hazard Precautions: ACUTE: ALLOYS ARE OF LOW TOXICITY IN LUMP FORM
|
||||
AND NO RESIDUAL INJURY IS EXPECTED. HIGH CONCENTRATION OF METALLIC DUST MAY
|
||||
CAUSE SOME IRRITATION TO EYE, NOSE AND THROAT. CHRONIC: NO RESIDUAL INJURY
|
||||
IS EXPECTED. SEE HEALTH HAZARDS.
|
||||
Label Name: ELKEM METALS CO
|
||||
Label P.O. Box: 1344
|
||||
Label City: NIAGARA FALLS
|
||||
Label State: NY
|
||||
Label Zip Code: 14302
|
||||
Label Country: US
|
||||
Label Emergency Number: 716-286-7548;800-424-9300(CHEMTREC)
|
||||
=======================================================================
|
||||
URL for this msds http://hazard.com. If you wish to change, add to, or
|
||||
delete information in this archive please sent updates to dan@hazard.com.
|
||||
165
textfiles.com/science/CHEMICALS/calcium_sulfate.txt
Normal file
165
textfiles.com/science/CHEMICALS/calcium_sulfate.txt
Normal file
@@ -0,0 +1,165 @@
|
||||
|
||||
MSDS - CALCIUM SULFATE, ANHYDROUS, POWDER
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CALCIUM SULFATE, ANHYDROUS, POWDER
|
||||
FORMULA: CASO4
|
||||
FORMULA WT: 136.14
|
||||
CAS NO.: 07778-18-9
|
||||
COMMON SYNONYMS: ANHYDRITE; ANHYDROUS GYPSUM
|
||||
PRODUCT CODES: 1458
|
||||
EFFECTIVE: 05/22/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1450 C ( 2642 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.96 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): SLIGHT (0.1 TO 1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE ODORLESS GRANULES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
SULFUR DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS, ALUMINUM
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF SULFUR
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
192
textfiles.com/science/CHEMICALS/calomel.txt
Normal file
192
textfiles.com/science/CHEMICALS/calomel.txt
Normal file
@@ -0,0 +1,192 @@
|
||||
|
||||
MSDS - CALOMEL
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CALOMEL
|
||||
FORMULA: HGCL
|
||||
FORMULA WT: 236.04
|
||||
CAS NO.: 07546-30-7
|
||||
NIOSH/RTECS NO.: OV8750000
|
||||
COMMON SYNONYMS: MERCUROUS CHLORIDE, MERCURY MONOCHLORIDE
|
||||
PRODUCT CODES: 1363
|
||||
EFFECTIVE: 10/24/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (POISON)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 3 SEVERE (LIFE)
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
MAY BE FATAL IF SWALLOWED OR INHALED
|
||||
EXCEPTIONAL HEALTH AND CONTACT HAZARDS - READ MATERIAL SAFETY DATA SHEET
|
||||
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MERCUROUS CHLORIDE 90-100 7546-30-7
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 384 C ( 723 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 302 C ( 576 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 7.15 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE POWDER WITH NO ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN CHLORIDE, MERCURY FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.1 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 210
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY CAUSE HEADACHE, COUGHING, DIZZINESS OR DIFFICULT BREATHING.
|
||||
INHALATION AND INGESTION ARE HARMFUL AND MAY BE FATAL.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INGESTION MAY CAUSE NAUSEA AND VOMITING.
|
||||
CHRONIC EFFECTS OF MERCURY POISONING INCLUDE A BUILDUP OF THE
|
||||
METAL IN THE BRAIN, LIVER AND KIDNEYS. SYMPTOMS INCLUDE HEADACHE,
|
||||
TREMORS, LOOSE TEETH, LOSS OF APPETITE, BLISTERS ON THE SKIN AND
|
||||
IMPAIRED MEMORY.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INGESTION, INHALATION, ABSORPTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: LIGHT
|
||||
|
||||
INCOMPATIBLES: STRONG BASES, CARBONATES, SULFIDES, CYANIDES, ALKALIES,
|
||||
SULFITES, SULFATES, HYDROGEN PEROXIDE, AMMONIA,
|
||||
HYDROGEN BROMIDE, IODINE
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, MERCURY FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D009 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE APPROPRIATE VENTILATION
|
||||
CONDITIONS EXIST. IF THE TLV IS EXCEEDED, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
|
||||
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP PRODUCT OUT OF LIGHT.
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURY COMPOUNDS, SOLID, N.O.S. (CALOMEL)
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN2025
|
||||
LABELS POISON
|
||||
|
||||
161
textfiles.com/science/CHEMICALS/castor_oil.txt
Normal file
161
textfiles.com/science/CHEMICALS/castor_oil.txt
Normal file
@@ -0,0 +1,161 @@
|
||||
|
||||
MSDS - CASTOR OIL
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CASTOR OIL
|
||||
FORMULA:
|
||||
FORMULA WT: .00
|
||||
CAS NO.: 8001-79-4
|
||||
NIOSH/RTECS NO.: FI4100000
|
||||
COMMON SYNONYMS: RICINUS OIL
|
||||
PRODUCT CODES: 1518
|
||||
EFFECTIVE: 03/24/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 313 C ( 595 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: -10 C ( 14 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 0.96 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 100
|
||||
|
||||
APPEARANCE & ODOR: PALE YELLOW VISCOUS LIQUID.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: 235 C ( 455 F)
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT MAY CAUSE MODERATE EYE IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. TAKE UP WITH SAND OR OTHER NONCOM-
|
||||
BUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL.
|
||||
FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP VAPOR AND MIST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
218
textfiles.com/science/CHEMICALS/cetone.txt
Normal file
218
textfiles.com/science/CHEMICALS/cetone.txt
Normal file
@@ -0,0 +1,218 @@
|
||||
|
||||
MSDS - ACETONE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: ACETONE
|
||||
FORMULA: (CH3)2CO
|
||||
FORMULA WT: 58.08
|
||||
CAS NO.: 67-64-1
|
||||
NIOSH/RTECS NO.: AL3150000
|
||||
COMMON SYNONYMS: DIMETHYL KETONE; METHYL KETONE; 2-PROPANONE
|
||||
PRODUCT CODES: 9010,9006,9002,9254,9009,9001,9004,5356,A134,9007,9005,9005
|
||||
9008
|
||||
EFFECTIVE: 08/27/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 2 MODERATE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DANGER
|
||||
CAUSES IRRITATION
|
||||
EXTREMELY FLAMMABLE
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE.
|
||||
FLUSH SPILL AREA WITH WATER SPRAY.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
ACETONE 90-100 67-64-1
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 56 C ( 133 F) VAPOR PRESSURE(MM HG): 181
|
||||
|
||||
MELTING POINT: -95 C ( -139 F) VAPOR DENSITY(AIR=1): 2.0
|
||||
|
||||
SPECIFIC GRAVITY: 0.79 EVAPORATION RATE: ~10
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100
|
||||
|
||||
APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID WITH A FRAGRANT SWEET ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: -18 C ( 0 F) NFPA 704M RATING: 1-3-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 13.0 % LOWER - 2.6 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
(WATER MAY BE INEFFECTIVE.)
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK.
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG
|
||||
OXIDIZERS MAY CAUSE FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 1780 MG/M3 ( 750 PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 2375 MG/M3 ( 1000 PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 2400 MG/M3 ( 1000 PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 9750
|
||||
LD50 (ORAL-MOUSE)(MG/KG) - 3000
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 1297
|
||||
LD50 (SKN-RABBIT) (G/KG) - 20
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
VAPORS MAY BE IRRITATING TO SKIN, EYES, NOSE AND THROAT.
|
||||
INHALATION OF VAPORS MAY CAUSE NAUSEA, VOMITING, HEADACHE, OR LOSS OF
|
||||
CONSCIOUSNESS.
|
||||
LIQUID MAY CAUSE PERMANENT EYE DAMAGE.
|
||||
CONTACT WITH SKIN HAS A DEFATTING EFFECT, CAUSING DRYING AND IRRITATION.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
|
||||
|
||||
TARGET ORGANS
|
||||
RESPIRATORY SYSTEM, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: HALOGEN ACIDS AND HALOGEN COMPOUNDS, STRONG BASES,
|
||||
STRONG OXIDIZING AGENTS, CAUSTICS, AMINES AND AMMONIA,
|
||||
CHLORINE AND CHLORINE COMPOUNDS,
|
||||
STRONG ACIDS, ESP. SULFURIC, NITRIC, HYDROCHLORIC
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE
|
||||
WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE
|
||||
ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH
|
||||
AREA WITH WATER.
|
||||
|
||||
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED
|
||||
FOR SPILLS OF THIS PRODUCT.
|
||||
|
||||
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: U002 (TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 5000 PPM, A GAS MASK WITH ORGANIC VAPOR
|
||||
CANNISTER IS RECOMMENDED. ABOVE THIS LEVEL, A
|
||||
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE
|
||||
SHIELD IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, BUTYL RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. KEEP CONTAINER
|
||||
TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID
|
||||
STORAGE AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME ACETONE
|
||||
HAZARD CLASS FLAMMABLE LIQUID
|
||||
UN/NA UN1090
|
||||
LABELS FLAMMABLE LIQUID
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME ACETONE
|
||||
HAZARD CLASS 3.1
|
||||
UN/NA UN1090
|
||||
LABELS FLAMMABLE LIQUID
|
||||
|
||||
100
textfiles.com/science/CHEMICALS/charcoal.txt
Normal file
100
textfiles.com/science/CHEMICALS/charcoal.txt
Normal file
@@ -0,0 +1,100 @@
|
||||
|
||||
|
||||
|
||||
|
||||
M A T E R I A L S A F E T Y D A T A S H E E T
|
||||
CHARCOAL, WOOD
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: CHARCOAL, WOOD
|
||||
FORMULA: C
|
||||
FORMULA WT: 12.01
|
||||
CAS NO.:
|
||||
COMMON SYNONYMS: N/A
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: N/A VAPOR PRESSURE @ 20C (MM HG): NA
|
||||
MELTING POINT: 3500C VAPOR DENSITY (AIR=1): NA
|
||||
SPECIFIC GRAVITY: 3.51 EVAPORATION RATE: NA
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): INSOLUBLE PERCENT VOLATILES BY VOLUME: NA
|
||||
APPEARANCE & ODOR: BLACK, ODORLESS, AMORPHOUS POWDER, LUMPS OR STICKS
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: N/A
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
WATER SPRAY OR FOAM
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
WET MATERIAL MAY IGNITE SPONTANEOUSLY IN AIR
|
||||
UNUSUAL FIRE AND EXPLOSION HAZARDS
|
||||
DUST PARTICLES CAN FORM EXPLOSIVE MIXTURE WITH AIR
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): NONE ESTABLISHED
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION OF NASAL AND RESPIRATORY
|
||||
PASSAGES. CONTACT WITH SKIN AND EYES MAY CAUSE IRRITATION
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
SKIN: WASH WITH SOAP AND WATER
|
||||
EYES: FLUSH THOROUGHLY WITH WATER
|
||||
INHALATION: REMOVE TO FRESH AIR
|
||||
INGESTION: GET MEDICAL ASSISTANCE
|
||||
GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE
|
||||
CONDITIONS TO AVOID: AVOID CONTACT WITH OXIDIZING MATERIALS
|
||||
INCOMPATIBILES: OXIDIZERS, BF3
|
||||
DECOMPOSITION PRODUCTS: COX FROM COMBUSTION
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
PROVIDE ADEQUATE GENERAL MECHANICAL AND LOCAL EXHAUST VENTILATION
|
||||
DUST RESPIRATOR MAY BE REQUIRED
|
||||
PROTECT EYES AND SKIN WITH SAFETY GOGGLES AND GLOVES
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
AVOID WETTING AND SUBSEQUENT DRYING IN STORAGE
|
||||
DO NOT BREATHE DUST
|
||||
AVOID CONTACT WITH SKIN OR EYES
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
NONE
|
||||
REV. 9/85
|
||||
|
||||
--------------------------------------------------------------------------------
|
||||
(TM) and (R) : Registered Trademarks
|
||||
N/A = Not Applicable OR Not Available
|
||||
The information published in this Material Safety Data Sheet has been compiled
|
||||
from our experience and data presented in various technical publications. It is
|
||||
the user's responsibility to determine the suitability of this information for
|
||||
adoption of necessary safety precautions. We reserve the right to revise
|
||||
Material Safety Data Sheets periodically as new information becomes available.
|
||||
Copyright by Manufacturer
|
||||
LICENSE GRANTED TO MAKE UNLIMITED COPIES FOR INTERNAL USE ONLY
|
||||
by OREGON STATE UNIVERSITY
|
||||
.
|
||||
151
textfiles.com/science/CHEMICALS/chlorowax.txt
Normal file
151
textfiles.com/science/CHEMICALS/chlorowax.txt
Normal file
@@ -0,0 +1,151 @@
|
||||
DOVER CHEMICAL -- CHLOREZ, 700-DD
|
||||
MATERIAL SAFETY DATA SHEET
|
||||
NSN: 681000N017088
|
||||
Manufacturer's CAGE: 2R633
|
||||
Part No. Indicator: A
|
||||
Part Number/Trade Name: CHLOREZ, 700-DD
|
||||
===========================================================================
|
||||
General Information
|
||||
===========================================================================
|
||||
Company's Name: DOVER CHEMICAL COMPANY
|
||||
Company's Street: W 15TH & DAVIS STS
|
||||
Company's City: DOVER
|
||||
Company's State: OH
|
||||
Company's Country: US
|
||||
Company's Zip Code: 44622
|
||||
Company's Emerg Ph #: 216-343-7711
|
||||
Company's Info Ph #: 216-343-7711
|
||||
Record No. For Safety Entry: 001
|
||||
Tot Safety Entries This Stk#: 001
|
||||
Status: SMJ
|
||||
Date MSDS Prepared: 12FEB88
|
||||
Safety Data Review Date: 15MAY95
|
||||
MSDS Serial Number: BLBZV
|
||||
Hazard Characteristic Code: N1
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: PARAFFIN WAXES, AND HYDROCARBON WAXES, CHLORINATED
|
||||
(CHLORINATED PARAFFIN)
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: RV0450000
|
||||
CAS Number: 63449-39-8
|
||||
OSHA PEL: NOT APPLICABLE
|
||||
ACGIH TLV: NOT APPLICABLE
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: WHITE TO CREAM POWDER OR FLAKE-NO DISTINCT ODOR.
|
||||
Boiling Point: SUPP DATA
|
||||
Specific Gravity: 1.6 (25C)
|
||||
Solubility In Water: NIL
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: >392F,>200C
|
||||
Flash Point Method: COC
|
||||
Extinguishing Media: DRY CHEMICAL, FOAM OR WATER FOG.
|
||||
Special Fire Fighting Proc: PROTECT AGAINST DECOMPOSITION OF PRODUCT- WEAR
|
||||
NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT (FP
|
||||
N).
|
||||
Unusual Fire And Expl Hazrds: MATERIAL WILL BECOME MOLTEN AND FREE FLOWING
|
||||
AT TEMPERATURES ABOVE THE SOFTENING POINT. THERMAL DECOMPOSITION PRODUCTS
|
||||
MAY INCLUDE HCL AND/OR PHOSGENE.
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
|
||||
Materials To Avoid: AVOID STRONG OXIDIZING AND REDUCING AGENTS.
|
||||
Hazardous Decomp Products: HYDROCHLORIC ACID, CARBON MONOXIDE, HCL AND/ OR
|
||||
PHOSGENE (FP N).
|
||||
Conditions To Avoid (Poly): HEATING TO DECOMPOSITION.
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: LD50:(ORAL)>4 G/KG
|
||||
Route Of Entry - Inhalation: NO
|
||||
Route Of Entry - Skin: YES
|
||||
Route Of Entry - Ingestion: NO
|
||||
Health Haz Acute And Chronic: ACUTE:MILD SKIN IRRITATION. SUBCHRONIC
|
||||
TOXICITY-NO COMPOUND RELATED EFFECTS. TERATOLOGY-NO MATERNAL TOXICITY
|
||||
OBSERVED. CONSIDERED CLASTOGENIC. CHLOROCARBON/CHLOROFLUORINATED (CFC)
|
||||
MATERIAL HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN
|
||||
LABORATORY ANIMALS AND COULD HAVE A SIMILAR EFFECT(EFTS OF OVEREXP)
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NOT RELEVANT.
|
||||
Signs/Symptoms Of Overexp: HLTH HAZ:IN HUMANS. ADRENOMIMETRICS (I.E.
|
||||
EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAINING USES IN
|
||||
HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS OR CFC'S (FP N).
|
||||
IRRITATION OF SKIN.
|
||||
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
|
||||
Emergency/First Aid Proc: EYE:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT
|
||||
LEAST 15 MINUTES. SKIN:WASH WITH SOAP AND WATER. INHAL:REMOVE TO FRESH AIR.
|
||||
CALL MD. INGEST:CALL MD IMMEDIATELY.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: WEAR NIOSH/MSHA APPROVED PROTECTIVE
|
||||
EQUIPMENT, PREVENT MATERIAL FROM ENTERING WATERWAY, SHOVEL INTO RECLAIM OR
|
||||
DISPOSAL CONTAINER.
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: ACCORDING TO ALL LOCAL, STATE AND FEDERAL
|
||||
REGULATIONS.
|
||||
Precautions-Handling/Storing: NONE SPECIFIED BY MANUFACTURER.
|
||||
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
|
||||
VICINITY OF ARC WELDING, OPEN FLAMES, OR HOT SURFACES. HEAT AND/OR UV
|
||||
RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE (FP N).
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: NIOSH/MSHA APPROVED DUST MASK.
|
||||
Ventilation: MECHANICAL EXHAUST TO REMOVE DUST.
|
||||
Protective Gloves: IMPERVIOUS GLOVES.
|
||||
Eye Protection: CHEMICAL WORKERS GOGGLES W/FSHLD (FP N).
|
||||
Other Protective Equipment: LONG SLEEVE SHIRT AND TROUSERS, EYE WASH,
|
||||
SAFETY SHOWER.
|
||||
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
|
||||
Suppl. Safety & Health Data: BP:SOFTENS AT 95-110 C.
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 91302
|
||||
DOT PSN Code: ZZZ
|
||||
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
IMO PSN Code: ZZZ
|
||||
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
|
||||
IATA PSN Code: ZZZ
|
||||
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
AFI PSN Code: ZZZ
|
||||
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
Additional Trans Data: NOT REGULATED FOR TRANSPORTATION
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Label Status: G
|
||||
Common Name: CHLOREZ, 700-DD
|
||||
Special Hazard Precautions: ACUTE:MILD SKIN IRRITATION. SUBCHRONIC
|
||||
TOXICITY-NO COMPOUND RELATED EFFECTS. TERATOLOGY-NO MATERNAL TOXICITY
|
||||
OBSERVED. CONSIDERED CLASTOGENIC. CHLOROCARBON/CHLOROFLUORINATED (CFC)
|
||||
MATERIAL HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN
|
||||
LABORATORY ANIMALS AND COULD HAVE A SIMILAR EFFECT(EFTS OF OVEREXP)HLTH
|
||||
HAZ:IN HUMANS. ADRENOMIMETRICS (I.E. EPINEPHRINE) MAY BE CONTRA-INDICATED
|
||||
EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO
|
||||
CHLOROCARBONS OR CFC'S (FP N). IRRITATION OF SKIN.
|
||||
Label Name: DOVER CHEMICAL COMPANY
|
||||
Label Street: W 15TH & DAVIS STS
|
||||
Label City: DOVER
|
||||
Label State: OH
|
||||
Label Zip Code: 44622
|
||||
Label Country: US
|
||||
Label Emergency Number: 216-343-7711
|
||||
=======================================================================
|
||||
URL for this msds http://siri.org If you wish to change, add to, or
|
||||
delete information in this archive please send updates to dan@siri.org.
|
||||
133
textfiles.com/science/CHEMICALS/cmc.txt
Normal file
133
textfiles.com/science/CHEMICALS/cmc.txt
Normal file
@@ -0,0 +1,133 @@
|
||||
CMC
|
||||
MATERIAL SAFETY DATA SHEET
|
||||
NSN: 685000F039725
|
||||
Manufacturer's CAGE: 0BLY0
|
||||
Part No. Indicator: A
|
||||
Part Number/Trade Name: AQUALON CELLULOSE GUM
|
||||
===========================================================================
|
||||
General Information
|
||||
===========================================================================
|
||||
Company's Name: ACT COMMUNICATIONS INC
|
||||
Company's P. O. Box: 375
|
||||
Company's City: ECTOR
|
||||
Company's State: TX
|
||||
Company's Country: US
|
||||
Company's Zip Code: 75418
|
||||
Company's Emerg Ph #: 903-961-2300
|
||||
Company's Info Ph #: 903-961-2300
|
||||
Record No. For Safety Entry: 001
|
||||
Tot Safety Entries This Stk#: 001
|
||||
Status: SE
|
||||
Date MSDS Prepared: 27SEP91
|
||||
Safety Data Review Date: 04MAY95
|
||||
Preparer's Company: ACT COMMUNICATIONS INC
|
||||
Preparer's City: ECTOR
|
||||
Preparer's State: TX
|
||||
Preparer's Zip Code: 75418
|
||||
MSDS Serial Number: BWXMY
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: CARBOXYMETHYLCELLULOSE
|
||||
Ingredient Sequence Number: 01
|
||||
Percent: >99.5
|
||||
NIOSH (RTECS) Number: FJ5950000
|
||||
CAS Number: 9004-32-4
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: WHITE TO OFF WHITE GRANULAR POWDER W/NO ODOR.
|
||||
Specific Gravity: 1.59
|
||||
Solubility In Water: SLIGHT
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Extinguishing Media: WATER SPRAY, DRY CHEMICAL, FOAM, CO2, HALON
|
||||
Unusual Fire And Expl Hazrds: MAY FORM FLAMMABLE DUST-AIR MIXTURES.
|
||||
AUTOIGNITION TEMP 440F. STATIC CHARGES GENERATED BY EMPTYING PACKAGE IN/
|
||||
NEAR FLAMMABLE VAPORS MAY CAUSE FLASH FIRE.
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): SUNLIGHT, ULTRAVIOLET LIGHT, HEAT, IGNITION
|
||||
SOURCES
|
||||
Hazardous Decomp Products: CO, CO2, SMOKE
|
||||
Hazardous Poly Occur: NO
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
Route Of Entry - Inhalation: NO
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: NO
|
||||
RESPIRATORY IRRITATION. LAXATIVE EFFECT AFTER REPEATED ORAL INGESTION OF
|
||||
LARGE AMOUNTS (10 GRAMS). A SINGLE CASE OF ALLERGIC CONTACT DERMATITIS
|
||||
AFTER REPEATED LONG TERM (8 YRS.) SKIN CONTACT.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NONE
|
||||
Signs/Symptoms Of Overexp: IRRITATION
|
||||
Med Cond Aggravated By Exp: NONE
|
||||
Emergency/First Aid Proc: EYES: IMMEDIATELY FLUSH W/PLENTY OF LOW-
|
||||
PRESSURE WATER FOR 15 MINS. REMOVE ANY CONTACT LENSES TO ASSURE THOROUGH
|
||||
FLUSHING. INHALATION: REMOVE TO FRESH AIR. TREAT ANY IRRITATION
|
||||
SYMPTOMATICALLY. OBTAIN MEDICAL ATTENTION IN ALL CASES.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: SWEEP UP MATERIAL FOR USE/DISPOSAL. SURFACES
|
||||
SUBJECT TO/DUSTING W/THIS PRODUCT CAN BECOME SLIPPERY WHEN WET.
|
||||
Waste Disposal Method: INCINERATION OF WASTE MATERIAL IN A PERMITTED
|
||||
FACILITY IAW/FEDERAL, STATE & LOCAL REGULATIONS IS RECOMMENDED. LANDFILLING
|
||||
IN A LICENSED FACILITY EQUIPPED W/LEACHATE COLLECTION IS A SUITABLE
|
||||
ALTERNATIVE. THIS PRODUCT IS BIODEGRADABLE. (SEE SUPP)
|
||||
Precautions-Handling/Storing: AVOID IGNITION SOURCES. GROUND ALL
|
||||
EQUIPMENT. WHEN EMPTYING BAGS WHERE FLAMMABLE VAPORS MAY BE PRESENT,
|
||||
BLANKET VESSEL W/INERT GAS/GROUND OPERATOR.
|
||||
Other Precautions: POUR MATERIAL SLOWLY INTO CONDUCTIVE, GROUNDED CHUTE.
|
||||
AVOID CONTACT W/EYES, SKIN & CLOTHING. AVOID BREATHING DUST.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: APPROPRIATE RESPIRATORY PROTECTION IS REQUIRED
|
||||
WHEN EXPOSED TO AN AIRBORNE CONTAMINANT IS LIKELY TO EXCEED ACCEPTABLE
|
||||
LIMITS.
|
||||
Ventilation: ADEQUATE VENTILATION SHOULD BE PROVIDED TO KEEP DUST
|
||||
CONCENTRATIONS BELOW ACCEPTABLE EXPOSURE LIMITS.
|
||||
Protective Gloves: IMPERVIOUS
|
||||
Eye Protection: SAFETY GLASSES
|
||||
Other Protective Equipment: EYEWASH FOUNTAINS, SAFETY SHOWERS SHOULD BE
|
||||
EASILY ACCESSIBLE.
|
||||
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. KEEP AREA CLEAN.
|
||||
Suppl. Safety & Health Data: BROWNING TEMP: 440F. WASTE CONT'D: WASTEWATER
|
||||
CONTAINING THIS PRODUCT CAN BE CONSIDERED FOR TREATMENT IN AN ACCLIMATED
|
||||
BIOLOGICAL TREATMENT SYSTEM OF ADEQUATE CAPACITY.
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Label Status: G
|
||||
Common Name: AQUALON CELLULOSE GUM
|
||||
Special Hazard Precautions: EYES: MILD IRRITATION. INHALATION: RESPIRATORY
|
||||
IRRITATION. LAXATIVE EFFECT AFTER REPEATED ORAL INGESTION OF LARGE AMOUNTS
|
||||
(10 GRAMS). A SINGLE CASE OF ALLERGIC CONTACT DERMATITIS AFTER REPEATED
|
||||
LONG TERM (8 YRS.) SKIN CONTACT. IRRITATION
|
||||
Label Name: ACT COMMUNICATIONS INC
|
||||
Label P.O. Box: 375
|
||||
Label City: ECTOR
|
||||
Label State: TX
|
||||
Label Zip Code: 75418
|
||||
Label Country: US
|
||||
Label Emergency Number: 903-961-2300
|
||||
=======================================================================
|
||||
URL for this msds http://siri.org. If you wish to change, add to, or
|
||||
delete information in this archive please send updates to dan@siri.org.
|
||||
|
||||
179
textfiles.com/science/CHEMICALS/copper.txt
Normal file
179
textfiles.com/science/CHEMICALS/copper.txt
Normal file
@@ -0,0 +1,179 @@
|
||||
|
||||
MSDS - COPPER
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: COPPER
|
||||
FORMULA: CU
|
||||
FORMULA WT: 63.55
|
||||
CAS NO.: 07440-50-8
|
||||
NIOSH/RTECS NO.: GL5325000
|
||||
COMMON SYNONYMS: BRONZE POWDER; C.I. 77400; ARWOOD COPPER
|
||||
PRODUCT CODES: 1732,1736,1720,1714,1728
|
||||
EFFECTIVE: 06/25/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 0 NONE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
COPPER 90-100 07440-50-8
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 2595 C ( 4703 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1083 C ( 1981 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 8.92 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: REDDISH, LUSTROUS, MALLEABLE METAL.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
COPPER FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 1.0 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY CAUSE SNEEZING AND COUGHING.
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
PROLONGED EXPOSURE MAY CAUSE DERMATITIS.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
NOTE: PRODUCT IS A SOLID MASS; HOWEVER, WARNINGS ARE BASED ON INHALATION
|
||||
DUST, MIST OR FUME EMISSIONS THAT ARE POSSIBLE DURING MANUFACTURING OR
|
||||
CHEMICAL REACTIONS.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS, ACTIVE HALOGEN COMPOUNDS, CHLORINE,
|
||||
FLUORINE, IODINE, BROMINE, AMMONIA
|
||||
|
||||
DECOMPOSITION PRODUCTS: COPPER FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A DUST/MIST RESPIRATOR IS
|
||||
RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF
|
||||
RESPIRATOR, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME COPPER, HEAVY FOIL
|
||||
HAZARD CLASS ORM-E
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
104
textfiles.com/science/CHEMICALS/copper_carbonate.txt
Normal file
104
textfiles.com/science/CHEMICALS/copper_carbonate.txt
Normal file
@@ -0,0 +1,104 @@
|
||||
|
||||
MSDS - CUPRIC CARBONATE
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: CUPRIC CARBONATE
|
||||
FORMULA: MIXTURE CU(CO3) & CU(OH)2
|
||||
FORMULA WT: .00
|
||||
CAS NO.: 01184-64-1
|
||||
COMMON SYNONYMS: COPPER(II)CARBONATE; CUPRIC CARBONATE,BASIC; COPPER
|
||||
CARBONATE HYDROXIDE
|
||||
PRODUCT CODES: 5465,5007,5001,1786
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
HEALTH - 2
|
||||
FLAMMABILITY - 0
|
||||
REACTIVITY - 0
|
||||
CONTACT - 1
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
SAFETY GLASSES; LAB COAT
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
COMPONENT % CAS NO.
|
||||
CUPRIC CARBONATE 90-100 1184-64-1
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
SPECIFIC GRAVITY: 3.90 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
APPEARANCE & ODOR: ODORLESS, GREEN TO BLUE POWDER.
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: N/A
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 1 MG/M3 ( PPM)
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INGESTION MAY CAUSE NAUSEA AND VOMITING.
|
||||
INGESTION MAY CAUSE GASTROINTESTINAL PAIN.
|
||||
DUST MAY IRRITATE EYES.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
INCOMPATIBLES: STRONG ACIDS
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 6 PPM, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A
|
||||
SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
DOMESTIC (D.O.T.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
INTERNATIONAL (I.M.O.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
|
||||
109
textfiles.com/science/CHEMICALS/copper_i_chloride.txt
Normal file
109
textfiles.com/science/CHEMICALS/copper_i_chloride.txt
Normal file
@@ -0,0 +1,109 @@
|
||||
|
||||
MSDS - CUPROUS CHLORIDE
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: CUPROUS CHLORIDE
|
||||
FORMULA: CUCL
|
||||
FORMULA WT: 99.00
|
||||
CAS NO.: 07758-89-6
|
||||
NIOSH/RTECS NO.: GL6990000
|
||||
COMMON SYNONYMS: COPPER(I)CHLORIDE; COPPER MONOCHLORIDE
|
||||
PRODUCT CODES: 1862
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
HEALTH - 2
|
||||
FLAMMABILITY - 0
|
||||
REACTIVITY - 0
|
||||
CONTACT - 1
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
SAFETY GLASSES; LAB COAT
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
COMPONENT % CAS NO.
|
||||
CUPROUS CHLORIDE 90-100 7758-89-6
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: 1490 C ( 2714 F) VAPOR PRESSURE(MM HG): N/A
|
||||
MELTING POINT: 430 C ( 806 F) VAPOR DENSITY(AIR=1): N/A
|
||||
SPECIFIC GRAVITY: 3.53 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
APPEARANCE & ODOR: WHITE CRYSTALLINE POWDER OR CUBIC CRYSTALS.
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: N/A
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN CHLORIDE
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 1 MG/M3 ( PPM)
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 265
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
CONDITIONS TO AVOID: MOISTURE, LIGHT
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, POTASSIUM METAL, WATER
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 12 PPM, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A
|
||||
SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
DOMESTIC (D.O.T.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
INTERNATIONAL (I.M.O.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
|
||||
351
textfiles.com/science/CHEMICALS/copper_ii_chloride.txt
Normal file
351
textfiles.com/science/CHEMICALS/copper_ii_chloride.txt
Normal file
@@ -0,0 +1,351 @@
|
||||
|
||||
MSDS - Copper(II) chloride dihydrate
|
||||
Cupric chloride dihydrate
|
||||
|
||||
|
||||
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
|
||||
|
||||
+------------+------------------------------------+---------+-----------+
|
||||
| CAS# | Chemical Name | % | EINECS# |
|
||||
|------------|------------------------------------|---------|-----------|
|
||||
| 10125-13-0|Copper(II) chloride dihydrate, reage|99% |unlisted |
|
||||
nt (powder), 99% (Titr.)
|
||||
+------------+------------------------------------+---------+-----------+
|
||||
Hazard Symbols: XN T
|
||||
Risk Phrases: 22 25 36 36/37/38
|
||||
|
||||
**** SECTION 3 - HAZARDS IDENTIFICATION ****
|
||||
|
||||
EMERGENCY OVERVIEW
|
||||
Appearance: Not available.
|
||||
WARNING! MAY CAUSE ALLERGIC SKIN REACTION. HYGROSCOPIC. HARMFUL IF
|
||||
SWALLOWED. MAY CAUSE SEVERE EYE IRRITATION AND POSSIBLE INJURY. MAY
|
||||
CAUSE LIVER AND KIDNEY DAMAGE. CAUSES SEVERE RESPIRATORY TRACT
|
||||
IRRITATION. INHALATION OF FUMES MAY CAUSE METAL-FUME FEVER. EYE
|
||||
CONTACT MAY RESULT IN PERMANENT EYE DAMAGE. MAY CAUSE SEVERE SKIN
|
||||
IRRITATION. CAUSES SEVERE DIGESTIVE TRACT IRRITATION WITH PAIN,
|
||||
NAUSEA, VOMITING AND DIARRHEA. MAY CORRODE THE DIGESTIVE TRACT WITH
|
||||
HEMORRHAGING AND POSSIBLE SHOCK.
|
||||
Target Organs: Kidneys, liver.
|
||||
|
||||
Potential Health Effects
|
||||
Eye:
|
||||
Exposure to particulates or solution may cause conjunctivitis,
|
||||
ulceration, and corneal abnormalities. Causes redness and pain.
|
||||
Skin:
|
||||
May cause skin sensitization, an allergic reaction, which becomes
|
||||
evident upon re-exposure to this material. Causes redness and pain.
|
||||
Skin contact can cause itching, redness, and an eczema-type rash.
|
||||
Ingestion:
|
||||
Harmful if swallowed. Causes gastrointestinal irritation with
|
||||
nausea, vomiting and diarrhea.
|
||||
Inhalation:
|
||||
Causes severe irritation of upper respiratory tract with coughing,
|
||||
burns, breathing difficulty, and possible coma. Inhalation of fumes
|
||||
may cause metal fume fever, which is characterized by flu-like
|
||||
symptoms with metallic taste, fever, chills, cough, weakness, chest
|
||||
pain, muscle pain and increased white blood cell count.
|
||||
Chronic:
|
||||
Prolonged or repeated skin contact may cause dermatitis. May cause
|
||||
liver and kidney damage.
|
||||
Chronic toxicity related to copper is found only in individuals with
|
||||
Wilson's disease, who are unable to excrete copper. This causes
|
||||
retention of copper in the body resulting in damage to the liver,
|
||||
kidneys, brain, blood, bones and endocrine glands).
|
||||
|
||||
|
||||
**** SECTION 4 - FIRST AID MEASURES ****
|
||||
|
||||
Eyes:
|
||||
Immediately flush eyes with plenty of water for at least 15 minutes,
|
||||
occasionally lifting the upper and lower lids. Get medical aid
|
||||
immediately.
|
||||
Skin:
|
||||
Get medical aid. Flush skin with plenty of soap and water for at
|
||||
least 15 minutes while removing contaminated clothing and shoes.
|
||||
Ingestion:
|
||||
Induce vomiting. If victim is conscious and alert, give 2-4 cupfuls
|
||||
of milk or water. Never give anything by mouth to an unconscious
|
||||
person. Get medical aid immediately.
|
||||
Inhalation:
|
||||
Get medical aid immediately. Remove from exposure to fresh air
|
||||
immediately. If not breathing, give artificial respiration. If
|
||||
breathing is difficult, give oxygen.
|
||||
Notes to Physician:
|
||||
Treat symptomatically and supportively.
|
||||
Penicallamine may be of value as a chelating agent.
|
||||
|
||||
|
||||
**** SECTION 5 - FIRE FIGHTING MEASURES ****
|
||||
|
||||
General Information:
|
||||
Wear appropriate protective clothing to prevent contact with skin
|
||||
and eyes. Wear a self-contained breathing apparatus (SCBA) to
|
||||
prevent contact with thermal decomposition products. Substance is
|
||||
noncombustible.
|
||||
Extinguishing Media:
|
||||
Substance is noncombustible; use agent most appropriate to
|
||||
extinguish surrounding fire.
|
||||
Autoignition Temperature: Not applicable.
|
||||
Flash Point: Not applicable.
|
||||
NFPA Rating: Not published.
|
||||
Explosion Limits, Lower: Not available.
|
||||
Upper: Not available.
|
||||
|
||||
|
||||
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
|
||||
|
||||
General Information: Use proper personal protective equipment as indicated
|
||||
in Section 8.
|
||||
Spills/Leaks:
|
||||
Vacuum or sweep up material and place into a suitable disposal
|
||||
container. Avoid generating dusty conditions.
|
||||
|
||||
|
||||
**** SECTION 7 - HANDLING and STORAGE ****
|
||||
|
||||
Handling:
|
||||
Wash thoroughly after handling. Minimize dust generation and
|
||||
accumulation. Do not get in eyes, on skin, or on clothing. Do not
|
||||
ingest or inhale. Use only in a chemical fume hood.
|
||||
Storage:
|
||||
Store in a tightly closed container. Store in a cool, dry,
|
||||
well-ventilated area away from incompatible substances.
|
||||
|
||||
|
||||
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
|
||||
|
||||
Engineering Controls:
|
||||
Local exhaust ventilation may be necessary to control any air
|
||||
contaminants to within their TLVs during the use of this product.
|
||||
|
||||
Exposure Limits
|
||||
+--------------------+-------------------+-------------------+-----------------+
|
||||
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|
||||
|--------------------|-------------------|-------------------|-----------------|
|
||||
| Copper(II) chloride|fume: 0.2 mg/m3 |as Cu: 1 mg/m3 |fume, as Cu: 0.1 |
|
||||
| dihydrate, reagent|TWA; dusts and | TWA (dusts and | mg/m3 TWA; dust|
|
||||
| (powder), 99% (Tit| mists, as Cu: 1 |mists); 0.1 mg/m3 |s and mists, as C|
|
||||
| r.) | mg/m3 TWA |TWA (fume) |u: 1 mg/m3 TWA |
|
||||
| | (listed under | (listed under | (listed under|
|
||||
| | COPPER | COPPER | COPPER |
|
||||
+--------------------+-------------------+-------------------+-----------------+
|
||||
|
||||
OSHA Vacated PELs:
|
||||
Copper(II) chloride dihydrate, reagent (powder), 99% (Titr.):
|
||||
No OSHA Vacated PELs are listed for this chemical.
|
||||
|
||||
Personal Protective Equipment
|
||||
|
||||
Eyes:
|
||||
Wear appropriate protective eyeglasses or chemical
|
||||
safety goggles as described by OSHA's eye and face
|
||||
protection regulations in 29 CFR 1910.133.
|
||||
Skin:
|
||||
Wear appropriate protective gloves to prevent skin
|
||||
exposure.
|
||||
Clothing:
|
||||
Wear appropriate protective clothing to minimize
|
||||
contact with skin.
|
||||
Respirators:
|
||||
Follow the OSHA respirator regulations found in 29CFR
|
||||
1010.134. Always use a NIOSH-approved respirator when
|
||||
necessary.
|
||||
|
||||
|
||||
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
|
||||
|
||||
Physical State: Solid
|
||||
Appearance: Not available.
|
||||
Odor: Odorless
|
||||
pH: 3.0-3.8 @ 5% aq.sol
|
||||
Vapor Pressure: Not available.
|
||||
Vapor Density: Not available.
|
||||
Evaporation Rate: Not available.
|
||||
Viscosity: Not available.
|
||||
Boiling Point: Not available.
|
||||
Freezing/Melting Point: 100_C
|
||||
Decomposition Temperature: 100_C
|
||||
Solubility: 1150 g/l (5% aq.sol)
|
||||
Specific Gravity/Density: 2.5400
|
||||
Molecular Formula: Cl2Cu.2H2O
|
||||
Molecular Weight: 170.4788
|
||||
|
||||
|
||||
**** SECTION 10 - STABILITY AND REACTIVITY ****
|
||||
|
||||
Chemical Stability:
|
||||
Stable. Stable under normal temperatures and pressures.
|
||||
Conditions to Avoid:
|
||||
Incompatible materials, acids, excess heat, temperatures above 65_C,
|
||||
exposure to moist air or water.
|
||||
Incompatibilities with Other Materials:
|
||||
Incompatible with hydrazine, nitromethane, and sodium hypobromite. A
|
||||
mixture of either potassium or sodium with cupric chloride produces
|
||||
a strong explosion on impact. Copper salts can form explosive
|
||||
acetylides in contact with acetylene. Copper salts may enhance the
|
||||
decomposition of hydrazine.
|
||||
Hazardous Decomposition Products:
|
||||
Hydrogen chloride, chloride fumes.
|
||||
Hazardous Polymerization: Will not occur.
|
||||
|
||||
|
||||
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
|
||||
|
||||
RTECS#:
|
||||
CAS# 10125-13-0: GL7030000
|
||||
LD50/LC50:
|
||||
Not available.
|
||||
Carcinogenicity:
|
||||
Copper(II) chloride dihydrate, reagent (powder), 99% (Titr.) -
|
||||
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
|
||||
Epidemiology:
|
||||
No data available.
|
||||
Teratogenicity:
|
||||
No data available.
|
||||
Reproductive Effects:
|
||||
No data available.
|
||||
Neurotoxicity:
|
||||
No data available.
|
||||
Mutagenicity:
|
||||
No data available.
|
||||
Other Studies:
|
||||
No data available.
|
||||
|
||||
|
||||
**** SECTION 12 - ECOLOGICAL INFORMATION ****
|
||||
|
||||
Ecotoxicity:
|
||||
Acute aquatic effects: 96-hour LC50; Fathead minnow: 0.43 mg/L
|
||||
96-hour LC50; Bluegill sunfish: 1.25 mg/L 48-hour LC50; Rainbow
|
||||
trout: 0.4-0.5 mg/L This chemical is expected to cause little oxygen
|
||||
depletion in aquatic systems. It has a high potential to affect
|
||||
aquatic organisms and secondary waste treatment microorganisms.
|
||||
Environmental Fate:
|
||||
This chemical is not likely to bioconcentrate.
|
||||
Physical/Chemical:
|
||||
Not available.
|
||||
Other:
|
||||
Not available.
|
||||
|
||||
|
||||
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
|
||||
|
||||
Dispose of in a manner consistent with federal, state, and local regulations.
|
||||
RCRA D-Series Maximum Concentration of Contaminants: Not listed.
|
||||
RCRA D-Series Chronic Toxicity Reference Levels: Not listed.
|
||||
RCRA F-Series: Not listed.
|
||||
RCRA P-Series: Not listed.
|
||||
RCRA U-Series: Not listed.
|
||||
Not listed as a material banned from land disposal according to RCRA.
|
||||
|
||||
|
||||
**** SECTION 14 - TRANSPORT INFORMATION ****
|
||||
|
||||
US DOT
|
||||
Shipping Name: COPPER CHLORIDE
|
||||
Hazard Class: 8
|
||||
UN Number: UN2802
|
||||
Packing Group: III
|
||||
IMO
|
||||
Shipping Name: COPPER CHLORIDE
|
||||
Hazard Class: 8
|
||||
UN Number: 2802
|
||||
Packing Group: 3
|
||||
IATA
|
||||
Shipping Name: COPPER CHLORIDE
|
||||
Hazard Class: 8
|
||||
UN Number: 2802
|
||||
Packing Group: 3
|
||||
RID/ADR
|
||||
Shipping Name: COPPER CHLORIDE
|
||||
Dangerous Goods Code: 8(11C)
|
||||
UN Number: 2802
|
||||
Canadian TDG
|
||||
No information available.
|
||||
|
||||
|
||||
**** SECTION 15 - REGULATORY INFORMATION ****
|
||||
|
||||
A. Federal
|
||||
TSCA
|
||||
CAS# 10125-13-0 is not on the TSCA Inventory. It is a hydrate and
|
||||
exempt from TSCA Inventory requirements (40CFR270.3(u)(2)).
|
||||
Health & Safety Reporting List
|
||||
None of the chemicals are on the Health & Safety Reporting List.
|
||||
Chemical Test Rules
|
||||
None of the chemicals in this product are under a Chemical Test Rule.
|
||||
Section 12b
|
||||
None of the chemicals are listed under TSCA Section 12b.
|
||||
TSCA Significant New Use Rule
|
||||
None of the chemicals in this material have a SNUR under TSCA.
|
||||
CERCLA/SARA
|
||||
Section 302 (RQ)
|
||||
None of the chemicals in this material have an RQ.
|
||||
Section 302 (TPQ)
|
||||
None of the chemicals in this product have a TPQ.
|
||||
SARA Codes
|
||||
CAS # 10125-13-0: acute, chronic.
|
||||
Section 313
|
||||
No chemicals are reportable under Section 313.
|
||||
Clean Air Act:
|
||||
This material does not contain any hazardous air pollutants.
|
||||
This material does not contain any Class 1 Ozone depletors.
|
||||
This material does not contain any Class 2 Ozone depletors.
|
||||
Clean Water Act:
|
||||
None of the chemicals in this product are listed as Hazardous
|
||||
Substances under the CWA.
|
||||
None of the chemicals in this product are listed as Priority
|
||||
Pollutants under the CWA.
|
||||
None of the chemicals in this product are listed as Toxic Pollutants
|
||||
under the CWA.
|
||||
OSHA:
|
||||
None of the chemicals in this product are considered highly hazardous
|
||||
by OSHA.
|
||||
B. State
|
||||
Not present on state lists from CA, PA, MN, MA, FL, or NJ.
|
||||
California No Significant Risk Level:
|
||||
None of the chemicals in this product are listed.
|
||||
|
||||
C. International
|
||||
Canada
|
||||
None of the chemicals in this product are listed on the DSL/NDSL list.
|
||||
CAS# 10125-13-0 is not listed on Canada's Ingredient Disclosure List.
|
||||
European Labeling in Accordance with EC Directives
|
||||
Hazard Symbols: XN T
|
||||
Risk Phrases:
|
||||
R 22 Harmful if swallowed.
|
||||
R 25 Toxic if swallowed.
|
||||
R 36 Irritating to eyes.
|
||||
R 36/37/38 Irritating to eyes, respiratory system
|
||||
and skin.
|
||||
Safety Phrases:
|
||||
S 22 Do not inhale dust.
|
||||
S 24/25 Avoid contact with skin and eyes.
|
||||
S 26 In case of contact with eyes, rinse immediately
|
||||
with plenty of water and seek medical advice.
|
||||
S 37/39 Wear suitable gloves and eye/face
|
||||
protection.
|
||||
S 44 If you feel unwell, seek medical advice (show
|
||||
the label where possible).
|
||||
Exposure Limits:
|
||||
OEL-ARAB Republic of Egypt:TWA 0.1 mg/m3 (fume). OEL-AUSTRALIA:TWA 0.2
|
||||
mg/m3 (fume). OEL-AUSTRALIA:TWA 1 mg/m3 (dust). OEL-BELGIUM:TWA 0.2 m
|
||||
g/m3 (fume). OEL-BELGIUM:TWA 1 mg/m3 (dust). OEL-DENMARK:TWA 0.1 mg/m3
|
||||
(fume). OEL-DENMARK:TWA 1 mg/m3 (dust). OEL-FINLAND:TWA 0.2 mg/m3 (fu
|
||||
me). OEL-FINLAND:TWA 1 mg/m3. OEL-FINLAND:TWA 1 mg/m3 (dust)
|
||||
CE:TWA 0.2 mg/m3 (fume). OEL-FRANCE:TWA 1 mg/m3;STEL 2 mg/m3 (dust). O
|
||||
EL-GERMANY:TWA 0.1 mg/m3 (fume). OEL-GERMANY:TWA 1 mg/m3. OEL-GERMANY:
|
||||
TWA 1 mg/m3 (dust). OEL-HUNGARY:TWA 0.2 mg/m3;STEL 0.4 mg/m3 (dust). O
|
||||
EL-INDIA:TWA 0.2 mg/m3 (fume). OEL-THE NETHERLANDS:TWA 02 mg/m3 (fume)
|
||||
. OEL-THE NETHERLANDS:TWA 1 mg/m3 (dust). OEL-THE PHILIPPINES:TWA 1.0
|
||||
mg/m3 (fume). OEL-POLAND:TWA 0.1 mg/m3 (fume). OEL-RUSSIA:STEL 0.5 ppm
|
||||
(1 mg/m3) (dust). OEL-SWEDEN:TWA 0.2 mg/m3 (resp. dust). OEL-SWEDEN:T
|
||||
WA 0.2 mg/m3 (fume). OEL-SWEDEN:TWA 1 mg/m3 (total dust). OEL-SWITZERL
|
||||
AND:TWA 0.1 mg/m3;STEL 0.2 mg/m3 (fume). OEL-SWITZERLAND:TWA 1 mg/m3;S
|
||||
TEL 1 mg/m3. OEL-THAILAND:TWA 0.1 mg/m3 (fume). OEL-THAILAND:TWA 1 mg/
|
||||
m3. OEL-UNITED KINGDOM:TWA 0.2 mg/m3 (fume). OEL-UNITED KINGDOM:TWA 1
|
||||
mg/m3. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OEL I
|
||||
N NEW ZEALM-7M-7
|
||||
|
||||
|
||||
130
textfiles.com/science/CHEMICALS/copper_ii_fluoride.txt
Normal file
130
textfiles.com/science/CHEMICALS/copper_ii_fluoride.txt
Normal file
@@ -0,0 +1,130 @@
|
||||
|
||||
MSDS - COPPER (II) FLUORIDE
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: FLUORIDES, AS F
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: LM6290000
|
||||
CAS Number: 16984-48-8
|
||||
OSHA PEL: 2.5 MG/M3 (AS F)
|
||||
ACGIH TLV: 2.5 MG/M3 (AS F)
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: WHITE POWDER
|
||||
Boiling Point: N/A
|
||||
Melting Point: 1742F,950C
|
||||
Vapor Pressure (MM Hg/70 F): N/A
|
||||
Vapor Density (Air=1): N/A
|
||||
Specific Gravity: 4.23
|
||||
Evaporation Rate And Ref: NOT APPLICABLE
|
||||
Solubility In Water: MODERATE
|
||||
Percent Volatiles By Volume: N/A
|
||||
Magnetism (Milligauss): N/P
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: NON-FLAMMABLE
|
||||
Flash Point Method: N/P
|
||||
Lower Explosive Limit: N/A
|
||||
Upper Explosive Limit: N/A
|
||||
Extinguishing Media: WATER, CO*2, FOAM, OR DRY POWDER.
|
||||
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA & FULL
|
||||
PROTECTIVE EQUIPMENT (FP N).
|
||||
Unusual Fire And Expl Hazrds: NONE KNOWN.
|
||||
Report for NIIN: 00N026157
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): NONE KNOWN.
|
||||
Materials To Avoid: STRONG ACIDS.
|
||||
Hazardous Decomp Products: CONTACT W/ACIDS MAY PRODUCE HF.
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): NOT RELEVANT
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
|
||||
Route Of Entry - Inhalation: NO
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: NO
|
||||
Health Haz Acute And Chronic: NO SPECIFIC TOXICOLOGICAL DATA AVAILABLE FOR
|
||||
THIS COMPOUND. PENDING EXPERIMENTAL DETERMINATION OF TOXICITY, THIS
|
||||
MATERIAL SHOULD BE TREATED W/CAUTION & DIRECT CONTACT SHOULD BE AVOIDED.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NOT RELEVANT
|
||||
Signs/Symptoms Of Overexp: NONE SPECIFIED BY MANUFACTURER.
|
||||
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
|
||||
Emergency/First Aid Proc: INGEST:GET MD. SKIN:FLUSH W/SOAP & WATER.
|
||||
EYES:IRRIGATE W/WATER FOR AT LEAST 15 MINUTES. GET MD. INHAL:REMOVE TO
|
||||
FRESH AIR.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: SWEEP UP & TRANSFER TO SUITABLE CONTAINER.
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
|
||||
REGULATIONS.
|
||||
Precautions-Handling/Storing: AVOID EYE & SKIN CONTACT. AVOID INHALATION.
|
||||
STORE AWAY FROM ACIDS.
|
||||
Other Precautions: COPPER (II) FLUORIDE IS HYGROSCOPIC; CONTACT W/MOIST
|
||||
AIR SLOWLY SHOWS BLUE COLORATION BECAUSE OF FORMATION OF THE DIHYDRATE.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR FOR
|
||||
CONCENTRATION ENCOUNTERED.
|
||||
Ventilation: LOCAL EXHAUST:FUME HOOD. OTHER:N(2) FED DRY BOX. *
|
||||
Protective Gloves: POLYVINYL CHLORIDE/NEOPRENE GLOVES.
|
||||
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
|
||||
Other Protective Equipment: PROTECTIVE CLOTHING AS NEEDED TOP PREVENT
|
||||
CONTACT.
|
||||
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
|
||||
Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER.
|
||||
Report for NIIN: 00N026157
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 92122
|
||||
DOT PSN Code: ZZZ
|
||||
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
IMO PSN Code: ZZZ
|
||||
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
|
||||
IATA PSN Code: ZZZ
|
||||
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
AFI PSN Code: ZZZ
|
||||
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
Additional Trans Data: NOT REGULATED FOR TRANSPORTATION
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
Report for NIIN: 00N026157
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 06FEB92
|
||||
Label Date: 03FEB92
|
||||
Label Status: M
|
||||
Common Name: COPPER (II) FLUORIDE
|
||||
Chronic Hazard: NO
|
||||
Signal Word: CAUTION!
|
||||
Acute Health Hazard-Slight: X
|
||||
Contact Hazard-None: X
|
||||
Fire Hazard-None: X
|
||||
Reactivity Hazard-None: X
|
||||
Special Hazard Precautions: AVOID EYE AND SKIN CONTACT. AVOID INHALATION.
|
||||
STORE AWAY FROM ACIDS. WASH THOROUGHLY AFTER USING. ACUTE:NO SPECIFIC
|
||||
TOXICOLOGICAL DATA AVAILABLE FOR THIS COMPOUND. PENDING EXPERIMENTAL
|
||||
DETERMINATION OF TOXICITY, MATERIAL SHOULD BE TREATED WITH CAUTION.
|
||||
CHRONIC:NONE LISTED BY MANUFACTURER.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
155
textfiles.com/science/CHEMICALS/copper_oxide_blk.txt
Normal file
155
textfiles.com/science/CHEMICALS/copper_oxide_blk.txt
Normal file
@@ -0,0 +1,155 @@
|
||||
|
||||
MSDS - CUPRIC OXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CUPRIC OXIDE
|
||||
FORMULA: CUO
|
||||
FORMULA WT: 79.55
|
||||
CAS NO.: 01317-38-0
|
||||
COMMON SYNONYMS: COPPER(II)OXIDE; BLACK COPPER OXIDE
|
||||
PRODUCT CODES: 1814,1820,5256,5255
|
||||
EFFECTIVE: 10/08/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
CUPRIC OXIDE 90-100 1317-38-0
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1326 C ( 2419 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 6.40 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: BLACK CRYSTALLINE POWDER OR GRANULES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 1 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 15 PPM, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A
|
||||
SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
170
textfiles.com/science/CHEMICALS/copper_oxide_red.txt
Normal file
170
textfiles.com/science/CHEMICALS/copper_oxide_red.txt
Normal file
@@ -0,0 +1,170 @@
|
||||
|
||||
MSDS - CUPROUS OXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: CUPROUS OXIDE
|
||||
FORMULA: CU2O
|
||||
FORMULA WT: 143.09
|
||||
CAS NO.: 01317-39-1
|
||||
NIOSH/RTECS NO.: GL8050000
|
||||
COMMON SYNONYMS: RED COPPER OXIDE; BROWN COPPER OXIDE
|
||||
PRODUCT CODES: 1878
|
||||
EFFECTIVE: 10/31/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
CUPROUS OXIDE 90-100 1317-39-1
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 1800 C ( 3272 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1232 C ( 2250 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 6.00 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: RED-BROWN POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
OXIDES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 470
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
EXCESSIVE INHALATION OF DUST IS IRRITATING AND MAY BE SEVERELY DAMAGING
|
||||
TO RESPIRATORY PASSAGES AND/OR LUNGS.
|
||||
INGESTION MAY BE HARMFUL.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: AIR, MOISTURE, HEAT, LIGHT
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 1 PPM, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A
|
||||
SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINERS OUT OF SUN AND AWAY FROM HEAT.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
252
textfiles.com/science/CHEMICALS/decaborane.txt
Normal file
252
textfiles.com/science/CHEMICALS/decaborane.txt
Normal file
@@ -0,0 +1,252 @@
|
||||
|
||||
Common Name: DECABORANE
|
||||
|
||||
CAS Number: 17702-41-9
|
||||
DOT Number: UN 1868
|
||||
------------------------------------------------------------
|
||||
Substance number: 0597
|
||||
Date: February 1989 Revision: First
|
||||
------------------------------------------------------------
|
||||
HAZARD SUMMARY
|
||||
* Decaborane can affect you when breathed in and by passing
|
||||
through your skin. * Exposure can cause restlessness, headaches,
|
||||
dizziness, and nausea. High concentrations can cause muscle
|
||||
twitching, convulsions, unconsciousness, and death. High or
|
||||
repeated exposures may damage the liver and kidneys. * Vapor
|
||||
exposure may cause clouding of the eyes with loss of vision.
|
||||
Contact can cause severe eye burns and may also irritate the
|
||||
skin. * Decaborane may explode on contact with heat or flame, or
|
||||
with oxygenated or halogenated solvents. Contact with water can
|
||||
form flammable Hydrogen gas.
|
||||
|
||||
|
||||
IDENTIFICATION
|
||||
Decaborane is a colorless or white crystalline solid with a
|
||||
bitter odor. It is used in rocket propellants and in making
|
||||
other chemicals.
|
||||
|
||||
|
||||
REASON FOR CITATION
|
||||
* Decaborane is on the Hazardous Substance List because it is
|
||||
regulated by OSHA and cited by ACGIH, NFPA, DOT and EPA.
|
||||
|
||||
|
||||
HOW TO DETERMINE IF YOU ARE BEING EXPOSED
|
||||
* Exposure to hazardous substances should be routinely evaluated.
|
||||
This may include collecting personal and area air samples. You
|
||||
can obtain copies of sampling results from your employer. You
|
||||
have a legal right to this information under OSHA 1910.20. * If
|
||||
you think you are experiencing any work-related health problems,
|
||||
see a doctor trained to recognize occupational diseases. Take
|
||||
this Fact Sheet with you.
|
||||
|
||||
|
||||
WORKPLACE EXPOSURE LIMITS
|
||||
OSHA: The legal airborne permissible exposure limit (PEL) is 0.05
|
||||
ppm averaged over an 8-hour workshift and 0.15 ppm not to be
|
||||
exceeded during any (15 minute) work period. (Final Rule January
|
||||
1989).
|
||||
|
||||
ACGIH: The recommended airborne exposure limit is 0.05 ppm
|
||||
averaged over an 8-hour workshift and 0.15 ppm as a STEL (short
|
||||
term exposure limit).
|
||||
|
||||
* The above exposure limits are for air levels only. When skin
|
||||
contact also occurs, you may be overexposed, even though air
|
||||
levels are less than the limits listed above.
|
||||
|
||||
|
||||
WAYS OF REDUCING EXPOSURE
|
||||
* Where possible, enclose operations and use local exhaust
|
||||
ventilation at the site of chemical release. If local exhaust
|
||||
ventilation or enclosure is not used, respirators should be worn.
|
||||
* Wear protective work clothing.
|
||||
* Wash thoroughly immediately after exposure to Decaborane and at
|
||||
the end of the workshift. * Post hazard and warning information
|
||||
in the work area. In addition, as part of an ongoing education
|
||||
and training effort, communicate all information on the health
|
||||
and safety hazards of Decaborane to potentially exposed workers.
|
||||
|
||||
|
||||
HEALTH HAZARD INFORMATION
|
||||
|
||||
Acute Health Effects
|
||||
The following acute (short-term) health effects may occur
|
||||
immediately or shortly after exposure to Decaborane:
|
||||
* Exposure can cause restlessness, headaches, fatigue,
|
||||
clumsiness, nausea, hiccups and shaking. High levels can cause
|
||||
muscle twitches, convulsions, unconsciousness, and death. *
|
||||
Contact can cause severe eye burns, leading to permanent damage.
|
||||
It may also irritate the skin, causing a rash or burning feeling
|
||||
on contact. * Exposure to the vapor can irritate the eyes, nose,
|
||||
and throat.
|
||||
|
||||
Chronic Health Effects
|
||||
The following chronic (long-term) health effects can occur at
|
||||
some time after exposure to Decaborane and can last for months or
|
||||
years:
|
||||
|
||||
Cancer Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Decaborane has not been tested for
|
||||
its ability to cause cancer in animals.
|
||||
|
||||
Reproductive Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Decaborane has not been tested for
|
||||
its ability to affect reproduction.
|
||||
|
||||
Other Long-Term Effects
|
||||
* Repeated exposures may affect the ability to concentrate and
|
||||
damage the nervous system, causing tremors and spasms. *
|
||||
Decaborane may damage the liver and kidneys.
|
||||
* Overexposure may cause clouding of the cornea and eyes with
|
||||
loss of vision.
|
||||
|
||||
|
||||
MEDICAL
|
||||
|
||||
Medical Testing
|
||||
Before beginning employment and at regular times after that, the
|
||||
following is recommended:
|
||||
|
||||
* Examination of the nervous system.
|
||||
|
||||
If symptoms develop or overexposure is suspected, the following
|
||||
may be useful:
|
||||
|
||||
* Liver and kidney function tests.
|
||||
* Exam of the eyes and vision.
|
||||
|
||||
Any evaluation should include a careful history of past and
|
||||
present symptoms with an exam. Medical tests that look for
|
||||
damage already done are not a substitute for controlling
|
||||
exposure.
|
||||
|
||||
Request copies of your medical testing. You have a legal right
|
||||
to this information under OSHA 1910.20.
|
||||
|
||||
Mixed Exposures
|
||||
Because smoking can cause heart disease, as well as lung cancer,
|
||||
emphysema, and other respiratory problems, it may worsen
|
||||
respiratory conditions caused by chemical exposure. Even if you
|
||||
have smoked for a long time, stopping now will reduce your risk
|
||||
of developing health problems.
|
||||
|
||||
|
||||
WORKPLACE CONTROLS AND PRACTICES
|
||||
|
||||
Unless a less toxic chemical can be substituted for a hazardous
|
||||
substance, ENGINEERING CONTROLS are the most effective way of
|
||||
reducing exposure. The best protection is to enclose operations
|
||||
and/or provide local exhaust ventilation at the site of chemical
|
||||
release. Isolating operations can also reduce exposure. Using
|
||||
respirators or protective equipment is less effective than the
|
||||
controls mentioned above, but is sometimes necessary.
|
||||
|
||||
In evaluating the controls present in your workplace, consider:
|
||||
(1) how hazardous the substance is, (2) how much of the substance
|
||||
is released into the workplace and (3) whether harmful skin or
|
||||
eye contact could occur. Special controls should be in place for
|
||||
highly toxic chemicals or when significant skin, eye, or
|
||||
breathing exposures are possible.
|
||||
|
||||
In addition, the following control is recommended:
|
||||
|
||||
* Where possible, automatically transfer Decaborane from drums or
|
||||
other storage containers to process containers.
|
||||
|
||||
Good WORK PRACTICES can help to reduce hazardous exposures. The
|
||||
following work practices are recommended:
|
||||
|
||||
* Workers whose clothing has been contaminated by Decaborane
|
||||
should change into clean clothing promptly. * Contaminated work
|
||||
clothes should be laundered by individuals who have been informed
|
||||
of the hazards of exposure to Decaborane. * Eye wash fountains in
|
||||
the immediate work area should be provided for emergency use. *
|
||||
On skin contact with Decaborane, immediately wash or shower to
|
||||
remove the chemical. * Wash any areas of the body that may have
|
||||
contacted Decaborane at the end of each work day, whether or not
|
||||
known skin contact has occurred. * Do not eat, smoke, or drink
|
||||
where Decaborane is handled, processed, or stored, since the
|
||||
chemical can be swallowed. Wash hands carefully before eating or
|
||||
smoking. * Do not dry sweep for clean-up. Use a vacuum or a wet
|
||||
method to reduce dust during clean-up.
|
||||
FIRE HAZARDS
|
||||
|
||||
* The solid can self-ignite in Oxygen, and mixtures with
|
||||
oxidizing materials can be explosive. * Decaborane is a
|
||||
combustible solid.
|
||||
* Use dry chemical or foam extinguishers. Avoid halogenated
|
||||
extinguishing agents, as they can react violently. * POISONOUS
|
||||
GASES ARE PRODUCED IN FIRE.
|
||||
* CONTAINERS MAY EXPLODE IN FIRE.
|
||||
* If employees are expected to fight fires, they must be trained
|
||||
and equipped as stated in OSHA 1910.156.
|
||||
|
||||
|
||||
SPILLS AND EMERGENCIES
|
||||
|
||||
If Decaborane is spilled or leaked, take the following steps:
|
||||
|
||||
* Restrict persons not wearing protective equipment from area of
|
||||
spill or leak until cleanup is complete. * Remove all ignition
|
||||
sources.
|
||||
* Ventilate area of spill or leak.
|
||||
* Collect powdered material in the most convenient manner and
|
||||
deposit in sealed containers. * It may be necessary to contain
|
||||
and dispose of Decaborane as a HAZARDOUS WASTE. Contact your
|
||||
Department of Environmental Protection (DEP) or your regional
|
||||
office of the federal Environmental Protection Agency (EPA) for
|
||||
specific recommendations.
|
||||
|
||||
|
||||
HANDLING AND STORAGE
|
||||
|
||||
* Prior to working with Decaborane you should be trained on its
|
||||
proper handling and storage. * Decaborane must be stored to avoid
|
||||
contact with OXIDIZERS, such as PERMANGANATES, NITRATES,
|
||||
PEROXIDES, CHLORATES, and PERCHLORATES; or HALOGENATED COMPOUNDS,
|
||||
since violent reactions occur. * Store in tightly closed
|
||||
containers in a cool, well ventilated area away from HEAT and
|
||||
WATER. HEAT can cause an explosion. Contact with WATER can
|
||||
slowly produce flammable Hydrogen gas. Detached storage is
|
||||
preferable. * Sources of ignition such as smoking and open flames
|
||||
are prohibited where Decaborane is handled, used, or stored.
|
||||
|
||||
|
||||
FIRST AID
|
||||
|
||||
Eye Contact
|
||||
* Immediately flush with large amounts of water for at least 15
|
||||
|
||||
minutes, occasionally lifting upper and lower lids. Seek medical
|
||||
attention immediately.
|
||||
|
||||
Skin Contact
|
||||
* Quickly remove contaminated clothing. Immediately wash area
|
||||
with large amounts of soap and water. Seek medical attention
|
||||
immediately.
|
||||
|
||||
Breathing
|
||||
* Remove the person from exposure.
|
||||
* Begin rescue breathing if breathing has stopped and CPR if
|
||||
heart action has stopped. * Transfer promptly to a medical
|
||||
facility.
|
||||
|
||||
|
||||
PHYSICAL DATA
|
||||
|
||||
Vapor Pressure: 0.05 mm Hg at 77 degrees F (25 degrees C)
|
||||
Flash Point: 176 degrees F (80 degrees C)
|
||||
Water Solubility: Insoluble
|
||||
|
||||
|
||||
OTHER COMMONLY USED NAMES
|
||||
|
||||
Chemical Name:
|
||||
Decaborane
|
||||
|
||||
Other Names and Formulations:
|
||||
Boron Hydride; Nido-Decaborane; Decaboron Tetradecahydride
|
||||
|
||||
160
textfiles.com/science/CHEMICALS/dechlorane.txt
Normal file
160
textfiles.com/science/CHEMICALS/dechlorane.txt
Normal file
@@ -0,0 +1,160 @@
|
||||
OCCIDENTAL CHEMICAL -- DECHLORANE PLUS 515 THE FLAMETAMER
|
||||
MATERIAL SAFETY DATA SHEET
|
||||
FSC: 6850
|
||||
NIIN: 00N011596
|
||||
Manufacturer's CAGE: 32618
|
||||
Part No. Indicator: A
|
||||
Part Number/Trade Name: DECHLORANE PLUS 515 THE FLAMETAMER
|
||||
===========================================================================
|
||||
General Information
|
||||
===========================================================================
|
||||
Company's Name: OCCIDENTAL CHEMICAL CORPORATION
|
||||
Company's Street: 360 RAINBOW BOULEVARD SOUTH,SUITE 400
|
||||
Company's City: NIAGARA FALLS
|
||||
Company's State: NY
|
||||
Company's Country: US
|
||||
Company's Zip Code: 14302
|
||||
Company's Emerg Ph #: 716-278-7021
|
||||
Company's Info Ph #: 716-286-3081
|
||||
Record No. For Safety Entry: 001
|
||||
Tot Safety Entries This Stk#: 001
|
||||
Date MSDS Prepared: 24MAY89
|
||||
Safety Data Review Date: 01MAR90
|
||||
MSDS Serial Number: BJKKF
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: DECH PLUS.PERCENT:99.90 BY VOL;99.95 BY WT.
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: IO1430000
|
||||
CAS Number: 13560-89-9
|
||||
OSHA PEL: N/K (FP N/ORNL)
|
||||
ACGIH TLV: N/K (FP N/ORNL)
|
||||
Other Recommended Limit: N/K (FP N/ORNL)
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: FREE-FLOWING WHITE,ODORLESS POWDER.
|
||||
Boiling Point: N/A
|
||||
Melting Point: 350C,662F
|
||||
Vapor Pressure (MM Hg/70 F): SEE SUPP
|
||||
Vapor Density (Air=1): N/A
|
||||
Specific Gravity: 1.8 (WATER=1)
|
||||
Decomposition Temperature: N/K (FP N)
|
||||
Evaporation Rate And Ref: N/K (FP N/ORNL)
|
||||
Solubility In Water: INSOLUBLE
|
||||
pH: SUP DA
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: N/A
|
||||
Lower Explosive Limit: N/A
|
||||
Upper Explosive Limit: N/A
|
||||
Extinguishing Media: NON-FLAMMABLE.USE AGENT SUITABLE FOR SURROUNDING
|
||||
FIRE.
|
||||
Special Fire Fighting Proc: USE NIOSH/MSHA APPROVED POSITIVE PRESSURE SCBA
|
||||
AND FULL PROTECTIVE EQUIPMENT.
|
||||
Unusual Fire And Expl Hazrds: DECOMPOSITION BY BURNING IN OPEN FLAME MAY
|
||||
YIELD HYDROGEN CHLORIDE GAS.
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Cond To Avoid (Stability): AVOID TEMPERATURES ABOVE 275C,527F.
|
||||
Materials To Avoid: PROLONGED HEATING IN EXCESS OF 275C,527F ACCELERATES
|
||||
THERMAL DEGRADATION.
|
||||
Hazardous Decomp Products: AT TEMPERATURES IN EXCESS OF 275C,527F
|
||||
DEGRADATION PRODUCTS INCLUDE HYDROGEN CHLORIDE.
|
||||
Conditions To Avoid (Poly): N/K (FP N/ORNL)
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: LD50 RAT ORAL >25 G/KG;LD50 (SEE SUPP)
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: YES
|
||||
Health Haz Acute And Chronic: SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NONE
|
||||
Signs/Symptoms Of Overexp: EYES:NO OCULAR EFFECTS HAVE BEEN OBSERVED.
|
||||
SKIN:NO IRRITANT EFFECTS HAVE BEEN OBSERVED.INGESTION:NOT HIGHLY TOXIC IF
|
||||
SWALLOWED.INHALATION:DUST MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT.
|
||||
Med Cond Aggravated By Exp: N/K (FP N/ORNL)
|
||||
Emergency/First Aid Proc: EYES:FLUSH W/ DIRECTED STREAM OF WATER AT LEAST
|
||||
15 MIN;HOLD LIDS APART.GET IMMED MED ATTN IF IRRIT OCCURS.SKIN:WASH W/
|
||||
SOAP,WATER.GET PROMPT MED ATTN IF IRRIT OCCURS.INGEST:NEVER GIVE ANYTHING
|
||||
BY MOUTH TO UNCON PERSON.GIVE SEVERAL GLASSES OF WATER,THEN TICKLE BACK OF
|
||||
THROAT W/ FINGER TO INDUCE VOMIT.KEEP AIRWAY CLEAR.SEEK MED ATTN
|
||||
IMMED.INHAL:REMOVE FROM EXPOS,GIVE SUPPORT TREATMENT IF NEEDED.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: SCOOP & SWEEP UP ALL SPILLED PRODUCT & OTHER
|
||||
CONTAMINATED MATERIAL & PLACE IN MARKED DISPOSAL CONTAINERS.CLEAN UP AREA
|
||||
ON A DRY BASIS.DO NOT FLUSH TO SEWER.
|
||||
Neutralizing Agent: N/K (FP N/ORNL)
|
||||
Waste Disposal Method: DISPOSAL MUST BE IAW FEDERAL,STATE & LOCAL REGS (FP
|
||||
N).DISPOSE OF SPILLED/WASTE PROD,OTHER CONTAM MATL IN LICENSED LANDFILL OR
|
||||
BURN IN LICENSED INCIN DESIGNED TO HANDLE HYDROGEN CHLORIDE AS COMBUST
|
||||
PROD.MATL NOT USED OR REPROCESSED DISP PER REGS.
|
||||
Precautions-Handling/Storing: STORE IN CLEAN,DRY,WELL VENTILATED AREA AWAY
|
||||
FROM HEAT.KEEP CONTR CLOSED TO PREVENT CONTAM.USE NORMAL SAFETY PRECAUTIONS
|
||||
& GOOD INDUS HYGIENE PRAC.
|
||||
Other Precautions: DO NOT REUSE CONTRS,RESIDUES MAY REMAIN;OBSERVE ALL
|
||||
LABEL PREC.DISPOSE OF CONTR PER GOVERNMENT REGS.INSURE ADEQ VENT IN WORK
|
||||
AREA.AVOID EYE CONTACT.DO NOT ALLOW TO ENTER SEWERS OR WATERWAYS.HEATING
|
||||
>275C,525F CAUSES DEGRADATION,TOXIC GASES.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
|
||||
EXPOSURE OF CONCERN (FP N).
|
||||
Ventilation: LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
|
||||
CONCENTRATION BELOW LEVEL OF CONCERN (FP N/ORNL).
|
||||
Protective Gloves: RESISTANT SUCH AS COTTON.
|
||||
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
|
||||
Other Protective Equipment: EYE WASH FACILITY SHOULD BE IN CLOSE
|
||||
PROXIMITY.OBSERVE GOOD WORK PRACTICES.WEAR APPROVED DUST MASK,CLOTHING.
|
||||
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE.WASH
|
||||
THOROUGHLY AFTER HANDLING.
|
||||
Suppl. Safety & Health Data: VP:0.006 MMHG @ 200C,392F.PH:7 100 GM/L.
|
||||
LD50-LC50 MIX:RABBIT DERMAL >8 G/KG;LC50 RAT INHALATION >2.25 MG/L/4 HR.
|
||||
ROUTES OF ENTRY:INHALATION/SKIN/INGESTION (FP N).
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 90347
|
||||
DOT PSN Code: ZZZ
|
||||
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
IMO PSN Code: ZZZ
|
||||
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
|
||||
IATA PSN Code: ZZZ
|
||||
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
AFI PSN Code: ZZZ
|
||||
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
Additional Trans Data: NOT REGULATE FOR TRANSPORTATION
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Label Status: G
|
||||
Common Name: DECHLORANE PLUS 515 THE FLAMETAMER
|
||||
Special Hazard Precautions: SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE.
|
||||
EYES:NO OCULAR EFFECTS HAVE BEEN OBSERVED.SKIN:NO IRRITANT EFFECTS HAVE
|
||||
BEEN OBSERVED.INGESTION:NOT HIGHLY TOXIC IF SWALLOWED.INHALATION:DUST MAY
|
||||
CAUSE IRRITATION OF THE RESPIRATORY TRACT.
|
||||
Label Name: OCCIDENTAL CHEMICAL CORPORATION
|
||||
Label Street: 360 RAINBOW BOULEVARD SOUTH,SUITE 400
|
||||
Label City: NIAGARA FALLS
|
||||
Label State: NY
|
||||
Label Zip Code: 14302
|
||||
Label Country: US
|
||||
Label Emergency Number: 716-278-7021
|
||||
=======================================================================
|
||||
URL for this msds http://hazard.com. If you wish to change, add to, or
|
||||
delete information in this archive please sent updates to dan@hazard.com.
|
||||
164
textfiles.com/science/CHEMICALS/dextrin.txt
Normal file
164
textfiles.com/science/CHEMICALS/dextrin.txt
Normal file
@@ -0,0 +1,164 @@
|
||||
|
||||
MSDS - DEXTRIN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: DEXTRIN
|
||||
FORMULA: (C6H10O5)N
|
||||
FORMULA WT: 162.14
|
||||
CAS NO.: 9004-53-9
|
||||
NIOSH/RTECS NO.: HH9450000
|
||||
COMMON SYNONYMS: STARCH GUM
|
||||
PRODUCT CODES: G193
|
||||
EFFECTIVE: 03/11/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 0 NONE
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 0 NONE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 1.45 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 10
|
||||
|
||||
APPEARANCE & ODOR: OFF-WHITE TO YELLOW POWDER WITH A BLAND ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
NO EFFECTS OF OVEREXPOSURE WERE DOCUMENTED.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: FLAME
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
269
textfiles.com/science/CHEMICALS/diazomethane.txt
Normal file
269
textfiles.com/science/CHEMICALS/diazomethane.txt
Normal file
@@ -0,0 +1,269 @@
|
||||
|
||||
Common Name: Diazomethane
|
||||
CAS Number: 334-88-3
|
||||
DOT Number: None
|
||||
Date: March, 1986
|
||||
-----------------------------------------
|
||||
|
||||
HAZARD SUMMARY
|
||||
* Diazomethane can affect you when breathed in.
|
||||
* It is extremely toxic. Exposure can cause severe lung damage
|
||||
with symptoms of coughing, chest pain, shortness of breath,
|
||||
fever and fatigue. These may not be felt until hours or days
|
||||
after exposure and this can cause death.
|
||||
* Exposure to the gas or liquid can cause severe skin burns and
|
||||
eye damage.
|
||||
* Repeated exposures, even at low levels, may cause an asthma-
|
||||
like lung allergy.
|
||||
* Heat, sunlight, or other bright lights can cause it to
|
||||
explode. Contact with alkali metals, drying agents and rough
|
||||
edges can also cause explosions.
|
||||
|
||||
IDENTIFICATION
|
||||
Diazomethane is a yellow gas at room temperature. It can also
|
||||
exist as a liquid under pressure. It is used in making other
|
||||
chemicals.
|
||||
|
||||
REASON FOR CITATION
|
||||
* Diazomethane is on the Hazardous Substance List because it is
|
||||
regulated by OSHA and cited by ACGIH.
|
||||
|
||||
HOW TO DETERMINE IF YOU ARE BEING EXPOSED
|
||||
* Exposure to hazardous substances should be routinely
|
||||
evaluated. This may include collecting personal and area air
|
||||
samples. You can obtain copies of sampling results from your
|
||||
employer. You have a legal right to this information under
|
||||
OSHA 1910.20.
|
||||
* If you think you are experiencing any work-related health
|
||||
problems, see a doctor trained to recognize occupational
|
||||
diseases. Take this Fact Sheet with you.
|
||||
-----------------------------------------
|
||||
|
||||
WORKPLACE EXPOSURE LIMITS
|
||||
OSHA: The legal airborne permissible exposure limit (PEL) is
|
||||
0.2 ppm averaged over an 8-hour work-shift.
|
||||
|
||||
ACGIH: The recommended airborne exposure limit is 0.2 ppm
|
||||
averaged over an 8-hour workshift.
|
||||
|
||||
WAYS OF REDUCING EXPOSURE
|
||||
* Where possible, enclose operations and use local exhaust
|
||||
ventilation at the site of chemical release. If local exhaust
|
||||
ventilation or enclosure is not used, respirators should be
|
||||
worn.
|
||||
* Wear protective work clothing.
|
||||
* Wash thoroughly immediately after exposure to Diazomethane.
|
||||
* Post hazard and warning information in the work area. In
|
||||
addition, as part of an ongoing education and training effort,
|
||||
communicate all information on the health and safety hazards
|
||||
of Diazomethane to potentially exposed workers.
|
||||
|
||||
This Fact Sheet is a summary source of information of all potential
|
||||
and most severe health hazards that may result from exposure.
|
||||
Duration of exposure, concentration of the substance and other
|
||||
factors will affect your susceptibility to any of the potential
|
||||
effects described below.
|
||||
------------------------------------------
|
||||
|
||||
HEALTH HAZARD INFORMATION
|
||||
|
||||
Acute Health Effects
|
||||
The following acute (short-term) health effects may occur
|
||||
immediately or shortly after exposure to Diazomethane:
|
||||
|
||||
* Breathing Diazomethane gas or vapors can cause severe lung
|
||||
damage. Immediate symptoms may include coughing, wheezing,
|
||||
shortness of breath, chest pain, dizziness, fatigue, headache,
|
||||
and irritation of the mouth, nose and throat. Nausea,
|
||||
vomiting, and fever may also occur. This can progress to a
|
||||
build-up of fluid in the lungs (pulmonary edema) and death.
|
||||
The effects may not be felt for hours or days after exposure.
|
||||
* Contact with Diazomethane gas, liquefied gas, or solutions can
|
||||
cause severe eye burns and permanent damage.
|
||||
* Skin contact can cause severe irritation, burns and scaling of
|
||||
the affected body area. Similar symptoms may occur on the
|
||||
skin inside the mouth, nose and throat following inhalation.
|
||||
|
||||
Chronic Health Effects
|
||||
The following chronic (long-term) health effects can occur at some
|
||||
time after exposure to Diazomethane and can last for months or
|
||||
years:
|
||||
|
||||
Cancer Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Diazomethane has not been tested
|
||||
for its ability to cause cancer in animals.
|
||||
|
||||
Reproductive Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Diazomethane has not been tested
|
||||
for its ability to affect reproduction.
|
||||
|
||||
Other Long-Term Effects
|
||||
* Repeated exposure to Diazomethane can cause an asthma-like
|
||||
lung allergy. Symptoms may include coughing, wheezing, and
|
||||
fatigue. The symptoms may become progressively worse with
|
||||
repeated attacks, and permanent lung damage (emphysema) may
|
||||
result.
|
||||
|
||||
MEDICAL
|
||||
|
||||
Medical Testing
|
||||
Before beginning employment and at regular times after that, the
|
||||
following are recommended:
|
||||
|
||||
* Lung function tests. These may be normal at first if the
|
||||
person is not having an attack at the time.
|
||||
|
||||
If symptoms develop or overexposure is suspected, the following may
|
||||
be useful:
|
||||
|
||||
* Evaluation by a qualified allergist, including careful
|
||||
exposure history and special testing, may help diagnose
|
||||
allergy.
|
||||
* Consider chest x-ray after acute over-exposure.
|
||||
|
||||
Any evaluation should include a careful history of past and present
|
||||
symptoms with an exam. Medical tests that look for damage already
|
||||
done are not a substitute for controlling exposure.
|
||||
|
||||
Request copies of your medical testing. You have a legal right to
|
||||
this information under OSHA 1910.20.
|
||||
|
||||
Mixed Exposures
|
||||
Because smoking can cause heart disease, as well as lung cancer,
|
||||
emphysema, and other respiratory problems, it may worsen
|
||||
respiratory conditions caused by chemical exposure. Even if you
|
||||
have smoked for a long time, stopping now will reduce your risk of
|
||||
developing health problems.
|
||||
|
||||
WORKPLACE CONTROLS AND PRACTICES
|
||||
|
||||
Unless a less toxic chemical can be substituted for a hazardous
|
||||
substance, ENGINEERING CONTROLS are the most effective way of
|
||||
reducing exposure. The best protection is to enclose operations
|
||||
and/or provide local exhaust ventilation at the site of chemical
|
||||
release. Isolating operations can also reduce exposure. Using
|
||||
respirators or protective equipment is less effective than the
|
||||
controls mentioned above, but is sometimes necessary.
|
||||
|
||||
In evaluating the controls present in your workplace, consider: (1)
|
||||
how hazardous the substance is, (2) how much of the substance is
|
||||
released into the workplace and (3) whether harmful skin or eye
|
||||
contact could occur. Special controls should be in place for
|
||||
highly toxic chemicals or when significant skin, eye, or breathing
|
||||
exposures are possible. In addition, the following control is
|
||||
recommended:
|
||||
|
||||
* Where possible, automatically transfer Diazomethane from
|
||||
cylinders or other storage containers to process containers.
|
||||
|
||||
Good WORK PRACTICES can help to reduce hazardous exposures. The
|
||||
following work practices are recommended:
|
||||
|
||||
* Workers whose clothing has been contaminated by liquid
|
||||
Diazomethane should change into clean clothing promptly.
|
||||
* Do not take contaminated work clothes home. Family members
|
||||
could be exposed.
|
||||
* Contaminated work clothes should be laundered by individuals
|
||||
who have been informed of the hazards of exposure to
|
||||
Diazomethane.
|
||||
* Eye wash fountains should be provided in the immediate work
|
||||
area for emergency use.
|
||||
* If there is the possibility of skin exposure, emergency shower
|
||||
facilities should be provided.
|
||||
* On skin contact with Diazomethane, immediately wash or shower
|
||||
to remove the chemical.
|
||||
* Do not eat, smoke, or drink where Diazomethane is handled,
|
||||
processed, or stored, since the chemical can be swallowed.
|
||||
Wash hands carefully before eating or smoking.
|
||||
|
||||
PERSONAL PROTECTIVE EQUIPMENT
|
||||
|
||||
WORKPLACE CONTROLS ARE BETTER THAN PERSONAL PROTECTIVE EQUIPMENT.
|
||||
However, for some jobs (such as outside work, confined space entry,
|
||||
jobs done only once in a while, or jobs done while workplace
|
||||
controls are being installed), personal protective equipment may be
|
||||
appropriate.
|
||||
|
||||
The following recommendations are only guidelines and may not apply
|
||||
to every situation.
|
||||
|
||||
Clothing
|
||||
* Avoid skin contact with Diazomethane. Wear protective gloves
|
||||
and clothing. Safety equipment suppliers/manufacturers can
|
||||
provide recommendations on the most protective glove/clothing
|
||||
material for your operation.
|
||||
* All protective clothing (suits, gloves, footwear, headgear)
|
||||
should be clean, available each day, and put on before work.
|
||||
|
||||
Eye Protection
|
||||
* Wear splash-proof chemical goggles and face shield when
|
||||
working with liquid Diazomethane, or gas-proof goggles when
|
||||
working with the gas, unless full facepiece respiratory
|
||||
protection is worn.
|
||||
|
||||
Respiratory Protection
|
||||
IMPROPER USE OF RESPIRATORS IS DANGEROUS. Such equipment should
|
||||
only be used if the employer has a written program that takes into
|
||||
account workplace conditions, requirements for worker training,
|
||||
respirator fit testing and medical exams, as described in OSHA
|
||||
1910.134.
|
||||
|
||||
* Where the potential exists for exposures over 0.2 ppm, use a
|
||||
MSHA/NIOSH approved supplied-air respirator with a full
|
||||
facepiece operated in the positive pressure mode or with a
|
||||
full facepiece, hood, or helmet in the continuous flow mode,
|
||||
or use a MSHA/NIOSH approved self-contained breathing
|
||||
apparatus with a full facepiece operated in pressure-demand or
|
||||
other positive pressure mode.
|
||||
* Exposure to 10 ppm is immediately dangerous to life and
|
||||
health. If the possibility of exposures above 10 ppm exists,
|
||||
use a MSHA/NIOSH approved self-contained breathing apparatus
|
||||
with a full facepiece operated in continuous flow or other
|
||||
positive pressure mode.
|
||||
|
||||
HANDLING AND STORAGE
|
||||
|
||||
* Prior to working with Diazomethane you should be trained on
|
||||
its proper handling and storage.
|
||||
* Diazomethane must be stored to avoid contact with ALKALI
|
||||
METALS, such as LITHIUM, SODIUM, or POTASSIUM; or DRYING
|
||||
AGENTS, such as CALCIUM SULFATE, since violent reactions
|
||||
occur.
|
||||
* Store in tightly closed containers in a cool well-ventilated
|
||||
area away from HEAT and LIGHT. The pure liquid material
|
||||
explodes above 302oF, whereas impure material explodes at
|
||||
lower temperatures. Exposure of the gas or solutions to
|
||||
SUNLIGHT or other BRIGHT LIGHTING may cause an explosion.
|
||||
Contact with ROUGH EDGES, such as found on ground glass, may
|
||||
cause an explosion. Safety barriers or shields should be used
|
||||
to protect workers from accidental explosions.
|
||||
* Sources of ignition such as smoking and open flames are
|
||||
prohibited where Diazomethane is handled, used, or stored.
|
||||
* Metal containers used in the transfer of 5 gallons or more of
|
||||
Diazomethane should be grounded and bonded. Drums must be
|
||||
equipped with self-closing valves, pressure vacuum bungs, and
|
||||
flame arresters.
|
||||
* Use only non-sparking tools and equipment, especially when
|
||||
opening and closing containers of Diazomethane.
|
||||
* Wherever Diazomethane is used, handled, manufactured, or
|
||||
stored, use explosion-proof electrical equipment and fittings.
|
||||
|
||||
Common Name: Diazomethane
|
||||
DOT Number: None
|
||||
DOT Emergency Guide code: No Citation
|
||||
CAS Number: 334-88-3
|
||||
-----------------------------------------
|
||||
Hazard rating NJ DOH NFPA
|
||||
FLAMMABILITY Not Found
|
||||
REACTIVITY Not Found
|
||||
EXPLOSIVE LIQUID
|
||||
----------------------------------------
|
||||
Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious;
|
||||
4=severe
|
||||
|
||||
FIRE HAZARDS
|
||||
|
||||
* Diazomethane will explode in a fire. In the event of a fire,
|
||||
immediately evacuate the area.
|
||||
340
textfiles.com/science/CHEMICALS/dioctyl_adipate.txt
Normal file
340
textfiles.com/science/CHEMICALS/dioctyl_adipate.txt
Normal file
@@ -0,0 +1,340 @@
|
||||
|
||||
Common Name: Bis (2-Ethylhexyl) Adipate
|
||||
CAS Number: 103-23-1
|
||||
DOT Number: None
|
||||
Date: January 4, 1989
|
||||
-----------------------------------------
|
||||
|
||||
HAZARD SUMMARY
|
||||
* Bis (2-Ethylhexyl) Adipate can affect you when breathed in.
|
||||
* Bis (2-Ethylhexyl) Adipate can cause eye irritation and may
|
||||
burn the skin.
|
||||
|
||||
IDENTIFICATION
|
||||
Bis (2-Ethylhexyl) Adipate is a light colored, oily liquid. It is
|
||||
used as a plasticizer in making polyvinyl and certain other
|
||||
plastics, and in solvents and aircraft lubricants.
|
||||
|
||||
REASON FOR CITATION
|
||||
* Bis (2-Ethylhexyl) Adipate is on the Hazardous Substance List
|
||||
because it is cited by DEP, EPA, IARC and NFPA.
|
||||
* Definitions are attached.
|
||||
|
||||
HOW TO DETERMINE IF YOU ARE BEING EXPOSED
|
||||
* Exposure to hazardous substances should be routinely
|
||||
evaluated. This may include collecting personal and area air
|
||||
samples. You can obtain copies of sampling results from your
|
||||
employer. You have a legal right to this information under
|
||||
OSHA 1910.20.
|
||||
* If you think you are experiencing any work related health
|
||||
problems, see a doctor trained to recognize occupational
|
||||
diseases. Take this Fact Sheet with you.
|
||||
|
||||
WORKPLACE EXPOSURE LIMITS
|
||||
No occupational exposure limits have been established for Bis (2-
|
||||
Ethylhexyl) Adipate. This does not mean that this substance is not
|
||||
harmful. Safe work practices should always be followed.
|
||||
|
||||
* Bis (2-Ethylhexyl) Adipate may cause cancer, mutations or
|
||||
reproductive problems. All contact with this chemical should
|
||||
be reduced to the lowest possible level.
|
||||
|
||||
WAYS OF REDUCING EXPOSURE
|
||||
* Where possible, enclose operations and use local exhaust
|
||||
ventilation at the site of chemical release. If local exhaust
|
||||
ventilation or enclosure is not used, respirators should be
|
||||
worn.
|
||||
* Wear protective work clothing.
|
||||
* Wash thoroughly immediately after exposure to Bis (2-
|
||||
Ethylhexyl) Adipate and at the end of the workshift.
|
||||
* Post hazard and warning information in the work area. In
|
||||
addition, as part of an ongoing education and training effort,
|
||||
communicate all information on the health and safety hazards of Bis
|
||||
(2-Ethylhexyl) Adipate to potentially exposed workers.
|
||||
|
||||
This Fact Sheet is a summary source of information of all potential
|
||||
and most severe health hazards that may result from exposure.
|
||||
Duration of exposure, concentration of the substance and other
|
||||
factors will affect your susceptibility to any of the potential
|
||||
effects described below.
|
||||
------------------------------------------
|
||||
|
||||
HEALTH HAZARD INFORMATION
|
||||
|
||||
Acute Health Effects
|
||||
The following acute (short term) health effects may occur
|
||||
immediately or shortly after exposure to Bis (2-Ethylhexyl)
|
||||
Adipate:
|
||||
|
||||
* Bis (2-Ethylhexyl) Adipate can irritate the eyes and may burn
|
||||
the skin.
|
||||
Chronic Health Effects
|
||||
The following chronic (long term) health effects can occur at some
|
||||
time after exposure to Bis (2-Ethylhexyl) Adipate and can last for
|
||||
months or years:
|
||||
|
||||
Cancer Hazard
|
||||
* There is limited evidence that Bis (2-Ethylhexyl) Adipate
|
||||
causes cancer in animals. It may cause cancer of the liver.
|
||||
* Many scientists believe there is no safe level of exposure to
|
||||
a carcinogen. Such substances may also have the potential for
|
||||
causing reproductive damage in humans.
|
||||
|
||||
Reproductive Hazard
|
||||
* There is limited evidence that Bis (2-Ethylhexyl) Adipate may
|
||||
damage the developing fetus.
|
||||
* There is limited evidence that Bis (2-Ethylhexyl) Adipate may
|
||||
decrease fertility in males and females.
|
||||
|
||||
Other Long Term Effects
|
||||
* Bis (2-Ethylhexyl) Adipate has not been tested for other
|
||||
chronic (long term) health effects.
|
||||
|
||||
MEDICAL
|
||||
|
||||
Medical Testing
|
||||
Any evaluation should include a careful history of past and present
|
||||
symptoms with an exam. Medical tests that look for damage already
|
||||
done are not a substitute for controlling exposure.
|
||||
|
||||
There is no special test for this chemical. However, if illness
|
||||
occurs or over exposure is suspected, medical attention is
|
||||
recommended.
|
||||
|
||||
Request copies of your medical testing. You have a legal right to
|
||||
this information under OSHA 1910.20.
|
||||
|
||||
WORKPLACE CONTROLS AND PRACTICES
|
||||
|
||||
Unless a less toxic chemical can be substituted for a hazardous
|
||||
substance, ENGINEERING CONTROLS are the most effective way of
|
||||
reducing exposure. The best protection is to enclose operations
|
||||
and/or provide local exhaust ventilation at the site of chemical
|
||||
release. Isolating operations can also reduce exposure. Using
|
||||
respirators or protective equipment is less effective than the
|
||||
controls mentioned above, but is sometimes necessary.
|
||||
|
||||
In evaluating the controls present in your workplace, consider: (1)
|
||||
how hazardous the substance is, (2) how much of the substance is
|
||||
released into the workplace and (3) whether harmful skin or eye
|
||||
contact could occur. Special controls should be in place for highly
|
||||
toxic chemicals or when significant skin, eye, or breathing
|
||||
exposures are possible.
|
||||
|
||||
In addition, the following control is recommended:
|
||||
* Where possible, automatically pump liquid Bis (2-Ethylhexyl)
|
||||
Adipate from drums or other storage containers to process
|
||||
containers.
|
||||
|
||||
Good WORK PRACTICES can help to reduce hazardous exposures. The
|
||||
following work practices are recommended:
|
||||
|
||||
* Workers whose clothing has been contaminated by Bis (2-
|
||||
Ethylhexyl) Adipate should change into clean clothing
|
||||
promptly.
|
||||
* If there is the possibility of skin exposure, emergency shower
|
||||
facilities should be provided.
|
||||
* Contaminated work clothes should be laundered by individuals
|
||||
who have been informed of the hazards of exposure to Bis (2-
|
||||
Ethylhexyl) Adipate.
|
||||
* On skin contact with Bis (2-Ethylhexyl) Adipate, immediately
|
||||
wash or shower to remove the chemical. At the end of the
|
||||
workshift, wash any areas of the body that may have contacted
|
||||
Bis (2-Ethylhexyl) Adipate, whether or not known skin contact
|
||||
has occurred.
|
||||
* Do not eat, smoke, or drink where Bis (2-Ethylhexyl) Adipate
|
||||
is handled, processed, or stored, since the chemical can be
|
||||
swallowed. Wash hands carefully before eating or smoking.
|
||||
|
||||
PERSONAL PROTECTIVE EQUIPMENT
|
||||
|
||||
WORKPLACE CONTROLS ARE BETTER THAN PERSONAL PROTECTIVE EQUIPMENT.
|
||||
However, for some jobs (such as outside work, confined space entry,
|
||||
jobs done only once in a while, or jobs done while workplace
|
||||
controls are being installed), personal protective equipment may be
|
||||
appropriate.
|
||||
|
||||
The following recommendations are only guidelines and may not apply
|
||||
to every situation.
|
||||
|
||||
Clothing
|
||||
* Avoid skin contact with Bis (2-Ethylhexyl) Adipate. Wear
|
||||
protective gloves and clothing. Safety equipment
|
||||
suppliers/manufacturers can provide recommendations on the
|
||||
most protective glove/clothing material for your operation.
|
||||
* All protective clothing (suits, gloves, footwear, headgear)
|
||||
should be clean, available each day, and put on before work.
|
||||
|
||||
Eye Protection
|
||||
* Wear splash proof chemical goggles and face shield when
|
||||
working with liquid Bis (2-Ethylhexyl) Adipate, unless full
|
||||
facepiece respiratory protection is worn.
|
||||
|
||||
Respiratory Protection
|
||||
IMPROPER USE OF RESPIRATORS IS DANGEROUS. Such equipment should
|
||||
only be used if the employer has a written program that takes into
|
||||
account workplace conditions, requirements for worker training,
|
||||
respirator fit testing and medical exams, as described in OSHA
|
||||
1910.134.
|
||||
* Engineering controls must be effective to ensure that exposure
|
||||
to Bis (2-Ethylhexyl) Adipate does not occur.
|
||||
* Where the potential exists for exposure to Bis (2-Ethylhexyl)
|
||||
Adipate, use a MSHA/NIOSH approved supplied air respirator
|
||||
with a full facepiece operated in the positive pressure mode
|
||||
or with a full facepiece, hood, or helmet in the continuous
|
||||
flow mode, or use a MSHA/NIOSH approved self contained
|
||||
breathing apparatus with a full facepiece operated in pressure
|
||||
demand or other positive pressure mode.
|
||||
|
||||
Common Name: Bis (2-Ethylhexyl) Adipate
|
||||
DOT Number: None
|
||||
DOT Emergency Guide code: No Citation
|
||||
CAS Number: 103-23-1
|
||||
----------------------------------------
|
||||
Hazard rating NJDOH NFPA
|
||||
FLAMMABILITY - 1
|
||||
REACTIVITY - 0
|
||||
----------------------------------------
|
||||
POISONOUS GASES ARE PRODUCED IN FIRE
|
||||
----------------------------------------
|
||||
Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious;
|
||||
4=severe
|
||||
|
||||
FIRE HAZARDS
|
||||
* Bis (2-Ethylhexyl) Adipate is a COMBUSTIBLE LIQUID.
|
||||
* Use dry chemical, CO2, or alcohol foam extinguishers.
|
||||
* POISONOUS GASES ARE PRODUCED IN FIRE, including acrid smoke
|
||||
and irritating fumes.
|
||||
* If employees are expected to fight fires, they must be trained
|
||||
and equipped as stated in OSHA 1910.156.
|
||||
|
||||
SPILLS AND EMERGENCIES
|
||||
If Bis (2-Ethylhexyl) Adipate is spilled or leaked, take the
|
||||
following steps:
|
||||
|
||||
* Restrict persons not wearing protective equipment from area of
|
||||
spill or leak until cleanup is complete.
|
||||
* Remove all ignition sources.
|
||||
* Absorb liquids in vermiculite, dry sand, earth, or a similar
|
||||
material and deposit in sealed containers.
|
||||
* It may be necessary to contain and dispose of Bis (2-
|
||||
Ethylhexyl) Adipate as a HAZARDOUS WASTE. Contact your state
|
||||
Environmental Program for specific recommendations.
|
||||
|
||||
==========================================
|
||||
FOR LARGE SPILLS AND FIRES immediately call your fire department.
|
||||
==========================================
|
||||
|
||||
HANDLING AND STORAGE
|
||||
* Prior to working with Bis (2-Ethylhexyl) Adipate you should be
|
||||
trained on its proper handling and storage.
|
||||
* Bis (2-Ethylhexyl) Adipate is an ester. Some esters may
|
||||
explode on mixing with NITRATES.
|
||||
* Store in tightly closed containers in a cool, well ventilated
|
||||
area.
|
||||
* Sources of ignition, such as smoking and open flames, are
|
||||
prohibited where Bis (2-Ethylhexyl) Adipate is used, handled,
|
||||
or stored in a manner that could create a potential fire or
|
||||
explosion hazard.
|
||||
|
||||
FIRST AID
|
||||
|
||||
POISON INFORMATION
|
||||
|
||||
Eye Contact
|
||||
* Immediately flush with large amounts of water for at least 15
|
||||
minutes, occasionally lifting upper and lower lids.
|
||||
|
||||
Skin Contact
|
||||
* Remove contaminated clothing. Wash contaminated skin with
|
||||
water.
|
||||
|
||||
Breathing
|
||||
* Remove the person from exposure.
|
||||
|
||||
PHYSICAL DATA
|
||||
|
||||
Vapor Pressure: 2.60 mm Hg at 392oF (200oC)
|
||||
Flash Point: 385oF (196oC)
|
||||
Water Solubility: Insoluble
|
||||
|
||||
OTHER COMMONLY USED NAMES
|
||||
|
||||
Chemical Name:
|
||||
Hexanedioic Acid, bis(2-ethylhexyl) ester
|
||||
|
||||
Other Names and Formulations:
|
||||
BEHA; DEHA; DOA; Dioctyl Adipate; Octyl Adipate; Di-2-Ethylhexyl
|
||||
Adipate.
|
||||
------------------------------------------
|
||||
Not intended to be copied and sold for commercial purposes.
|
||||
------------------------------------------
|
||||
NEW JERSEY DEPARTMENT OF HEALTH
|
||||
Right to Know Program
|
||||
CN 368, Trenton, NJ 08625 0368
|
||||
------------------------------------------
|
||||
------------------------------------------
|
||||
|
||||
ECOLOGICAL INFORMATION
|
||||
|
||||
Bis (2-Ethylhexyl) Adipate is a liquid used to make plastics and
|
||||
lubricants. It may enter the environment from industrial
|
||||
discharges or spills.
|
||||
|
||||
ACUTE (SHORT-TERM) ECOLOGICAL EFFECTS
|
||||
|
||||
Acute toxic effects may include the death of animals, birds, or
|
||||
fish, and death or low growth rate in plants. Acute effects are
|
||||
seen two to four days after animals or plants come in contact with
|
||||
a toxic chemical substance.
|
||||
|
||||
Bis(2-Ethylhexyl) Adipate has slight acute toxicity to aquatic
|
||||
life. Insufficient data are available to evaluate or predict the
|
||||
short-term effects of this chemical to plants, birds, or land
|
||||
animals.
|
||||
|
||||
CHRONIC (LONG-TERM) ECOLOGICAL EFFECTS
|
||||
|
||||
Chronic toxic effects may include shortened lifespan, reproductive
|
||||
problems, lower fertility, and changes in appearance or behavior.
|
||||
Chronic effects can be seen long after first exposure(s) to a toxic
|
||||
chemical.
|
||||
|
||||
Bis (2-Ethylhexyl) Adipate has slight chronic toxicity to aquatic
|
||||
life. Insufficient data are available to evaluate or predict the
|
||||
long-term effects of this chemical to plants, birds, or land
|
||||
animals.
|
||||
|
||||
WATER SOLUBILITY
|
||||
|
||||
Bis (2-Ethylhexyl) Adipate is slightly soluble in water.
|
||||
Concentrations of 1 milligram and less will mix with a liter of
|
||||
water.
|
||||
|
||||
DISTRIBUTION AND PERSISTENCE IN THE ENVIRONMENT
|
||||
|
||||
Bis (2-Ethylhexyl) Adipate is slightly persistent in water, with a
|
||||
half-life of between 2 to 20 days. The half-life of a pollutant is
|
||||
the amount of time it takes for one-half of the chemical to be
|
||||
degraded. About 47.5% of this chemical will eventually end up in
|
||||
terrestrial soils; about 44% will end up in aquatic sediments; and
|
||||
the rest will end up in the air.
|
||||
|
||||
BIOACCUMULATION IN AQUATIC ORGANISMS
|
||||
|
||||
Some substances increase in concentration, or bioaccumulate, in
|
||||
living organisms as they breathe contaminated air, drink
|
||||
contaminated water, or eat contaminated food. These chemicals can
|
||||
become concentrated in the tissues and internal organs of animals
|
||||
and humans.
|
||||
|
||||
The concentration of Bis (2-Ethylhexyl) Adipate found in fish
|
||||
tissues is expected to be considerably higher than the average
|
||||
concentration of this chemical in the water from which the fish was
|
||||
taken.
|
||||
|
||||
SUPPORT DOCUMENT: AQUIRE Database, ERL-Duluth, U.S. EPA.
|
||||
|
||||
|
||||
...............................................................................
|
||||
.
|
||||
168
textfiles.com/science/CHEMICALS/disilver_oxide.txt
Normal file
168
textfiles.com/science/CHEMICALS/disilver_oxide.txt
Normal file
@@ -0,0 +1,168 @@
|
||||
|
||||
MSDS - SILVER OXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: SILVER OXIDE
|
||||
FORMULA: AG2O
|
||||
FORMULA WT: 231.74
|
||||
CAS NO.: 20667-12-3
|
||||
NIOSH/RTECS NO.: VW4900000
|
||||
COMMON SYNONYMS: ARGENTOUS OXIDE; DISILVER OXIDE
|
||||
PRODUCT CODES: V005,3427,5005
|
||||
EFFECTIVE: 10/24/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 2 MODERATE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
STORAGE: KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
SILVER OXIDE 90-100 20667-12-3
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 7.22 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: BROWNISH-BLACK ODORLESS POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
|
||||
MODERATE OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.1 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST INHALATION MAY CAUSE TIGHTNESS AND PAIN IN CHEST, COUGHING, AND
|
||||
DIFFICULTY IN BREATHING.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: AIR, LIGHT, HEAT
|
||||
|
||||
INCOMPATIBLES: MOST COMMON METALS, COMBUSTIBLE MATERIALS, AMMONIA,
|
||||
MAGNESIUM, ORGANIC MATERIALS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. KEEP COMBUSTIBLES (WOOD, PAPER, OIL,
|
||||
ETC.) AWAY FROM SPILLED MATERIAL. WITH CLEAN SHOVEL, CAREFULLY PLACE
|
||||
MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH
|
||||
SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. IF CONCENTRATION
|
||||
EXCEEDS CAPACITY OF RESPIRATOR, A SELF-CONTAINED
|
||||
BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
KEEP PRODUCT OUT OF LIGHT.
|
||||
ISOLATE FROM INCOMPATIBLE MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
222
textfiles.com/science/CHEMICALS/ethanol.txt
Normal file
222
textfiles.com/science/CHEMICALS/ethanol.txt
Normal file
@@ -0,0 +1,222 @@
|
||||
|
||||
MSDS - ALCOHOL, ANHYDROUS, REAGENT
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: ALCOHOL, ANHYDROUS, REAGENT
|
||||
FORMULA: MIXTURE C2H5OH & C3H7OH & CH3OH
|
||||
FORMULA WT: .00
|
||||
CAS NO.: - -
|
||||
NIOSH/RTECS NO.: KQ6300000
|
||||
COMMON SYNONYMS: ETHANOL
|
||||
PRODUCT CODES: 9229,9401,A478,5128,9400
|
||||
EFFECTIVE: 08/06/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (POISON)
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B
|
||||
EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
FLAMMABLE - VAPOR HARMFUL
|
||||
MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED
|
||||
CANNOT BE MADE NON-POISONOUS
|
||||
CAUTION - POISON - CONTAINS METHYL ALCOHOL. NOT FOR INTERNAL OR
|
||||
EXTERNAL USE.
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE WATER SPRAY,
|
||||
ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH SPILL AREA WITH WATER
|
||||
SPRAY.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
ETHYL ALCOHOL 90-100 64-17-5
|
||||
ISOPROPYL ALCOHOL >1 67-63-0
|
||||
METHYL ALCOHOL >1 67-56-1
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 78 C ( 172 F) VAPOR PRESSURE(MM HG): 44
|
||||
|
||||
MELTING POINT: -114 C ( -173 F) VAPOR DENSITY(AIR=1): 1.6
|
||||
|
||||
SPECIFIC GRAVITY: 0.79 EVAPORATION RATE: 3.1
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100
|
||||
|
||||
APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID WITH A PLEASANT ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP: 13 C ( 55 F)
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 19.0 % LOWER - 3.3 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK.
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG
|
||||
OXIDIZERS MAY CAUSE FIRE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TLV AND PEL ARE BASED ON ABSOLUTE ETHANOL. ETHYL ALCOHOL HAS BEEN LINKED
|
||||
TO BIRTH DEFECTS AND CANCER IN HUMANS.
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 1900 MG/M3 ( 1000 PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 1900 MG/M3 ( 1000 PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 7060
|
||||
LD50 (IPR-RAT)(MG/KG) - 4070
|
||||
LD50 (IV-RAT) (MG/KG) - 1440
|
||||
LC50 (INHAL-MOUSE) (G/M3) - 39
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF VAPORS MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS,
|
||||
DROWSINESS, IRRITATION OF RESPIRATORY TRACT, AND LOSS OF CONSCIOUSNESS.
|
||||
CONTACT MAY CAUSE IRRITATION OF SKIN, EYES, AND MUCOUS MEMBRANES.
|
||||
PROLONGED EXPOSURE MAY CAUSE DERMATITIS.
|
||||
INGESTION MAY CAUSE BLINDNESS.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INGESTION, INHALATION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION,
|
||||
SUNLIGHT AND ULTRAVIOLET LIGHT
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, ALUMINUM, ALKALI METALS,
|
||||
ACETYL CHLORIDE
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK
|
||||
IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP
|
||||
WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO
|
||||
CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
|
||||
|
||||
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED
|
||||
FOR SPILLS OF THIS PRODUCT.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC
|
||||
VAPOR CARTRIDGE IS RECOMMENDED. IF CONCENTRATION
|
||||
EXCEEDS CAPACITY OF CARTRIDGE RESPIRATOR, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM,
|
||||
PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID.
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED,
|
||||
FLAMMABLE LIQUID STORAGE AREA OR CABINET.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME ETHYL ALCOHOL
|
||||
HAZARD CLASS FLAMMABLE LIQUID
|
||||
UN/NA UN1170
|
||||
LABELS FLAMMABLE LIQUID
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME ETHANOL
|
||||
HAZARD CLASS 3.2
|
||||
UN/NA UN1170
|
||||
LABELS FLAMMABLE LIQUID
|
||||
|
||||
164
textfiles.com/science/CHEMICALS/ferric_oxide.txt
Normal file
164
textfiles.com/science/CHEMICALS/ferric_oxide.txt
Normal file
@@ -0,0 +1,164 @@
|
||||
|
||||
MSDS - FERRIC OXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: FERRIC OXIDE
|
||||
FORMULA: FE2O3
|
||||
FORMULA WT: 159.69
|
||||
CAS NO.: 1309-37-1
|
||||
NIOSH/RTECS NO.: NO7400000
|
||||
COMMON SYNONYMS: IRON(III)OXIDE; RED IRON OXIDE; C.I. 77491
|
||||
PRODUCT CODES: 2024
|
||||
EFFECTIVE: 05/05/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
FERRIC OXIDE 90-100 1309-37-1
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1565 C ( 2849 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 5.24 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: RED TO REDDISH-BROWN, ODORLESS POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 5 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE EYES.
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
97
textfiles.com/science/CHEMICALS/gallic_acid.txt
Normal file
97
textfiles.com/science/CHEMICALS/gallic_acid.txt
Normal file
@@ -0,0 +1,97 @@
|
||||
|
||||
MSDS - BISMUTH SUBGALLATE
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: BISMUTH SUBGALLATE
|
||||
FORMULA: HOCOC6H2(OH)OBI(OH H2O)O
|
||||
FORMULA WT: 412.12
|
||||
CAS NO.: 00099-26-3
|
||||
COMMON SYNONYMS: BASIC BISMUTH GALLATE; GALLIC ACID BISMUTH BASIC SALT
|
||||
PRODUCT CODES: 1131
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN
|
||||
CAUSES IRRITATION
|
||||
THERE IS INSUFFICIENT DATA IN THE PUBLISHED LITERATURE TO ASSIGN COMPLETE
|
||||
NUMERICAL SAF-T-DATA RATINGS AND LABORATORY PROTECTIVE EQUIPMENT FOR THIS
|
||||
PRODUCT. SPECIAL PRECAUTIONS MUST BE USED IN STORAGE, USE AND HANDLING.
|
||||
PROTECTIVE EQUIPMENT FOR LABORATORY BENCH USE SHOULD BE CHOSEN USING
|
||||
PROFESSIONAL JUDGMENT BASED ON THE SIZE AND TYPE OF REACTION OR TEST TO BE
|
||||
CONDUCTED AND THE AVAILABLE VENTILATION, WITH OVERRIDING CONSIDERATION TO
|
||||
MINIMIZE CONTACT WITH THE CHEMICAL.
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
COMPONENT % CAS NO.
|
||||
NOT APPLICABLE
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
SPECIFIC GRAVITY: N/A EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
APPEARANCE & ODOR: BRIGHT YELLOW, ODORLESS POWDER.
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: N/A
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
NO EFFECTS OF OVEREXPOSURE WERE DOCUMENTED.
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
CONDITIONS TO AVOID: LIGHT
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
EYE/SKIN PROTECTION: SINCE SOME OF THE HAZARDS OF THIS PRODUCT ARE
|
||||
UNKNOWN, AN INDUSTRIAL HYGIENIST SHOULD BE
|
||||
CONSULTED ON VENTILATION AND PERSONAL PROTECTIVE
|
||||
EQUIPMENT. COVER THE BODY AS MUCH AS POSSIBLE TO
|
||||
AVOID CONTACT WITH THE CHEMICAL. WEAR SAFETY
|
||||
GOGGLES, GLOVES, AND IMPERVIOUS CLOTHING.
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP PRODUCT OUT OF LIGHT.
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
DOMESTIC (D.O.T.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
INTERNATIONAL (I.M.O.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
|
||||
109
textfiles.com/science/CHEMICALS/graphite.txt
Normal file
109
textfiles.com/science/CHEMICALS/graphite.txt
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@@ -0,0 +1,109 @@
|
||||
|
||||
MSDS - GRAPHITE
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: GRAPHITE
|
||||
FORMULA: C
|
||||
FORMULA WT: 12.01
|
||||
CAS NO.: 07782-42-5
|
||||
NIOSH/RTECS NO.: VV7780000
|
||||
COMMON SYNONYMS: NATURAL GRAPHITE; MINERAL CARBON; BLACK LEAD
|
||||
PRODUCT CODES: M845
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
HEALTH - 1
|
||||
FLAMMABILITY - 2
|
||||
REACTIVITY - 0
|
||||
CONTACT - 0
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
CAUTION
|
||||
COMBUSTIBLE
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. IN CASE OF FIRE, SOAK WITH WATER. IN CASE OF SPILL, SWEEP UP AND
|
||||
REMOVE. FLUSH SPILL AREA WITH WATER.
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
COMPONENT % CAS NO.
|
||||
GRAPHITE 90-100 7782-42-5
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
SPECIFIC GRAVITY: 2.20 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
APPEARANCE & ODOR: DARK GRAY TO BLACK ODORLESS POWDER.
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: N/A
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
(WATER MAY BE INEFFECTIVE.)
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 2.5 MG/M3 ( PPM)
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE EYES.
|
||||
DUST MAY CAUSE SNEEZING AND COUGHING.
|
||||
MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE
|
||||
TO GRAPHITE: SKIN, SINUS AND PULMONARY DISEASES.
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
CONDITIONS TO AVOID: AIR, MOISTURE
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
|
||||
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
|
||||
WITH WATER.
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 5 PPM, A DUST/MIST RESPIRATOR IS
|
||||
RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED
|
||||
BREATHING APPARATUS IS ADVISED.
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
|
||||
AWAY FROM HEAT, SPARKS, OR FLAME.
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
DOMESTIC (D.O.T.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
INTERNATIONAL (I.M.O.)
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S.
|
||||
|
||||
79
textfiles.com/science/CHEMICALS/gum_arabic.txt
Normal file
79
textfiles.com/science/CHEMICALS/gum_arabic.txt
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@@ -0,0 +1,79 @@
|
||||
|
||||
MSDS - ARABIC GUM
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: ARABIC GUM
|
||||
FORMULA: COMPOSITION VARIES
|
||||
FORMULA WT: 240,000
|
||||
CAS NO.:
|
||||
COMMON SYNONYMS: ACACIA GUM
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: N/A VAPOR PRESSURE @ 20C (MM HG): N/A
|
||||
MELTING POINT: N/A VAPOR DENSITY (AIR=1): N/A
|
||||
SPECIFIC GRAVITY: 1.49 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): 37 PERCENT VOLATILES BY VOLUME: N/A
|
||||
APPEARANCE & ODOR: WHITE TO PALE YELLOW POWDER
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: NONFLAMMABLE
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
WATER SPRAY, CO2, DRY CHEMICAL
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS
|
||||
UNUSUAL FIRE AND EXPLOSION HAZARDS
|
||||
EMITS EXTREMELY CORROSIVE FUMES ON DECOMPOSITION
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): NONE ESTABLISHED
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT MAY CAUSE DERMATITIS. DUST INHALATION MAY CAUSE RESPIRATORY
|
||||
SYMPTOMS: COUGHING, ASTHMA, WHEEZING
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
SKIN: WASH WITH SOAP/WATER
|
||||
EYES: FLUSH WITH WATER; GET MEDICAL ASSISTANCE
|
||||
INHALATION: REMOVE TO FRESH AIR; GET MEDICAL ATTENTION
|
||||
INGESTION: GET MEDICAL ATTENTION
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE
|
||||
CONDITIONS TO AVOID:
|
||||
INCOMPATIBILES: N/A
|
||||
DECOMPOSITION PRODUCTS: CO
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
EXHAUST VENTILATION PREFERRED
|
||||
DUST RESPIRATOR MAY BE REQUIRED
|
||||
PROTECTIVE GLOVES AND SAFETY GOGGLES RECOMMENDED
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
SPECIFIC GRAVITY: 1.35 - 1.49
|
||||
|
||||
125
textfiles.com/science/CHEMICALS/gum_copal.txt
Normal file
125
textfiles.com/science/CHEMICALS/gum_copal.txt
Normal file
@@ -0,0 +1,125 @@
|
||||
RUGBY LABS -- COPAL CAVITY VARNISH - RESIN COPAL
|
||||
MATERIAL SAFETY DATA SHEET
|
||||
FSC: 6520
|
||||
NIIN: 012178855
|
||||
Manufacturer's CAGE: 4V824
|
||||
Part No. Indicator: A
|
||||
Part Number/Trade Name: COPAL CAVITY VARNISH
|
||||
===========================================================================
|
||||
General Information
|
||||
===========================================================================
|
||||
Item Name: RESIN COPAL
|
||||
Company's Name: RUGBY LABS, INC
|
||||
Company's Street: 898 ORLANDO AVE
|
||||
Company's City: WEST HEMPSTEAD
|
||||
Company's State: NY
|
||||
Company's Zip Code: 11552
|
||||
Company's Emerg Ph #: (800) 645-2158
|
||||
Company's Info Ph #: (800) 645-2158
|
||||
Record No. For Safety Entry: 001
|
||||
Tot Safety Entries This Stk#: 002
|
||||
Date MSDS Prepared: 20JAN86
|
||||
Safety Data Review Date: 28AUG90
|
||||
Preparer's Company: OK ANALYTICAL LAB
|
||||
Preparer's St Or P. O. Box: 141 LANZA AVE BLDG 12, 3 FLOOR
|
||||
Preparer's City: GARFIELD
|
||||
Preparer's State: NJ
|
||||
Preparer's Zip Code: 07026
|
||||
MSDS Serial Number: BJCTR
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: TRACHYLOLIC ACID
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: 1005170TA
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: CLEAR LIGHT BROWN LIQUID WITH ALCOHOLIC ODORL.
|
||||
Boiling Point: 113F
|
||||
Vapor Pressure (MM Hg/70 F): 350
|
||||
Vapor Density (Air=1): 4.0
|
||||
Specific Gravity: 1.144F
|
||||
Evaporation Rate And Ref: (BU AC = 1): 5.0
|
||||
Solubility In Water: 20%
|
||||
Percent Volatiles By Volume: 90%
|
||||
pH: 3.40
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: 57F
|
||||
Flash Point Method: PMCC
|
||||
Lower Explosive Limit: 2.6%
|
||||
Upper Explosive Limit: 7.8%
|
||||
Extinguishing Media: WATER FOG, FOAM, CO2, DRY CHEMICAL
|
||||
Special Fire Fighting Proc: KEEP VAPORS AWAY FROM POSSIBLE IGNITION
|
||||
SOURCE. WEAR POSITIVE PRESSURE, SELF CONTAINED BREATHING APPARATUS.
|
||||
Unusual Fire And Expl Hazrds: DON'T PRESSURIZE, CUT, HEAT, WELD OR EXPOSED
|
||||
SUCH CONTAINERS TO FLAME.
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): FLAME, HEAT, IGNITION SOURCE
|
||||
Materials To Avoid: ALUMINUM, ALLOYS, AMINES & AMMONIA
|
||||
Hazardous Decomp Products: HYDROGEN CHLORIDE & CO
|
||||
Hazardous Poly Occur: NO
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: ORAL RATS LD50 = 250 MG/KG
|
||||
Route Of Entry - Inhalation: NO
|
||||
Route Of Entry - Skin: YES
|
||||
Route Of Entry - Ingestion: YES
|
||||
IRRITATION. INGESTION: RAPID ABSORPTION MAY OCCUR THROUGH LUNGS IF
|
||||
ASPIRATED & CAUSE SYSTEMIC EFFECTS.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NONE
|
||||
IRRITATION.
|
||||
Emergency/First Aid Proc: INGESTION: DECISION TO INDUCE VOMITING OR NOT
|
||||
SHOULD BE MADE BY PHYSICIAN.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: FOR SMALL SPILLS: SMOTHER W/FOAM OR SPONGE
|
||||
MATERIALS.
|
||||
Waste Disposal Method: BURN IN SYSTEM EQUIPPED W/AN HYDROCHLORIC ACID
|
||||
SCRUBBER IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE & LOCAL
|
||||
REGULATIONS.
|
||||
Precautions-Handling/Storing: DON'T BREATHE VAPORS. DON'T GET IN EYES, OR
|
||||
SKIN OR ON CLOTHING. DON'T TAKE INTERNALLY.
|
||||
Other Precautions: NO SMOKING.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: APPROVED FULL-FACE, SUPPLIED AIR RESPIRATOR.
|
||||
Ventilation: LOCAL EXHAUST: RECOMMENDED
|
||||
Protective Gloves: RUBBER
|
||||
Eye Protection: CHEMICAL GOGGLES
|
||||
Other Protective Equipment: RUBBER PROTECTIVE CLOTH
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Label Status: G
|
||||
Common Name: COPAL CAVITY VARNISH
|
||||
IRRITATION. INGESTION: RAPID ABSORPTION MAY OCCUR THROUGH LUNGS IF
|
||||
IRRITATION.
|
||||
Label Name: RUGBY LABS, INC
|
||||
Label Street: 898 ORLANDO AVE
|
||||
Label City: WEST HEMPSTEAD
|
||||
Label State: NY
|
||||
Label Zip Code: 11552
|
||||
Label Emergency Number: (800) 645-2158
|
||||
=======================================================================
|
||||
URL for this msds http://hazard.com. If you wish to change, add to, or
|
||||
delete information in this archive please sent updates to dan@hazard.com.
|
||||
131
textfiles.com/science/CHEMICALS/gum_tragacanth.txt
Normal file
131
textfiles.com/science/CHEMICALS/gum_tragacanth.txt
Normal file
@@ -0,0 +1,131 @@
|
||||
Fisher Acros -- Tragacanth Gum 9000-65-1
|
||||
|
||||
ACC39013
|
||||
|
||||
----------------------------------------------------------------------------
|
||||
|
||||
Tragacanth gum
|
||||
|
||||
Acros Catalog #s: AC421385000 AC421395000
|
||||
*** This product is for research and development purposes only. ***
|
||||
|
||||
MATERIAL SAFETY DATA SHEET
|
||||
|
||||
Pittsburgh, PA 15219-4785
|
||||
1-800-ACROS-01 (1-800-227-6701)
|
||||
For Emergency Transportation Information call CHEMTREC: 800-424-9300
|
||||
|
||||
Date of Revision: 10/31/90 Accession Number: 120242
|
||||
Modified by Fisher Scientific: 12/94
|
||||
==============================================================================
|
||||
SECTION I. IDENTIFICATION
|
||||
|
||||
- Product Name: Tragacanth Gum
|
||||
- Synonym(s): Gum Tragacanth
|
||||
- Formula: Gummy exudation from Astragalus Gummifer Labill
|
||||
- CAT No(s): 136 9875; 136 9883; 164 6520; 193 6061
|
||||
- Chem. No(s): 15409
|
||||
==============================================================================
|
||||
SECTION II. PRODUCT AND COMPONENT HAZARD DATA
|
||||
|
||||
ACGIH
|
||||
COMPONENT(S): Percent TLV(R) CAS Reg. No.
|
||||
|
||||
Tragacanth Gum ca. 100 --- 9000-65-1
|
||||
==============================================================================
|
||||
SECTION III. PHYSICAL DATA
|
||||
|
||||
- Appearance and Odor: White to yellow solid; odorless
|
||||
- Melting Point: Not Available
|
||||
- Vapor Pressure: Negligible
|
||||
- Evaporation Rate (n-butyl acetate = 1): Negligible
|
||||
- Volatile Fraction by Weight: Negligible
|
||||
- Specific Gravity (Water = 1): Not Available
|
||||
- Solubility in Water (by Weight): Not Available
|
||||
==============================================================================
|
||||
SECTION IV. FIRE AND EXPLOSION HAZARD DATA
|
||||
|
||||
- Flash Point: Not Applicable
|
||||
- Extinguishing Media: Water spray; Dry chemical; Carbon dioxide
|
||||
- Special Fire Fighting Procedures: Wear self-contained breathing
|
||||
apparatus and protective clothing.
|
||||
- Unusual Fire and Explosion Hazards: Fire or excessive heat may produce
|
||||
hazardous decomposition products.
|
||||
==============================================================================
|
||||
SECTION V. REACTIVITY DATA
|
||||
|
||||
- Stability: Stable
|
||||
- Incompatibility: Strong oxidizers
|
||||
- Hazardous Decomposition Products: Combustion will produce carbon
|
||||
dioxide and probably carbon monoxide. Oxides of nitrogen may also be
|
||||
present.
|
||||
- Hazardous Polymerization: Will not occur.
|
||||
==============================================================================
|
||||
R-0354.000C 85-5404
|
||||
|
||||
-2-
|
||||
|
||||
==============================================================================
|
||||
SECTION VI. TOXICITY AND HEALTH HAZARD DATA
|
||||
|
||||
A. EXPOSURE LIMITS: Not established.
|
||||
|
||||
B. EXPOSURE EFFECTS:
|
||||
Inhalation: Low hazard for usual industrial handling.
|
||||
Skin: Low hazard for usual industrial handling.
|
||||
Eye: No specific hazard known. Contact may cause transient irritation.
|
||||
Ingestion: Expected to be a low ingestion hazard.
|
||||
|
||||
C. FIRST AID:
|
||||
Inhalation: If symptomatic, remove to fresh air. Get medical attention
|
||||
if symptoms persist.
|
||||
Skin: Wash after each contact. Get medical attention if symptoms occur.
|
||||
Eye: Any material that contacts the eye should be washed out
|
||||
immediately with water. Get medical attention if symptoms occur.
|
||||
Ingestion: Drink 1-2 glasses of water. Seek medical attention.
|
||||
==============================================================================
|
||||
SECTION VII. VENTILATION AND PERSONAL PROTECTION
|
||||
|
||||
A. VENTILATION AND RESPIRATORY PROTECTION:
|
||||
Good ventilation* should be sufficient. Supplementary ventilation or
|
||||
respiratory protection may be needed in special circumstances.
|
||||
|
||||
* Typically ten room volumes per hour is considered good general
|
||||
ventilation; ventilation rates should be matched to conditions of use.
|
||||
|
||||
B. SKIN AND EYE PROTECTION:
|
||||
Safety glasses with side shields are recommended in industrial
|
||||
operations involving chemicals.
|
||||
If prolonged or repeated skin contact is necessary, impervious gloves
|
||||
or other protection may be required.
|
||||
==============================================================================
|
||||
SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS
|
||||
|
||||
Keep from contact with oxidizing materials.
|
||||
==============================================================================
|
||||
SECTION IX. SPILL, LEAK, AND DISPOSAL PROCEDURES
|
||||
|
||||
Sweep up material and package for safe feed to an incinerator.
|
||||
Dispose by incineration or contract with licensed chemical waste disposal
|
||||
agency. Discharge, treatment, or disposal may be subject to federal, state
|
||||
or local laws.
|
||||
==============================================================================
|
||||
R-0354.000C 85-5404
|
||||
|
||||
-3-
|
||||
|
||||
==============================================================================
|
||||
SECTION X. ADDITIONAL INFORMATION
|
||||
|
||||
WHMIS STATUS: Noncontrolled Product
|
||||
|
||||
The information contained herein is furnished without warranty of any kind.
|
||||
Users should consider these data only as a supplement to other information
|
||||
gathered by them and must make independent determinations of the suitability
|
||||
and completeness of information from all sources to assure proper use and
|
||||
disposal of these materials and the safety and health of employees and
|
||||
customers.
|
||||
==============================================================================
|
||||
R-0354.000C 85-5404 @120242*
|
||||
|
||||
----------------------------------------------------------------------------
|
||||
273
textfiles.com/science/CHEMICALS/hexachlorobenzene.txt
Normal file
273
textfiles.com/science/CHEMICALS/hexachlorobenzene.txt
Normal file
@@ -0,0 +1,273 @@
|
||||
|
||||
MSDS - Hexachlorobenzene
|
||||
|
||||
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
|
||||
|
||||
+------------+------------------------------------+---------+-----------+
|
||||
| CAS# | Chemical Name | % | EINECS# |
|
||||
|------------|------------------------------------|---------|-----------|
|
||||
| 118-74-1|Hexachlorobenzene, 99% | |unlisted |
|
||||
+------------+------------------------------------+---------+-----------+
|
||||
Hazard Symbols: T+
|
||||
Risk Phrases: 36/37/38 43 45
|
||||
|
||||
|
||||
**** SECTION 3 - HAZARDS IDENTIFICATION ****
|
||||
|
||||
EMERGENCY OVERVIEW
|
||||
Appearance: white fine crystalline powder.
|
||||
|
||||
|
||||
Target Organs: None.
|
||||
|
||||
Potential Health Effects
|
||||
The toxicological properties of this material have not been
|
||||
investigated. Use appropriate procedures to prevent opportunities
|
||||
for direct contact with the skin or eyes and to prevent inhalation.
|
||||
|
||||
|
||||
**** SECTION 4 - FIRST AID MEASURES ****
|
||||
|
||||
Eyes:
|
||||
Immediately flush eyes with plenty of water for at least 15 minutes,
|
||||
occasionally lifting the upper and lower lids.
|
||||
Skin:
|
||||
Flush skin with plenty of soap and water for at least 15 minutes
|
||||
while removing contaminated clothing and shoes.
|
||||
Ingestion:
|
||||
DO NOT induce vomiting. Allow the victim to rinse his mouth and then
|
||||
to drink 2-4 cupfuls of water, and seek medical advice.
|
||||
Inhalation:
|
||||
Remove from exposure to fresh air immediately.
|
||||
Notes to Physician:
|
||||
Treat symptomatically.
|
||||
|
||||
|
||||
**** SECTION 5 - FIRE FIGHTING MEASURES ****
|
||||
|
||||
General Information:
|
||||
As in any fire, wear a self-contained breathing apparatus in
|
||||
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
|
||||
protective gear.
|
||||
Extinguishing Media:
|
||||
In case of fire, use water, dry chemical, chemical foam, or
|
||||
alcohol-resistant foam.
|
||||
Autoignition Temperature: Not available.
|
||||
Flash Point: 242_C (467.60_F)
|
||||
NFPA Rating: Not published.
|
||||
Explosion Limits, Lower: Not available.
|
||||
Upper: Not available.
|
||||
|
||||
|
||||
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
|
||||
|
||||
General Information: Use proper personal protective equipment as indicated
|
||||
in Section 8.
|
||||
Spills/Leaks:
|
||||
Sweep up, then place into a suitable container for disposal.
|
||||
|
||||
|
||||
**** SECTION 7 - HANDLING and STORAGE ****
|
||||
|
||||
Handling:
|
||||
Not available.
|
||||
Storage:
|
||||
Not available.
|
||||
|
||||
|
||||
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
|
||||
|
||||
Engineering Controls:
|
||||
Use adequate general or local exhaust ventilation to keep airborne
|
||||
concentrations below the permissible exposure limits.
|
||||
|
||||
Exposure Limits
|
||||
+--------------------+-------------------+-------------------+-----------------+
|
||||
| Chemical Name | ACGIH | NIOSH |OSHA - Final PELs|
|
||||
|--------------------|-------------------|-------------------|-----------------|
|
||||
| Hexachlorobenzene, |none listed |none listed |none listed |
|
||||
| 99% | | | |
|
||||
+--------------------+-------------------+-------------------+-----------------+
|
||||
|
||||
OSHA Vacated PELs:
|
||||
Hexachlorobenzene, 99%:
|
||||
No OSHA Vacated PELs are listed for this chemical.
|
||||
|
||||
Personal Protective Equipment
|
||||
|
||||
Eyes:
|
||||
Wear safety glasses and chemical goggles if splashing
|
||||
is possible.
|
||||
Skin:
|
||||
Wear appropriate protective gloves and clothing to
|
||||
prevent skin exposure.
|
||||
Clothing:
|
||||
Wear appropriate protective clothing to minimize
|
||||
contact with skin.
|
||||
Respirators:
|
||||
Wear a NIOSH/MSHA-approved (or equivalent)
|
||||
full-facepiece airline respirator in the positive
|
||||
pressure mode with emergency escape provisions.
|
||||
|
||||
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
|
||||
|
||||
Physical State: Not available.
|
||||
Appearance: White fine crystalline powder
|
||||
Odor: None reported.
|
||||
pH: Not available.
|
||||
Vapor Pressure: 1 mbar @ 114 C
|
||||
Vapor Density: Not available.
|
||||
Evaporation Rate: Not available.
|
||||
Viscosity: Not available.
|
||||
Boiling Point: 332.0_C
|
||||
Freezing/Melting Point: 227.00 - 229.00
|
||||
Decomposition Temperature: Not available.
|
||||
Solubility: Insoluble in water.
|
||||
Specific Gravity/Density: Not available.
|
||||
Molecular Formula: C6 Cl6
|
||||
Molecular Weight: Not available.
|
||||
|
||||
|
||||
**** SECTION 10 - STABILITY AND REACTIVITY ****
|
||||
|
||||
Chemical Stability:
|
||||
Stable under normal temperatures and pressures.
|
||||
Conditions to Avoid:
|
||||
Not available.
|
||||
Incompatibilities with Other Materials:
|
||||
Strong oxidizing agents.
|
||||
Hazardous Decomposition Products:
|
||||
Hydrogen chloride, carbon monoxide, carbon dioxide.
|
||||
Hazardous Polymerization: Has not been reported.
|
||||
|
||||
|
||||
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
|
||||
|
||||
RTECS#:
|
||||
CAS# 118-74-1: DA2975000
|
||||
LD50/LC50:
|
||||
CAS# 118-74-1: Inhalation, mouse: LC50 =4 gm/m3; Inhalation, rabbit:
|
||||
LC50 =1800 mg/m3; Inhalation, rat: LC50 =3600 mg/m3; Oral, mouse:
|
||||
LD50 = 4 gm/kg; Oral, rabbit: LD50 = 2600 mg/kg; Oral, rat: LD50 = 10
|
||||
gm/kg.
|
||||
Carcinogenicity:
|
||||
Hexachlorobenzene, 99% -
|
||||
ACGIH: A2-suspected human carcinogen
|
||||
California: carcinogen
|
||||
NIOSH: occupational carcinogen
|
||||
NTP: Suspect carcinogen
|
||||
OSHA: Possible Select carcinogen
|
||||
IARC: Group 2B carcinogen
|
||||
|
||||
|
||||
**** SECTION 12 - ECOLOGICAL INFORMATION ****
|
||||
|
||||
Ecotoxicity:
|
||||
Not available.
|
||||
|
||||
|
||||
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
|
||||
|
||||
Dispose of in a manner consistent with federal, state, and local regulations.
|
||||
RCRA D-Series Maximum Concentration of Contaminants: waste number D032; regulato
|
||||
RCRA D-Series Chronic Toxicity Reference Levels: chronic toxicity reference leve
|
||||
RCRA F-Series: Not listed.
|
||||
RCRA P-Series: Not listed.
|
||||
RCRA U-Series: waste number U127
|
||||
This material is banned from land disposal according to RCRA.
|
||||
|
||||
|
||||
**** SECTION 14 - TRANSPORT INFORMATION ****
|
||||
|
||||
US DOT
|
||||
Shipping Name: HEXACHLOROBENZENE
|
||||
Hazard Class: 6.1
|
||||
UN Number: UN2729
|
||||
Packing Group: III
|
||||
IMO
|
||||
Shipping Name: HEXACHLOROBENZENE
|
||||
Hazard Class: 6.1
|
||||
UN Number: 2729
|
||||
Packing Group: 3
|
||||
IATA
|
||||
Shipping Name: HEXACHLOROBENZENE
|
||||
Hazard Class: 6.1
|
||||
UN Number: 2729
|
||||
Packing Group: 3
|
||||
RID/ADR
|
||||
Shipping Name: HEXACHLOROBENZENE
|
||||
Dangerous Goods Code: 6.1(17C)
|
||||
UN Number: 2729
|
||||
Canadian TDG
|
||||
No information available.
|
||||
|
||||
|
||||
**** SECTION 15 - REGULATORY INFORMATION ****
|
||||
|
||||
A. Federal
|
||||
TSCA
|
||||
CAS# 118-74-1 is listed on the TSCA inventory.
|
||||
Health & Safety Reporting List
|
||||
None of the chemicals are on the Health & Safety Reporting List.
|
||||
Chemical Test Rules
|
||||
None of the chemicals in this product are under a Chemical Test Rule.
|
||||
Section 12b
|
||||
None of the chemicals are listed under TSCA Section 12b.
|
||||
TSCA Significant New Use Rule
|
||||
None of the chemicals in this material have a SNUR under TSCA.
|
||||
CERCLA/SARA
|
||||
Section 302 (RQ)
|
||||
None of the chemicals in this material have an RQ.
|
||||
Section 302 (TPQ)
|
||||
None of the chemicals in this product have a TPQ.
|
||||
Section 313
|
||||
This chemical is not at a high enough concentration to be reportable
|
||||
under Section 313.
|
||||
No chemicals are reportable under Section 313.
|
||||
Clean Air Act:
|
||||
CAS# 118-74-1 is listed as a hazardous air pollutant (HAP).
|
||||
This material does not contain any Class 1 Ozone depletors.
|
||||
This material does not contain any Class 2 Ozone depletors.
|
||||
Clean Water Act:
|
||||
None of the chemicals in this product are listed as Hazardous
|
||||
Substances under the CWA.
|
||||
CAS# 118-74-1 is listed as a Priority Pollutant under the Clean Water
|
||||
Act.
|
||||
None of the chemicals in this product are listed as Toxic Pollutants
|
||||
under the CWA.
|
||||
OSHA:
|
||||
None of the chemicals in this product are considered highly hazardous
|
||||
by OSHA.
|
||||
B. State
|
||||
Hexachlorobenzene, 99% can be found on the following state right to
|
||||
know lists: New Jersey, Florida, Pennsylvania, Minnesota,
|
||||
Massachusetts.
|
||||
The following statement(s) is(are) made in order to comply with
|
||||
the California Safe Drinking Water Act:
|
||||
This product contains Hexachlorobenzene, 99%, a chemical known to the
|
||||
state of California to cause cancer.
|
||||
This product contains Hexachlorobenzene, 99%, a chemical known to the
|
||||
state of California to cause developmental effects.
|
||||
California No Significant Risk Level:
|
||||
CAS# 118-74-1: no significant risk level = 0.4 ug/day
|
||||
C. International
|
||||
Canada
|
||||
CAS# 118-74-1 is listed on Canada's DSL/NDSL List.
|
||||
CAS# 118-74-1 is listed on Canada's Ingredient Disclosure List.
|
||||
European Labeling in Accordance with EC Directives
|
||||
Hazard Symbols: T+
|
||||
Risk Phrases:
|
||||
R 36/37/38 Irritating to eyes, respiratory system
|
||||
and skin.
|
||||
R 43 May cause sensitization by skin contact.
|
||||
R 45 May cause cancer.
|
||||
Safety Phrases:
|
||||
S 44 If you feel unwell, seek medical advice (show
|
||||
the label where possible).
|
||||
S 53 Avoid exposure - obtain special instructions
|
||||
before use.
|
||||
Exposure Limits:
|
||||
OEL-CZECHOSLOVAKIA:TWA 1 mg/m3;STEL 2 mg/m3. OEL-FRANCE;Carcinogen. OE
|
||||
L-RUSSIA:STEL 0.9 mg/m3;Skin
|
||||
|
||||
|
||||
117
textfiles.com/science/CHEMICALS/hexachloroethane.txt
Normal file
117
textfiles.com/science/CHEMICALS/hexachloroethane.txt
Normal file
@@ -0,0 +1,117 @@
|
||||
|
||||
MSDS - HEXACHLOROETHANE
|
||||
|
||||
SECTION I. IDENTIFICATION
|
||||
|
||||
- Product Name: Hexachloroethane
|
||||
- Synonym(s): Perchloroethane
|
||||
- Formula: C2 Cl6
|
||||
==============================================================================
|
||||
|
||||
SECTION II. PRODUCT AND COMPONENT HAZARD DATA
|
||||
ACGIH
|
||||
COMPONENT(S): Percent TLV(R) CAS Reg. No.
|
||||
|
||||
Hexachloroethane ca. 100 10 ppm 67-72-1
|
||||
==============================================================================
|
||||
|
||||
SECTION III. PHYSICAL DATA
|
||||
|
||||
- Appearance and odor: Colorless crystals; camphor-like odor
|
||||
- Melting Point: 187 C (369 F)
|
||||
- Vapor Pressure: Negligible
|
||||
- Evaporation Rate (n-butyl acetate = 1): 2.1
|
||||
- Volatile Fraction by Weight: Negligible
|
||||
- Specific Gravity (Water = 1): 2.09
|
||||
- Solubility in Water: Negligible
|
||||
==============================================================================
|
||||
|
||||
SECTION IV. FIRE AND EXPLOSION HAZARD DATA
|
||||
|
||||
- Flash Point: Noncombustible
|
||||
- Extinguishing Media: Use appropriate agent for surrounding fire.
|
||||
- Special Fire Fighting Procedures: Wear self-contained breathing
|
||||
apparatus and protective clothing.
|
||||
- Unusual Fire and Explosion Hazards: Fire or excessive heat may produce
|
||||
hazardous decomposition products. May react with metals and alkalies
|
||||
forming spontaneously explosive materials.
|
||||
==============================================================================
|
||||
|
||||
SECTION V. REACTIVITY DATA
|
||||
|
||||
- Stability: Stable
|
||||
- Incompatibility: Strong oxidizers, strong bases, metals
|
||||
- Hazardous Decomposition Products: Thermal decomposition may produce
|
||||
carbon dioxide and carbon monoxide. Hydrogen chloride gas and phosgene
|
||||
may also be present.
|
||||
- Hazardous Polymerization: Will not occur.
|
||||
==============================================================================
|
||||
|
||||
SECTION VI. TOXICITY AND HEALTH HAZARD DATA
|
||||
|
||||
A. EXPOSURE LIMITS:
|
||||
Threshold Limit Value (TLV): 1 ppm, 8-hr TWA, ACGIH 1990-1991.
|
||||
Permissible Exposure Limit (PEL): 1 ppm (skin), OSHA.
|
||||
|
||||
B. EXPOSURE EFFECTS: Exposure to high concentrations may cause liver and
|
||||
kidney damage.
|
||||
|
||||
Carcinogenicity Status: Hexachloroethane has been identified as a
|
||||
carcinogen or potential carcinogen for hazard communication purposes by:
|
||||
|
||||
California: WARNING. Hexachloroethane is known to the State of
|
||||
California to cause cancer.
|
||||
|
||||
Inhalation: Harmful if inhaled. Dust or vapor irritating to the
|
||||
respiratory tract.
|
||||
Skin: Harmful if absorbed through the skin.
|
||||
Eye: Causes eye irritation.
|
||||
Ingestion: Harmful if swallowed. Ingestion of large amounts may cause
|
||||
central nervous system depression based on animal data.
|
||||
|
||||
C. FIRST AID:
|
||||
Inhalation: Remove to fresh air. Treat symptomatically. If symptoms
|
||||
are present get medical attention.
|
||||
Skin: In case of contact, immediately flush skin with plenty of water
|
||||
for at least 15 minutes while removing contaminated clothing and
|
||||
shoes. Wash contaminated clothing before reuse. Destroy or thoroughly
|
||||
clean contaminated shoes. If symptoms are present after washing, get
|
||||
medical attention.
|
||||
Eye: Immediately flush eyes with plenty of water for at least 15
|
||||
minutes and get medical attention.
|
||||
Ingestion: If swallowed, induce vomiting immediately as directed by
|
||||
medical personnel. Never give anything by mouth to an unconscious
|
||||
person. Call a physician or poison control center immediately.
|
||||
==============================================================================
|
||||
|
||||
SECTION VII. VENTILATION AND PERSONAL PROTECTION
|
||||
|
||||
A. VENTILATION:
|
||||
Use process enclosures, local exhaust ventilation or other engineering
|
||||
controls to reduce dust concentrations to an acceptable level.
|
||||
|
||||
B. RESPIRATORY PROTECTION:
|
||||
If engineering controls are inadequate to control dust concentrations
|
||||
to an acceptable level, a NIOSH-approved dust or vapor respirator
|
||||
should be worn if needed. If respirators are used, a program should be
|
||||
instituted to assure compliance with OSHA Standard 29 CFR 1910.134.
|
||||
|
||||
C. SKIN AND EYE PROTECTION:
|
||||
Protective gloves and clothing should be worn. Safety glasses, goggles,
|
||||
or a face shield should be worn.
|
||||
==============================================================================
|
||||
|
||||
SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS
|
||||
|
||||
Keep from contact with oxidizing materials, metals or bases. Do not store
|
||||
in metal containers.
|
||||
==============================================================================
|
||||
|
||||
SECTION IX. SPILL, LEAK, AND DISPOSAL PROCEDURES
|
||||
|
||||
Sweep up material and package for safe feed to an incinerator. Dispose by
|
||||
incineration or contract with licensed chemical waste disposal agency.
|
||||
Discharge, treatment, or disposal may be subject to federal, state or local
|
||||
laws.
|
||||
|
||||
|
||||
184
textfiles.com/science/CHEMICALS/hexamine.txt
Normal file
184
textfiles.com/science/CHEMICALS/hexamine.txt
Normal file
@@ -0,0 +1,184 @@
|
||||
|
||||
MSDS - HEXAMETHYLENETETRAMINE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: HEXAMETHYLENETETRAMINE
|
||||
FORMULA: (CH2)6N4
|
||||
FORMULA WT: 140.19
|
||||
CAS NO.: 00100-97-0
|
||||
NIOSH/RTECS NO.: MN4725000
|
||||
COMMON SYNONYMS: METHENAMINE; UROTROPIN; HMTA ; HEXAFORM
|
||||
PRODUCT CODES: N145
|
||||
EFFECTIVE: 05/06/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; CLASS B EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
CAUSES IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): 4.9
|
||||
|
||||
SPECIFIC GRAVITY: 1.30 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE CRYSTALLINE POWDER WITH MILD AMINE ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP 250 C ( 482 F)
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
GIVES OFF IRRITATING VAPORS.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
AMMONIA, FORMALDEHYDE, NITROGEN OXIDES, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (IV-RAT) (MG/KG) - 9200
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
PROLONGED CONTACT MAY CAUSE SKIN SENSITIZATION.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, MOISTURE
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS, STRONG OXIDIZING AGENTS
|
||||
|
||||
DECOMPOSITION PRODUCTS: AMMONIA, FORMALDEHYDE, OXIDES OF NITROGEN,
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
|
||||
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
|
||||
WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
|
||||
AWAY FROM HEAT, SPARKS, OR FLAME.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME HEXAMINE
|
||||
HAZARD CLASS 4.1
|
||||
UN/NA UN1328
|
||||
LABELS FLAMMABLE SOLID
|
||||
|
||||
183
textfiles.com/science/CHEMICALS/iron.txt
Normal file
183
textfiles.com/science/CHEMICALS/iron.txt
Normal file
@@ -0,0 +1,183 @@
|
||||
|
||||
MSDS - IRON
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: IRON
|
||||
FORMULA: FE
|
||||
FORMULA WT: 55.85
|
||||
CAS NO.: 07439-89-6
|
||||
COMMON SYNONYMS: METALLIC IRON; ELEMENTAL IRON;STEEL
|
||||
PRODUCT CODES: 2228,2234,2230,2226
|
||||
EFFECTIVE: 06/25/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 0 NONE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; CLASS D EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF INHALED
|
||||
DUST MAY FORM FLAMMABLE AND EXPLOSIVE MIXTURE WITH AIR, ESPECIALLY
|
||||
WHEN DAMP.
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
DO NOT USE WATER. USE DRY SAND, EARTH OR SODA ASH. IN CASE OF SPILL,
|
||||
SWEEP UP AND CAREFULLY REMOVE.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
IRON 90-100 7439-89-6
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 3000 C ( 5432 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1535 C ( 2795 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 7.86 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: GRAY CRYSTALLINE POWDER OR CHIPS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE POWDERED GRAPHITE, POWDERED SALT, OR POWDERED LIMESTONE.
|
||||
DO NOT USE WATER, CARBON DIOXIDE, OR DRY CHEMICAL.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
PROLONGED CONTACT MAY CAUSE SKIN IRRITATION.
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
CHRONIC EFFECTS INCUDE IRRITATION OF SKIN, EYES, NOSE, THROAT, AND LUNGS.
|
||||
NOTE: PRODUCT IS A SOLID MASS; HOWEVER, WARNINGS ARE BASED ON INHALATION
|
||||
OF
|
||||
DUST, MIST OR FUME EMISSIONS THAT ARE POSSIBLE DURING MANUFACTURING OR
|
||||
CHEMICAL REACTIONS.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
|
||||
WASH CLOTHING BEFORE RE-USE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE, HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: ORGANIC ACIDS, STRONG OXIDIZING AGENTS, WATER,
|
||||
MINERAL ACIDS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
|
||||
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
|
||||
WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, A DUST/MIST RESPIRATOR IS RECOMMENDED.
|
||||
IF CONCENTRATION EXCEEDS CAPACITY OF RESPIRATOR,
|
||||
A SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
|
||||
AWAY FROM HEAT, SPARKS, OR FLAME.
|
||||
DO NOT STORE NEAR OXIDIZING MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
183
textfiles.com/science/CHEMICALS/iron_filings.txt
Normal file
183
textfiles.com/science/CHEMICALS/iron_filings.txt
Normal file
@@ -0,0 +1,183 @@
|
||||
|
||||
MSDS - IRON
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: IRON
|
||||
FORMULA: FE
|
||||
FORMULA WT: 55.85
|
||||
CAS NO.: 07439-89-6
|
||||
COMMON SYNONYMS: METALLIC IRON; ELEMENTAL IRON;STEEL
|
||||
PRODUCT CODES: 2228,2234,2230,2226
|
||||
EFFECTIVE: 06/25/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 0 NONE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; CLASS D EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF INHALED
|
||||
DUST MAY FORM FLAMMABLE AND EXPLOSIVE MIXTURE WITH AIR, ESPECIALLY
|
||||
WHEN DAMP.
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
DO NOT USE WATER. USE DRY SAND, EARTH OR SODA ASH. IN CASE OF SPILL,
|
||||
SWEEP UP AND CAREFULLY REMOVE.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
IRON 90-100 7439-89-6
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 3000 C ( 5432 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1535 C ( 2795 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 7.86 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: GRAY CRYSTALLINE POWDER OR CHIPS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE POWDERED GRAPHITE, POWDERED SALT, OR POWDERED LIMESTONE.
|
||||
DO NOT USE WATER, CARBON DIOXIDE, OR DRY CHEMICAL.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
PROLONGED CONTACT MAY CAUSE SKIN IRRITATION.
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
CHRONIC EFFECTS INCUDE IRRITATION OF SKIN, EYES, NOSE, THROAT, AND LUNGS.
|
||||
NOTE: PRODUCT IS A SOLID MASS; HOWEVER, WARNINGS ARE BASED ON INHALATION
|
||||
OF
|
||||
DUST, MIST OR FUME EMISSIONS THAT ARE POSSIBLE DURING MANUFACTURING OR
|
||||
CHEMICAL REACTIONS.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
|
||||
WASH CLOTHING BEFORE RE-USE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE, HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: ORGANIC ACIDS, STRONG OXIDIZING AGENTS, WATER,
|
||||
MINERAL ACIDS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
|
||||
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
|
||||
WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, A DUST/MIST RESPIRATOR IS RECOMMENDED.
|
||||
IF CONCENTRATION EXCEEDS CAPACITY OF RESPIRATOR,
|
||||
A SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
|
||||
AWAY FROM HEAT, SPARKS, OR FLAME.
|
||||
DO NOT STORE NEAR OXIDIZING MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
164
textfiles.com/science/CHEMICALS/iron_iii_oxide.txt
Normal file
164
textfiles.com/science/CHEMICALS/iron_iii_oxide.txt
Normal file
@@ -0,0 +1,164 @@
|
||||
|
||||
MSDS - FERRIC OXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: FERRIC OXIDE
|
||||
FORMULA: FE2O3
|
||||
FORMULA WT: 159.69
|
||||
CAS NO.: 1309-37-1
|
||||
NIOSH/RTECS NO.: NO7400000
|
||||
COMMON SYNONYMS: IRON(III)OXIDE; RED IRON OXIDE; C.I. 77491
|
||||
PRODUCT CODES: 2024
|
||||
EFFECTIVE: 05/05/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
FERRIC OXIDE 90-100 1309-37-1
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1565 C ( 2849 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 5.24 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: RED TO REDDISH-BROWN, ODORLESS POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 5 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE EYES.
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
183
textfiles.com/science/CHEMICALS/iron_powder.txt
Normal file
183
textfiles.com/science/CHEMICALS/iron_powder.txt
Normal file
@@ -0,0 +1,183 @@
|
||||
|
||||
MSDS - IRON
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: IRON
|
||||
FORMULA: FE
|
||||
FORMULA WT: 55.85
|
||||
CAS NO.: 07439-89-6
|
||||
COMMON SYNONYMS: METALLIC IRON; ELEMENTAL IRON;STEEL
|
||||
PRODUCT CODES: 2228,2234,2230,2226
|
||||
EFFECTIVE: 06/25/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 0 NONE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; CLASS D EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF INHALED
|
||||
DUST MAY FORM FLAMMABLE AND EXPLOSIVE MIXTURE WITH AIR, ESPECIALLY
|
||||
WHEN DAMP.
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
DO NOT USE WATER. USE DRY SAND, EARTH OR SODA ASH. IN CASE OF SPILL,
|
||||
SWEEP UP AND CAREFULLY REMOVE.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
IRON 90-100 7439-89-6
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 3000 C ( 5432 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 1535 C ( 2795 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 7.86 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: GRAY CRYSTALLINE POWDER OR CHIPS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE POWDERED GRAPHITE, POWDERED SALT, OR POWDERED LIMESTONE.
|
||||
DO NOT USE WATER, CARBON DIOXIDE, OR DRY CHEMICAL.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
PROLONGED CONTACT MAY CAUSE SKIN IRRITATION.
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
CHRONIC EFFECTS INCUDE IRRITATION OF SKIN, EYES, NOSE, THROAT, AND LUNGS.
|
||||
NOTE: PRODUCT IS A SOLID MASS; HOWEVER, WARNINGS ARE BASED ON INHALATION
|
||||
OF
|
||||
DUST, MIST OR FUME EMISSIONS THAT ARE POSSIBLE DURING MANUFACTURING OR
|
||||
CHEMICAL REACTIONS.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
|
||||
WASH CLOTHING BEFORE RE-USE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE, HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: ORGANIC ACIDS, STRONG OXIDIZING AGENTS, WATER,
|
||||
MINERAL ACIDS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
|
||||
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
|
||||
WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, A DUST/MIST RESPIRATOR IS RECOMMENDED.
|
||||
IF CONCENTRATION EXCEEDS CAPACITY OF RESPIRATOR,
|
||||
A SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
|
||||
AWAY FROM HEAT, SPARKS, OR FLAME.
|
||||
DO NOT STORE NEAR OXIDIZING MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
217
textfiles.com/science/CHEMICALS/isopropyl_alcohol.txt
Normal file
217
textfiles.com/science/CHEMICALS/isopropyl_alcohol.txt
Normal file
@@ -0,0 +1,217 @@
|
||||
|
||||
MSDS - ISOPROPYL ALCOHOL
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: ISOPROPYL ALCOHOL
|
||||
FORMULA: CH3CHOHCH3
|
||||
FORMULA WT: 60.10
|
||||
CAS NO.: 67-63-0
|
||||
NIOSH/RTECS NO.: NT805000
|
||||
COMMON SYNONYMS: 2-PROPANOL; ISOPROPANOL; SEC-PROPYL ALCOHOL; IPA;
|
||||
DIMETHYLCARBINOL
|
||||
PRODUCT CODES: U298,5082,9080
|
||||
EFFECTIVE: 09/03/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
FLAMMABLE
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE.
|
||||
FLUSH SPILL AREA WITH WATER SPRAY.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
ISOPROPYL ALCOHOL 90-100 67-63-0
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 82 C ( 180 F) VAPOR PRESSURE(MM HG): 33
|
||||
|
||||
MELTING POINT: -89 C ( -128 F) VAPOR DENSITY(AIR=1): 2.1
|
||||
|
||||
SPECIFIC GRAVITY: 0.79 EVAPORATION RATE: 2.83
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100
|
||||
|
||||
APPEARANCE & ODOR: COLORLESS LIQUID WITH SLIGHT ODOR OF RUBBING ALCOHOL.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP 12 C ( 53 F) NFPA 704M RATING: 1-3-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 12.0 % LOWER - 2.0 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
(WATER MAY BE INEFFECTIVE.)
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK.
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG
|
||||
OXIDIZERS MAY CAUSE FIRE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 980 MG/M3 ( 400 PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 1225 MG/M3 ( 500 PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 980 MG/M3 ( 400 PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 5045
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 933
|
||||
LD50 (SKN-RABBIT) (G/KG) - 13
|
||||
LD50 (IV-MOUSE) (MG/KG) - 1863
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF VAPORS MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS,
|
||||
DROWSINESS, IRRITATION OF RESPIRATORY TRACT, AND LOSS OF CONSCIOUSNESS.
|
||||
INHALATION OF VAPORS MAY CAUSE PULMONARY EDEMA.
|
||||
LIQUID MAY BE IRRITATING TO SKIN AND EYES. PROLONGED SKIN CONTACT MAY
|
||||
RESULT IN DERMATITIS. EYE CONTACT MAY RESULT IN TEMPORARY CORNEAL DAMAGE.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN, RESPIRATORY SYSTEM
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, DO NOT INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, ALUMINUM, NITRIC ACID,
|
||||
SULFURIC ACID, AMINES AND AMMONIA,
|
||||
HALOGEN ACIDS AND HALOGEN COMPOUNDS
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE
|
||||
WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE
|
||||
ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH
|
||||
AREA WITH WATER.
|
||||
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED
|
||||
FOR SPILLS OF THIS PRODUCT.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 1000 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH
|
||||
ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE
|
||||
THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS RECOMMENDED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, NEOPRENE GLOVES
|
||||
ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. KEEP CONTAINER
|
||||
TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID
|
||||
STORAGE AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME ISOPROPANOL
|
||||
HAZARD CLASS FLAMMABLE LIQUID
|
||||
UN/NA UN1219
|
||||
LABELS FLAMMABLE LIQUID
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME ISOPROPANOL
|
||||
HAZARD CLASS 3.2
|
||||
UN/NA UN1219
|
||||
LABELS FLAMMABLE LIQUID
|
||||
|
||||
161
textfiles.com/science/CHEMICALS/kaolin.txt
Normal file
161
textfiles.com/science/CHEMICALS/kaolin.txt
Normal file
@@ -0,0 +1,161 @@
|
||||
|
||||
MSDS - KAOLIN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: KAOLIN
|
||||
FORMULA: AL2O3 2SIO2 2H2O
|
||||
FORMULA WT: .00
|
||||
CAS NO.: 01332-58-7
|
||||
COMMON SYNONYMS: KAOLINITE; CHINA CLAY; BOLUS ALBA; PORCELAIN CLAY
|
||||
PRODUCT CODES: 2242,2240
|
||||
EFFECTIVE: 06/30/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 0 NONE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
KAOLIN 90-100 1332-58-7
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.60 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE TO YELLOWISH OR GRAY POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 20 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
PROLONGED CONTACT MAY CAUSE SKIN IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS
|
||||
ABOVE 10 MG/M3, A DUST/MIST RESPIRATOR IS
|
||||
RECOMMENDED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
167
textfiles.com/science/CHEMICALS/kieselguhr.txt
Normal file
167
textfiles.com/science/CHEMICALS/kieselguhr.txt
Normal file
@@ -0,0 +1,167 @@
|
||||
|
||||
MSDS - DIATOMACEOUS EARTH
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: DIATOMACEOUS EARTH
|
||||
FORMULA:
|
||||
FORMULA WT: .00
|
||||
CAS NO.: 68855-54-9
|
||||
COMMON SYNONYMS: DIATOMITE; CELITE; KIESELGUHR SODA ASH FLUX CALCINED
|
||||
PRODUCT CODES: 1939,1939
|
||||
EFFECTIVE: 09/26/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
MAY CAUSE IRRITATION
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
DIATOMACEOUS EARTH 90-100 68855-54-9
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.30 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): SLIGHT (0.1 TO 1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE TO PALE GRAY TO PALE BUFF POWDER WITH NO ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
OXIDES OF SILICON
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
PROLONGED EXPOSURE TO EXCESSIVE CONCENTRATIONS OF DUST MAY CAUSE PULMONARY
|
||||
DISEASE.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: HYDROGEN FLUORIDE
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF SILICON
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
159
textfiles.com/science/CHEMICALS/lactose.txt
Normal file
159
textfiles.com/science/CHEMICALS/lactose.txt
Normal file
@@ -0,0 +1,159 @@
|
||||
|
||||
MSDS - D-(+)-LACTOSE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: D-(+)-LACTOSE
|
||||
FORMULA: C12H22O11
|
||||
FORMULA WT: 342.30
|
||||
CAS NO.: 63-42-3
|
||||
NIOSH/RTECS NO.: OO9625000
|
||||
COMMON SYNONYMS: B-LACTOSE; MILK SUGAR; 4-0-BETA-D-GALACTOPYRANOSYL-D-GLUCOSE
|
||||
PRODUCT CODES: P347
|
||||
EFFECTIVE: 06/09/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 0 NONE
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 0 NONE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 1.53 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE CRYSTALLINE POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
NO EFFECTS OF OVEREXPOSURE WERE DOCUMENTED.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
106
textfiles.com/science/CHEMICALS/lampblack.txt
Normal file
106
textfiles.com/science/CHEMICALS/lampblack.txt
Normal file
@@ -0,0 +1,106 @@
|
||||
|
||||
|
||||
|
||||
|
||||
M A T E R I A L S A F E T Y D A T A S H E E T
|
||||
CARBON (LAMPBLACK)
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
MANUFACTURERS NAME : PFIZER INC.,MINERALS,PIGMENTS,METALS
|
||||
EMERGENCY TEL. NO. : (212)573-2816
|
||||
PREPARATION DATE : 05/07/86
|
||||
INFORMATION TEL. NO. : ( ) -
|
||||
PRODUCT NUMBER : 00575
|
||||
PRODUCT NAME : CARBON (LAMPBLACK)
|
||||
PRODUCT CLASS : NONE
|
||||
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
NONE LISTED
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING RANGE : NA VAPOUR DENSITY(AIR=1) : NA
|
||||
EVAPORATION RATE: NA VOLATILE VOLUME : 1.8 WT/GAL: NA
|
||||
OTHER PROPERTIES :
|
||||
BLACK POWDER
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
SPECIAL PRECAUTIONS :
|
||||
AWAY FROM STRONG OXIDIZING AGENTS
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
DISPOSAL PROCEDURE :
|
||||
RECLAIM FOR USE OR REMOVE TO DUMP
|
||||
OTHER PRECAUTIONS :
|
||||
NONE
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
RESPIRATORY PROTECTION :
|
||||
FULTER MASK
|
||||
VENTILATION :
|
||||
GENERAL MECH
|
||||
SKIN PROTECTION :
|
||||
NONE
|
||||
EYE PROTECTION :
|
||||
SAFETY GOGGLES
|
||||
OTHER PROTECTIVE EQUIPMENT :
|
||||
NONE
|
||||
HYGIENIC PRACTICES :
|
||||
NONE
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
FLAMMABILITY CLASSIFICATION : NONE
|
||||
FLASH POINT : NA
|
||||
FLAMMABLE LIMITS UPPER - NA LOWER - NA
|
||||
EXTINGUISHING MEDIA :
|
||||
WATER
|
||||
UNUSUAL FIRE AND EXPLOSION HAZARDS :
|
||||
NONE
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES :
|
||||
NONE
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
STABILITY : STABLE
|
||||
HAZARDOUS POLYMERIZATION : WILL NOT OCCUR
|
||||
HAZARDOUS DECOMPOSITION PRODUCTS :
|
||||
NONE
|
||||
CONDITIONS TO AVOID :
|
||||
NONE
|
||||
INCOMPATIBILITY ( MATERIALS TO AVOID ) :
|
||||
STRONG OXIDIZING AGENT
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
EFFECTS OF OVEREXPOSURE :
|
||||
RESP/IRR
|
||||
MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE :
|
||||
NONE
|
||||
PRIMARY ROUTE(S) OF ENTRY : EYE/SKIN
|
||||
EMERGENCY AND FIRST AID PROCEDURES :
|
||||
EYE/SKIN/WASH W/WATER-SEE DR FOR EYES
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
N/A
|
||||
|
||||
--------------------------------------------------------------------------------
|
||||
(TM) and (R) : Registered Trademarks
|
||||
N/A = Not Applicable OR Not Available
|
||||
The information published in this Material Safety Data Sheet has been compiled
|
||||
from our experience and data presented in various technical publications. It is
|
||||
the user's responsibility to determine the suitability of this information for
|
||||
adoption of necessary safety precautions. We reserve the right to revise
|
||||
Material Safety Data Sheets periodically as new information becomes available.
|
||||
Copyright by Manufacturer
|
||||
LICENSE GRANTED TO MAKE UNLIMITED COPIES FOR INTERNAL USE ONLY
|
||||
by OREGON STATE UNIVERSITY
|
||||
.
|
||||
106
textfiles.com/science/CHEMICALS/lampblack_conductive.txt
Normal file
106
textfiles.com/science/CHEMICALS/lampblack_conductive.txt
Normal file
@@ -0,0 +1,106 @@
|
||||
|
||||
|
||||
|
||||
|
||||
M A T E R I A L S A F E T Y D A T A S H E E T
|
||||
CARBON (LAMPBLACK)
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
MANUFACTURERS NAME : PFIZER INC.,MINERALS,PIGMENTS,METALS
|
||||
EMERGENCY TEL. NO. : (212)573-2816
|
||||
PREPARATION DATE : 05/07/86
|
||||
INFORMATION TEL. NO. : ( ) -
|
||||
PRODUCT NUMBER : 00575
|
||||
PRODUCT NAME : CARBON (LAMPBLACK)
|
||||
PRODUCT CLASS : NONE
|
||||
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
NONE LISTED
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING RANGE : NA VAPOUR DENSITY(AIR=1) : NA
|
||||
EVAPORATION RATE: NA VOLATILE VOLUME : 1.8 WT/GAL: NA
|
||||
OTHER PROPERTIES :
|
||||
BLACK POWDER
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
SPECIAL PRECAUTIONS :
|
||||
AWAY FROM STRONG OXIDIZING AGENTS
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
DISPOSAL PROCEDURE :
|
||||
RECLAIM FOR USE OR REMOVE TO DUMP
|
||||
OTHER PRECAUTIONS :
|
||||
NONE
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
RESPIRATORY PROTECTION :
|
||||
FULTER MASK
|
||||
VENTILATION :
|
||||
GENERAL MECH
|
||||
SKIN PROTECTION :
|
||||
NONE
|
||||
EYE PROTECTION :
|
||||
SAFETY GOGGLES
|
||||
OTHER PROTECTIVE EQUIPMENT :
|
||||
NONE
|
||||
HYGIENIC PRACTICES :
|
||||
NONE
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
FLAMMABILITY CLASSIFICATION : NONE
|
||||
FLASH POINT : NA
|
||||
FLAMMABLE LIMITS UPPER - NA LOWER - NA
|
||||
EXTINGUISHING MEDIA :
|
||||
WATER
|
||||
UNUSUAL FIRE AND EXPLOSION HAZARDS :
|
||||
NONE
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES :
|
||||
NONE
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
STABILITY : STABLE
|
||||
HAZARDOUS POLYMERIZATION : WILL NOT OCCUR
|
||||
HAZARDOUS DECOMPOSITION PRODUCTS :
|
||||
NONE
|
||||
CONDITIONS TO AVOID :
|
||||
NONE
|
||||
INCOMPATIBILITY ( MATERIALS TO AVOID ) :
|
||||
STRONG OXIDIZING AGENT
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
EFFECTS OF OVEREXPOSURE :
|
||||
RESP/IRR
|
||||
MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE :
|
||||
NONE
|
||||
PRIMARY ROUTE(S) OF ENTRY : EYE/SKIN
|
||||
EMERGENCY AND FIRST AID PROCEDURES :
|
||||
EYE/SKIN/WASH W/WATER-SEE DR FOR EYES
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
N/A
|
||||
|
||||
--------------------------------------------------------------------------------
|
||||
(TM) and (R) : Registered Trademarks
|
||||
N/A = Not Applicable OR Not Available
|
||||
The information published in this Material Safety Data Sheet has been compiled
|
||||
from our experience and data presented in various technical publications. It is
|
||||
the user's responsibility to determine the suitability of this information for
|
||||
adoption of necessary safety precautions. We reserve the right to revise
|
||||
Material Safety Data Sheets periodically as new information becomes available.
|
||||
Copyright by Manufacturer
|
||||
LICENSE GRANTED TO MAKE UNLIMITED COPIES FOR INTERNAL USE ONLY
|
||||
by OREGON STATE UNIVERSITY
|
||||
.
|
||||
35
textfiles.com/science/CHEMICALS/lead_azide.txt
Normal file
35
textfiles.com/science/CHEMICALS/lead_azide.txt
Normal file
@@ -0,0 +1,35 @@
|
||||
SUBSTANCE NAME: Lead azide
|
||||
CAS Number: 13424-46-9
|
||||
|
||||
UN Number: 0129
|
||||
|
||||
CLASSIFICATION OF PURE SUBSTANCE
|
||||
Risk Phrases:
|
||||
|
||||
R3 Extreme risk of explosion by shock, friction, fire or other
|
||||
sources of ignition.
|
||||
|
||||
R20/22 Harmful by inhalation and if swallowed.
|
||||
|
||||
R33 Danger of cumulative effects.
|
||||
|
||||
Safety Phrases:
|
||||
|
||||
S33 Take precautionary measures against static discharges.
|
||||
|
||||
S34 Avoid shock and friction.
|
||||
|
||||
S35 This material and its container must be disposed of in a safe
|
||||
way.
|
||||
|
||||
CLASSIFICATION OF SUBSTANCE AS AN INGREDIENT IN MIXTURE
|
||||
Health Hazard Classification : Harmful
|
||||
Concentration Cut-off level : 25 % weight/weight
|
||||
|
||||
Above this concentration ingredient to be classified with R20
|
||||
and/or R21 and/or R22.
|
||||
|
||||
When classifying a substance as an ingredient in a mixture at a
|
||||
particular concentration cut-off level take into account any
|
||||
risk phrases that apply at the lower concentration cut-off level.
|
||||
|
||||
186
textfiles.com/science/CHEMICALS/lead_chloride.txt
Normal file
186
textfiles.com/science/CHEMICALS/lead_chloride.txt
Normal file
@@ -0,0 +1,186 @@
|
||||
|
||||
MSDS - LEAD CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: LEAD CHLORIDE
|
||||
FORMULA: PBCL2
|
||||
FORMULA WT: 278.10
|
||||
CAS NO.: 07758-95-4
|
||||
NIOSH/RTECS NO.: OF9450000
|
||||
COMMON SYNONYMS: LEAD(II)CHLORIDE; LEAD DICHLORIDE
|
||||
PRODUCT CODES: 2308,2310,5195
|
||||
EFFECTIVE: 10/17/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (LIFE)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
EXCEPTIONAL HEALTH HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
LEAD CHLORIDE 90-100 7758-95-4
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 950 C ( 1742 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 501 C ( 934 F) VAPOR DENSITY(AIR=1): 9.6
|
||||
|
||||
SPECIFIC GRAVITY: 5.85 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: ODORLESS,WHITE CRYSTALLINE POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A NFPA 704M RATING: 4-0-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CHLORINE, HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.15 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CHRONIC EFFECTS RESULTING FROM LOW LEVEL EXPOSURE TO LEAD COMPOUNDS
|
||||
MAY INCLUDE ANEMIA, KIDNEY DAMAGE, IMPAIRED EYESIGHT, AND LEAD
|
||||
BUILD-UP IN THE CENTRAL NERVOUS SYSTEM (PARTICULARLY THE BRAIN).
|
||||
SKIN ABSORPTION MAY BE HARMFUL.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D008 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. IF CONCENTRATION
|
||||
EXCEEDS CAPACITY OF RESPIRATOR, A SELF-CONTAINED
|
||||
BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD CHLORIDE
|
||||
HAZARD CLASS ORM-E
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 100 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD COMPOUNDS, SOLUBLE, N.O.S. (LEAD CHLORIDE)
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN2291
|
||||
LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS
|
||||
|
||||
190
textfiles.com/science/CHEMICALS/lead_dioxide.txt
Normal file
190
textfiles.com/science/CHEMICALS/lead_dioxide.txt
Normal file
@@ -0,0 +1,190 @@
|
||||
|
||||
MSDS - LEAD DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: LEAD DIOXIDE
|
||||
FORMULA: PBO2
|
||||
FORMULA WT: 239.19
|
||||
CAS NO.: 01309-60-0
|
||||
NIOSH/RTECS NO.: OG0700000
|
||||
COMMON SYNONYMS: LEAD(IV)OXIDE; LEAD PEROXIDE; LEAD BROWN; LEAD OXIDE BROWN
|
||||
PRODUCT CODES: 2353,2352,2351,2348
|
||||
EFFECTIVE: 06/30/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (LIFE)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 3 SEVERE (OXIDIZER)
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DANGER
|
||||
EXCEPTIONAL HEALTH HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. DO NOT
|
||||
STORE NEAR COMBUSTIBLE MATERIALS. AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, SOAK WITH WATER.
|
||||
IN CASE OF SPILL, SWEEP UP AND REMOVE. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
LEAD DIOXIDE 90-100 1309-60-0
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): 8.2
|
||||
|
||||
SPECIFIC GRAVITY: 9.38 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: DARK BROWN POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
CAN REACT VIOLENTLY WITH SHOCK, FRICTION OR HEAT.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.15 MG/M3 ( PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 0.45 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (IPR-GUINEA PIG) (MG/KG) - 220
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CHRONIC EFFECTS RESULTING FROM LOW LEVEL EXPOSURE TO LEAD COMPOUNDS
|
||||
MAY INCLUDE ANEMIA, KIDNEY DAMAGE, IMPAIRED EYESIGHT, AND LEAD
|
||||
BUILD-UP IN THE CENTRAL NERVOUS SYSTEM (PARTICULARLY THE BRAIN).
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: SHOCK, FRICTION, HEAT
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS, COMBUSTIBLE MATERIALS,
|
||||
CHEMICALLY ACTIVE METALS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D003 (REACTIVE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: A RESPIRATOR WITH DUST/MIST FILTER IS RECOMMENDED.
|
||||
IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, BUTYL RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
|
||||
AND COMBUSTIBLE MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD PEROXIDE
|
||||
HAZARD CLASS OXIDIZER
|
||||
UN/NA UN1872
|
||||
LABELS OXIDIZER
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD DIOXIDE
|
||||
HAZARD CLASS 5.1
|
||||
UN/NA UN1872
|
||||
LABELS OXIDIZING AGENT
|
||||
|
||||
178
textfiles.com/science/CHEMICALS/lead_ii_oxide.txt
Normal file
178
textfiles.com/science/CHEMICALS/lead_ii_oxide.txt
Normal file
@@ -0,0 +1,178 @@
|
||||
|
||||
MSDS - LEAD OXIDE (LITHARGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: LEAD OXIDE (LITHARGE)
|
||||
FORMULA: PBO
|
||||
FORMULA WT: 223.19
|
||||
CAS NO.: 01317-36-8
|
||||
NIOSH/RTECS NO.: OG1750000
|
||||
COMMON SYNONYMS: LEAD(II)OXIDE; LEAD MONOXIDE; LEAD OXIDE YELLOW
|
||||
PRODUCT CODES: 4995,2338,2340
|
||||
EFFECTIVE: 10/16/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (LIFE)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
EXCEPTIONAL HEALTH HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
LEAD OXIDE 90-100 1317-36-8
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 888 C ( 1630 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 9.53 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: YELLOW TO REDDISH POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.15 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
CHRONIC EFFECTS RESULTING FROM LOW LEVEL EXPOSURE TO LEAD COMPOUNDS
|
||||
MAY INCLUDE ANEMIA, KIDNEY DAMAGE, IMPAIRED EYESIGHT, AND LEAD
|
||||
BUILD-UP IN THE CENTRAL NERVOUS SYSTEM (PARTICULARLY THE BRAIN).
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS, COMBUSTIBLE MATERIALS,
|
||||
CHEMICALLY ACTIVE METALS, ALUMINUM, SODIUM METAL
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. IF CONCENTRATION
|
||||
EXCEEDS CAPACITY OF RESPIRATOR, A SELF-CONTAINED
|
||||
BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD OXIDE
|
||||
HAZARD CLASS ORM-E
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 1 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD COMPOUNDS, SOLUBLE, N.O.S. (LEAD OXIDE (LITHARGE))
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN2291
|
||||
LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS
|
||||
|
||||
195
textfiles.com/science/CHEMICALS/lead_nitrate.txt
Normal file
195
textfiles.com/science/CHEMICALS/lead_nitrate.txt
Normal file
@@ -0,0 +1,195 @@
|
||||
|
||||
MSDS - LEAD NITRATE, CRYSTAL
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: LEAD NITRATE, CRYSTAL
|
||||
FORMULA: PB(NO3)2
|
||||
FORMULA WT: 331.20
|
||||
CAS NO.: 10099-74-8
|
||||
NIOSH/RTECS NO.: OG2100000
|
||||
COMMON SYNONYMS: LEAD(II)NITRATE; LEAD DINITRATE; NITRIC ACID, LEAD(2+)SALT
|
||||
PRODUCT CODES: 5044,5048,5162,2322,2328
|
||||
EFFECTIVE: 06/30/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (LIFE)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 3 SEVERE (OXIDIZER)
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DANGER
|
||||
EXCEPTIONAL HEALTH HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. DO NOT
|
||||
STORE NEAR COMBUSTIBLE MATERIALS. AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, SOAK WITH WATER.
|
||||
IN CASE OF SPILL, SWEEP UP AND REMOVE. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
LEAD NITRATE 90-100 10099-74-8
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): 11.0
|
||||
|
||||
SPECIFIC GRAVITY: 4.53 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE OR COLORLESS CRYSTALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A NFPA 704M RATING: 0-0-0 OXY
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
CAN REACT VIOLENTLY WITH SHOCK, FRICTION OR HEAT.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
NITROGEN OXIDES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.15 MG/M3 ( PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 0.45 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CHRONIC EFFECTS RESULTING FROM LOW LEVEL EXPOSURE TO LEAD COMPOUNDS
|
||||
MAY INCLUDE ANEMIA, KIDNEY DAMAGE, IMPAIRED EYESIGHT, AND LEAD
|
||||
BUILD-UP IN THE CENTRAL NERVOUS SYSTEM (PARTICULARLY THE BRAIN).
|
||||
DUST MAY CAUSE HEADACHE, COUGHING, DIZZINESS OR DIFFICULT BREATHING.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING AND LOSS OF CONSCIOUSNESS.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: SHOCK, FRICTION, HEAT
|
||||
|
||||
INCOMPATIBLES: COMBUSTIBLE MATERIALS, ORGANIC MATERIALS,
|
||||
STRONG REDUCING AGENTS
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D003 (REACTIVE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: A RESPIRATOR WITH DUST/MIST FILTER IS RECOMMENDED.
|
||||
IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, BUTYL RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
|
||||
AND COMBUSTIBLE MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD NITRATE
|
||||
HAZARD CLASS OXIDIZER
|
||||
UN/NA UN1469
|
||||
LABELS OXIDIZER
|
||||
REPORTABLE QUANTITY 100 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD NITRATE
|
||||
HAZARD CLASS 5.1, 6.1
|
||||
UN/NA UN1469
|
||||
LABELS OXIDIZING AGENT, POISON
|
||||
|
||||
187
textfiles.com/science/CHEMICALS/lead_oxide.txt
Normal file
187
textfiles.com/science/CHEMICALS/lead_oxide.txt
Normal file
@@ -0,0 +1,187 @@
|
||||
|
||||
MSDS - LEAD OXIDE, RED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: LEAD OXIDE, RED
|
||||
FORMULA: PB3O4
|
||||
FORMULA WT: 685.57
|
||||
CAS NO.: 01314-41-6
|
||||
NIOSH/RTECS NO.: OG5425000
|
||||
COMMON SYNONYMS: LEAD TETROXIDE; MINERAL RED
|
||||
PRODUCT CODES: 2334
|
||||
EFFECTIVE: 10/22/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (LIFE)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
EXCEPTIONAL HEALTH HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
HARMFUL IF SWALLOWED OR INHALED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
LEAD OXIDE, RED 90-100 1314-41-6
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 1472 C ( 2682 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 9.10 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: ODORLESS,BRIGHT RED POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.15 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (IPR-RAT)(MG/KG) - 630
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CHRONIC EFFECTS RESULTING FROM LOW LEVEL EXPOSURE TO LEAD COMPOUNDS
|
||||
MAY INCLUDE ANEMIA, KIDNEY DAMAGE, IMPAIRED EYESIGHT, AND LEAD
|
||||
BUILD-UP IN THE CENTRAL NERVOUS SYSTEM (PARTICULARLY THE BRAIN).
|
||||
DUST MAY IRRITATE SKIN.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D008 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. IF CONCENTRATION
|
||||
EXCEEDS CAPACITY OF RESPIRATOR, A SELF-CONTAINED
|
||||
BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, NEOPRENE GLOVES
|
||||
ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD OXIDE, RED, POWDER
|
||||
HAZARD CLASS ORM-E
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 1 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME LEAD COMPOUNDS, SOLUBLE, N.O.S. (LEAD OXIDE, RED)
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN2291
|
||||
LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS
|
||||
|
||||
126
textfiles.com/science/CHEMICALS/linseed_oil.txt
Normal file
126
textfiles.com/science/CHEMICALS/linseed_oil.txt
Normal file
@@ -0,0 +1,126 @@
|
||||
|
||||
MSDS - BOILED LINSEED OIL
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: LINSEED OIL; (BOILED LINSEED OIL)
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: OI9690000
|
||||
CAS Number: 8001-26-1
|
||||
OSHA PEL: NOT APPLICABLE
|
||||
ACGIH TLV: NOT APPLICABLE
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: AMBER COLOR LIQUID; OIL ODOR.
|
||||
Boiling Point: >300F,>149C
|
||||
Vapor Density (Air=1): HVR/AIR
|
||||
Specific Gravity: 0.93 (H*2O=1)
|
||||
Evaporation Rate And Ref: SLOWER THAN ETHER
|
||||
Solubility In Water: NIL
|
||||
Percent Volatiles By Volume: 0
|
||||
pH: N/A
|
||||
Magnetism (Milligauss): N/P
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: 250F,121C
|
||||
Flash Point Method: TCC
|
||||
Lower Explosive Limit: N/A
|
||||
Upper Explosive Limit: N/A
|
||||
Extinguishing Media: FOAM, DRY CHEMICAL, OR CARBON DIOXIDE.
|
||||
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL
|
||||
PROTECTIVE EQUIPMENT (FP N).
|
||||
Unusual Fire And Expl Hazrds: NONE
|
||||
Report for NIIN: 00N030448
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): NONE
|
||||
Materials To Avoid: STRONG OXIDIZING AGENTS.
|
||||
Hazardous Decomp Products: CARBON MONOXIDE.
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): NOT RELEVANT
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
|
||||
Route Of Entry - Inhalation: YES
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: YES
|
||||
Health Haz Acute And Chronic: PROLONGED OR REPEATED EXPOSURE MAY CAUSE
|
||||
NAUSEA, HEADACHE, AND LOSS OF CONSCIOUSNESS, NARCOSIS AND IRRITATION OF
|
||||
RESPIRATORY SYSTEM. LIQUID IRRITATING TO EYES AND SKIN.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NOT RELEVANT
|
||||
Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS.
|
||||
Med Cond Aggravated By Exp: NONE KNOWN
|
||||
Emergency/First Aid Proc: SKIN: WASH THOROUGHLY WITH WATER. OBTAIN MEDICAL
|
||||
HELP IF IRRITATION PERSISTS. EYES: WASH THOROUGHLY WITH WATER FOR AT LEAST
|
||||
15 MINUTES. OBTAIN MEDICAL HELP IF IRRITATION PERSISTS. INHAL: REMOVE TO
|
||||
FRESH AIR. INGEST: CALL MD IMMEDIATELY (FP N).
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: ABSORB WITH INERT MATERIAL. REMOVE FOR
|
||||
DISPOSAL.
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: INCINERATION OR LANDFILL. DISPOSE OF I/A/W FEDERAL,
|
||||
STATE AND LOCAL REGULATIONS (FP N).
|
||||
Precautions-Handling/Storing: NONE SPECIFIED BY MANUFACTURER.
|
||||
Other Precautions: PROVIDE ADEQUATE VENTILATION. AVOID PROLONGED OR
|
||||
REPEATED SKIN CONTACT.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: NIOSH/MSHA APPROVED SELF-CONTAINED RESPIRATOR.
|
||||
Ventilation: LOCAL EXHAUST.
|
||||
Protective Gloves: SOLVENT RESISTANT GLOVES.
|
||||
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
|
||||
Other Protective Equipment: NONE
|
||||
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
|
||||
Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER.
|
||||
Report for NIIN: 00N030448
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 92267
|
||||
DOT PSN Code: ZZZ
|
||||
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
IMO PSN Code: ZZZ
|
||||
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
|
||||
IATA PSN Code: ZZZ
|
||||
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
AFI PSN Code: ZZZ
|
||||
AFI Prop. Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
|
||||
Additional Trans Data: NOT REGULATED FOR TRANSPORTATION
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
Report for NIIN: 00N030448
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 07MAY92
|
||||
Label Status: M
|
||||
Common Name: 150800, BOILED LINSEED OIL
|
||||
Chronic Hazard: NO
|
||||
Signal Word: CAUTION!
|
||||
Acute Health Hazard-Slight: X
|
||||
Contact Hazard-Slight: X
|
||||
Fire Hazard-Slight: X
|
||||
Reactivity Hazard-None: X
|
||||
Special Hazard Precautions: ACUTE: PROLONGED OR REPEATED INHALATION MAY
|
||||
CAUSE NAUSEA, HEADACHE, LOSS OF CONSCIOUSNESS, NARCOSIS AND IRRITATION OF
|
||||
RESPIRATORY SYSTEM. LIQUID CONTACT WITH EYES AND SKIN MAY CAUSE IRRITATION.
|
||||
CHRONIC: NONE LISTED BY MANUFACTURER.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
167
textfiles.com/science/CHEMICALS/lithium_carbonate.txt
Normal file
167
textfiles.com/science/CHEMICALS/lithium_carbonate.txt
Normal file
@@ -0,0 +1,167 @@
|
||||
|
||||
MSDS - LITHIUM CARBONATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: LITHIUM CARBONATE
|
||||
FORMULA: LI2CO3
|
||||
FORMULA WT: 73.89
|
||||
CAS NO.: 00554-13-2
|
||||
NIOSH/RTECS NO.: OJ5800000
|
||||
COMMON SYNONYMS: CARBONIC ACID, DILITHIUM SALT; CARBONIC ACID LITHIUM SALT;
|
||||
DILITHIUM CARBONATE
|
||||
PRODUCT CODES: 4919,2362
|
||||
EFFECTIVE: 09/26/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
LITHIUM CARBONATE 90-100 554-13-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 720 C ( 1328 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.11 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE ODORLESS POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 525
|
||||
LD50 (IPR-RAT)(MG/KG) - 156
|
||||
LD50 (SCU-RAT)(MG/KG) - 434
|
||||
LD50 (IV-RAT) (MG/KG) - 241
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INGESTION MAY CAUSE ACUTE LOCAL TISSUE DAMAGE, WITH OTHER EFFECTS
|
||||
RANGING FROM NAUSEA AND DIZZINESS TO UNCONSCIOUSNESS.
|
||||
INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE
|
||||
|
||||
INCOMPATIBLES: FLUORINE, WATER, STRONG ACIDS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
J. T. BAKER NEUTRACIT-2(R) CAUSTIC NEUTRALIZER IS RECOMMENDED
|
||||
FOR SPILLS OF THIS PRODUCT.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
167
textfiles.com/science/CHEMICALS/lithium_chloride.txt
Normal file
167
textfiles.com/science/CHEMICALS/lithium_chloride.txt
Normal file
@@ -0,0 +1,167 @@
|
||||
|
||||
MSDS - LITHIUM CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: LITHIUM CHLORIDE
|
||||
FORMULA: LICL
|
||||
FORMULA WT: 42.39
|
||||
CAS NO.: 07447-41-8
|
||||
NIOSH/RTECS NO.: OJ5950000
|
||||
PRODUCT CODES: 5188,2374,2370
|
||||
EFFECTIVE: 09/26/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
LITHIUM CHLORIDE 90-100 7447-41-8
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 1360 C ( 2480 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 613 C ( 1135 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.07 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE ODORLESS SOLID.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 526
|
||||
LD50 (IPR-RAT)(MG/KG) - 514
|
||||
LD50 (SCU-RAT)(MG/KG) - 499
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
PROLONGED CONTACT MAY CAUSE SKIN SENSITIZATION.
|
||||
INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: BROMINE TRIFLUORIDE AND TRICHLORIDE
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
103
textfiles.com/science/CHEMICALS/lycopodium.txt
Normal file
103
textfiles.com/science/CHEMICALS/lycopodium.txt
Normal file
@@ -0,0 +1,103 @@
|
||||
|
||||
MSDS - LYCOPODIUM
|
||||
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: LYCOPODIUM
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: 1005003LY
|
||||
OSHA PEL: N/K (FP N)
|
||||
ACGIH TLV: N/K (FP N)
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: SOLID
|
||||
Evaporation Rate And Ref: NOT KNOWN
|
||||
Solubility In Water: INSOLUBLE
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: NOT AVAILABLE
|
||||
Flash Point Method: N/P
|
||||
Extinguishing Media: CO*2, DRY CHEMICALS, FOAM AND WATER.
|
||||
Special Fire Fighting Proc: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
|
||||
EQUIPMENT (FP N).
|
||||
Unusual Fire And Expl Hazrds: FLAMMABLE.
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
|
||||
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
|
||||
Hazardous Decomp Products: NONE SPECIFIED BY MANUFACTURER.
|
||||
Hazardous Poly Occur: NO
|
||||
Conditions To Avoid (Poly): NOT RELEVANT.
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
|
||||
Route Of Entry - Inhalation: NO
|
||||
Route Of Entry - Skin: NO
|
||||
Route Of Entry - Ingestion: NO
|
||||
Health Haz Acute And Chronic: NONE SPECIFIED BY MANUFACTURER.
|
||||
Carcinogenicity - NTP: NO
|
||||
Carcinogenicity - IARC: NO
|
||||
Carcinogenicity - OSHA: NO
|
||||
Explanation Carcinogenicity: NOT RELEVANT.
|
||||
Signs/Symptoms Of Overexp: NONE SPECIFIED BY MANUFACTURER.
|
||||
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
|
||||
Emergency/First Aid Proc: INGEST:CALL MD IMMEDIATELY (FP N). INHAL: REMOVE
|
||||
TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). SKIN: WASH
|
||||
IMMEDIATELY WITH PLENTY OF WATER AND SOAP. EYES:RINSE IMMEDIATELY WITH
|
||||
PLENTY OF WATER FOR AT LEAST 15 MINUTES AND SEEK MEDICAL ADVICE. TAKE OFF
|
||||
IMMEDIATELY ALL CONTAMINATED CLOTHING.
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: COLLECT IN SUITABLE CONTAINERS. WASH
|
||||
REMAINDER AWAY WITH COPIOUS QUANTITIES OF WATER AND DETERGENT.
|
||||
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
|
||||
Waste Disposal Method: THE COMPOUND SHOULD BE BURNED IN ACCORDANCE WITH
|
||||
FEDERAL, STATE OR LOCAL LAWS.
|
||||
Precautions-Handling/Storing: PROTECT FROM MOISTURE.
|
||||
Other Precautions: HIGHLY FLAMMABLE. KEEP AWAY FROM SOURCES OF IGNITION -
|
||||
NO SMOKING.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
|
||||
EXPOSURE OF CONCERN (FP N).
|
||||
Ventilation: NONE SPECIFIED BY MANUFACTURER.
|
||||
Protective Gloves: IMPERVIOUS GLOVES (FP N).
|
||||
Eye Protection: ANSI APPRVD CHEM WORKER GOGGLES (FP N).
|
||||
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
|
||||
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
|
||||
Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER.
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Technical Review Date: 11JAN94
|
||||
Label Date: 11JAN94
|
||||
Label Status: M
|
||||
Common Name: LYCOPODIUM 62800
|
||||
Chronic Hazard: NO
|
||||
Signal Word: DANGER!
|
||||
Acute Health Hazard-None: X
|
||||
Contact Hazard-None: X
|
||||
Fire Hazard-Severe: X
|
||||
Reactivity Hazard-None: X
|
||||
Special Hazard Precautions: FLAMMABLE. ACUTE & CHRONIC:NONE SPECIFIED BY
|
||||
MANUFACTURER.
|
||||
Protect Eye: Y
|
||||
Protect Skin: Y
|
||||
Protect Respiratory: Y
|
||||
|
||||
199
textfiles.com/science/CHEMICALS/magnesium.txt
Normal file
199
textfiles.com/science/CHEMICALS/magnesium.txt
Normal file
@@ -0,0 +1,199 @@
|
||||
|
||||
MSDS - MAGNESIUM
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MAGNESIUM
|
||||
FORMULA: MG
|
||||
FORMULA WT: 24.30
|
||||
CAS NO.: 7439-95-4
|
||||
NIOSH/RTECS NO.: OM2100000
|
||||
PRODUCT CODES: 2416
|
||||
EFFECTIVE: 10/24/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 4 EXTREME (FLAMMABLE)
|
||||
REACTIVITY - 3 SEVERE (WATER REACTIVE)
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; CLASS D EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES IRRITATION
|
||||
DUST MAY FORM FLAMMABLE AND EXPLOSIVE MIXTURE WITH AIR, ESPECIALLY
|
||||
WHEN DAMP.
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
DO NOT USE WATER. USE DRY SAND, EARTH OR SODA ASH. IN CASE OF SPILL,
|
||||
SWEEP UP AND CAREFULLY REMOVE.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MAGNESIUM 90-100 7439-95-4
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 1107 C ( 2025 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 650 C ( 1202 F) VAPOR DENSITY(AIR=1): 0.84
|
||||
|
||||
SPECIFIC GRAVITY: 1.74 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): DECOMPOSES % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: SILVERY, WHITE METALLIC POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP 634 C ( 1175 F) NFPA 704M RATING: 0-1-2 W
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
SMOTHER WITH DRY SODA ASH. NEVER USE WATER OR CHEMICAL FIRE
|
||||
EXTINGUISHERS.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
BURNS WITH A VERY BRIGHT FLAME, FIRE GLASSES MUST BE WORN.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
REACTS VIOLENTLY WITH WATER PRODUCING HIGHLY FLAMMABLE VAPORS.
|
||||
CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION.
|
||||
DUST MAY FORM EXPLOSIVE MIXTURE WITH AIR.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN GAS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TLV IS LISTED FOR MAGNESIUM OXIDE FUME.
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
INHALATION OF FUMES MAY RESULT IN LEUKOCYTOSIS.
|
||||
CONTACT MAY CAUSE IRRITATION OF SKIN, EYES, AND MUCOUS MEMBRANES.
|
||||
|
||||
TARGET ORGANS
|
||||
RESPIRATORY SYSTEM, EYES
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE LARGE AMOUNTS OF
|
||||
WATER.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE, HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG ACIDS, WATER, HALOGENS,
|
||||
CYANIDES
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. DO NOT USE WATER.
|
||||
WITH CLEAN SHOVEL, PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER.
|
||||
MOVE CONTAINER(S) FROM SPILL AREA.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D001, D003 (IGNITABLE, REACTIVE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY FROM WATER OR LOCATIONS WHERE
|
||||
WATER MAY BE USED TO EXTINGUISH FIRE.
|
||||
STORE IN A COOL, WELL-VENTILATED AREA AWAY FROM SOURCES OF HEAT, FLAME, OR
|
||||
IGNITION.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME MAGNESIUM METAL (POWDERED)
|
||||
HAZARD CLASS FLAMMABLE SOLID
|
||||
UN/NA UN1869
|
||||
LABELS FLAMMABLE SOLID, DANGEROUS WHEN WET
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME MAGNESIUM, POWDER, NON-PYROPHORIC
|
||||
HAZARD CLASS 4.3
|
||||
UN/NA UN1418
|
||||
LABELS DANGEROUS WHEN WET
|
||||
|
||||
98
textfiles.com/science/CHEMICALS/magnesium_carbonate.txt
Normal file
98
textfiles.com/science/CHEMICALS/magnesium_carbonate.txt
Normal file
@@ -0,0 +1,98 @@
|
||||
|
||||
|
||||
|
||||
|
||||
M A T E R I A L S A F E T Y D A T A S H E E T
|
||||
MAGNESIUM CARBONATE
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: MAGNESIUM CARBONATE
|
||||
FORMULA: 4MGCO3.MG(OH)2.5H2O
|
||||
FORMULA WT: 485.74
|
||||
CAS NO.:
|
||||
COMMON SYNONYMS: N/A
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: N/A VAPOR PRESSURE @ 20C (MM HG): N/A
|
||||
MELTING POINT: N/A VAPOR DENSITY (AIR=1): N/A
|
||||
SPECIFIC GRAVITY: 2.16 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): 0.04 PERCENT VOLATILES BY VOLUME: N/A
|
||||
APPEARANCE & ODOR: COLORLESS TO WHITE CRYSTALS
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: NONFLAMMABLE
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
ANY SUITABLE FOR OTHER MATERIALS INVOLVED
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS
|
||||
UNUSUAL FIRE AND EXPLOSION HAZARDS
|
||||
NONE
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): NONE ESTABLISHED
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
PROLONGED CONTACT AND ACUTE INGESTION MAY RESULT IN ALLERGIC REACTION
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
EYES: WASH WITH WATER 15 MINUTES; GET MEDICAL ASSISTANCE
|
||||
SKIN: WASH WITH SOAP/WATER; GET MEDICAL ASSISTANCE
|
||||
INGESTION: GET MEDICAL ATTENTION
|
||||
INHALATION: REMOVE TO FRESH AIR; GET MEDICAL ASSISTANCE
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE
|
||||
CONDITIONS TO AVOID: NONE
|
||||
INCOMPATIBILES: ACIDS, OXIDIZERS, CYANIDES, HALOGENS, HALOGEN
|
||||
COMPOUNDS OXIDIZING MATERIALS (REACTS VIGOROUSLY)
|
||||
DECOMPOSITION PRODUCTS: CO2 MGO
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
SWEEP UP & CONTAINERIZE FOR DISPOSAL
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
PROVIDE ADEQUATE GENERAL MECHANICAL VENTILATION
|
||||
PROTECT EYES AND SKIN WITH SAFETY GOGGLES AND GLOVES
|
||||
DO NOT BREATHE DUST
|
||||
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
KEEP CONTAINER CLOSED
|
||||
STORE IN A COOL, DRY, WELL-VENTILATED AREA
|
||||
WASH THOROUGHLY AFTER HANDLING
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
NONE
|
||||
|
||||
--------------------------------------------------------------------------------
|
||||
(TM) and (R) : Registered Trademarks
|
||||
N/A = Not Applicable OR Not Available
|
||||
The information published in this Material Safety Data Sheet has been compiled
|
||||
from our experience and data presented in various technical publications. It is
|
||||
the user's responsibility to determine the suitability of this information for
|
||||
adoption of necessary safety precautions. We reserve the right to revise
|
||||
Material Safety Data Sheets periodically as new information becomes available.
|
||||
Copyright by Manufacturer
|
||||
LICENSE GRANTED TO MAKE UNLIMITED COPIES FOR INTERNAL USE ONLY
|
||||
by OREGON STATE UNIVERSITY
|
||||
.
|
||||
168
textfiles.com/science/CHEMICALS/magnesium_oxide.txt
Normal file
168
textfiles.com/science/CHEMICALS/magnesium_oxide.txt
Normal file
@@ -0,0 +1,168 @@
|
||||
|
||||
MSDS - MAGNESIUM OXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MAGNESIUM OXIDE
|
||||
FORMULA: MGO
|
||||
FORMULA WT: 40.30
|
||||
CAS NO.: 1309-48-4
|
||||
NIOSH/RTECS NO.: OM3850000
|
||||
PRODUCT CODES: 2477,2484,2476,2480
|
||||
EFFECTIVE: 09/03/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
MAY CAUSE IRRITATION
|
||||
MAY BE HARMFUL IF INHALED
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MAGNESIUM OXIDE 90-100 1309-48-4
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 3600 C ( 6512 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 2800 C ( 5072 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 3.60 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE TO LIGHT-GRAY POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 15 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST INHALATION MAY CAUSE TIGHTNESS AND PAIN IN CHEST, COUGHING, AND
|
||||
DIFFICULTY IN BREATHING.
|
||||
INHALATION OF FUMES MAY RESULT IN LEUKOCYTOSIS.
|
||||
CONTACT CAN CAUSE EYE IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
RESPIRATORY SYSTEM, EYES
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: AIR
|
||||
|
||||
INCOMPATIBLES: BROMINE TRIFLUORIDE AND TRICHLORIDE,
|
||||
PHOSPHORUS PENTACHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 45 PPM, A HIGH-EFFICIENCY PARTICULATE
|
||||
RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A
|
||||
SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, NEOPRENE GLOVES
|
||||
ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
166
textfiles.com/science/CHEMICALS/magnesium_sulfate.txt
Normal file
166
textfiles.com/science/CHEMICALS/magnesium_sulfate.txt
Normal file
@@ -0,0 +1,166 @@
|
||||
|
||||
MSDS - MAGNESIUM SULFATE, ANHYDROUS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MAGNESIUM SULFATE, ANHYDROUS
|
||||
FORMULA: MGSO4
|
||||
FORMULA WT: 120.37
|
||||
CAS NO.: 07487-88-9
|
||||
NIOSH/RTECS NO.: OM4500000
|
||||
COMMON SYNONYMS: EPSOM SALTS
|
||||
PRODUCT CODES: 2506
|
||||
EFFECTIVE: 05/30/86
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 2.65 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WHITE CRYSTALLINE POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
SULFUR DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (SCU-MOUSE)(MG/KG) - 980
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
PROLONGED CONTACT MAY BE IRRITATING TO THE SKIN, EYES, AND MUCOUS
|
||||
MEMBRANES.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: MOISTURE, HEAT
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF SULFUR
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
167
textfiles.com/science/CHEMICALS/malachite_green.txt
Normal file
167
textfiles.com/science/CHEMICALS/malachite_green.txt
Normal file
@@ -0,0 +1,167 @@
|
||||
|
||||
MSDS - MALACHITE GREEN HYDROCHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MALACHITE GREEN HYDROCHLORIDE
|
||||
FORMULA: C23H25N2CL
|
||||
FORMULA WT: 364.92
|
||||
CAS NO.: 00569-64-2
|
||||
NIOSH/RTECS NO.: BQ1180000
|
||||
COMMON SYNONYMS: C.I. BASIC GREEN 4; C.I. 42000
|
||||
PRODUCT CODES: P451
|
||||
EFFECTIVE: 10/29/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 2 MODERATE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
HARMFUL IF SWALLOWED
|
||||
CAUSES IRRITATION
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MALACHITE GREEN HYDROCHLORIDE 90-100 569-64-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: N/A EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: GREEN CRYSTALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TOXICITY: LD50 (ORAL-MOUSE)(MG/KG) - 80
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 4.2
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INGESTION MAY BE HARMFUL.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
PROLONGED EXPOSURE MAY CAUSE DERMATITIS.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, UNIFORM, RUBBER
|
||||
GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME POISONOUS SOLIDS, N.O.S. (MALACHITE GREEN
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN2811
|
||||
LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS
|
||||
|
||||
185
textfiles.com/science/CHEMICALS/manganese_dioxide.txt
Normal file
185
textfiles.com/science/CHEMICALS/manganese_dioxide.txt
Normal file
@@ -0,0 +1,185 @@
|
||||
|
||||
MSDS - MANGANESE DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MANGANESE DIOXIDE
|
||||
FORMULA: MNO2
|
||||
FORMULA WT: 86.94
|
||||
CAS NO.: 1313-13-9
|
||||
NIOSH/RTECS NO.: OP0350000
|
||||
COMMON SYNONYMS: BLACK MANGANESE OXIDE; CEMENT BLACK; MANGANESE (IV) OXIDE
|
||||
PRODUCT CODES: Z134,2526,8392,5308,2527,5298
|
||||
EFFECTIVE: 09/08/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF INHALED
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MANGANESE DIOXIDE 90-100 1313-13-9
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 535 C ( 995 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 5.02 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: ODORLESS BLACK CRYSTALLINE POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TLV LISTED DENOTES CEILING LIMIT.
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 5 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY IRRITATE SKIN OR EYES.
|
||||
INHALATION OF EXCESSIVE AMOUNTS OF DUST MAY CAUSE NAUSEA, WEAKNESS,
|
||||
CHILLS, AND LOSS OF APPETITE.
|
||||
INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT.
|
||||
INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
|
||||
PROLONGED INHALATION OF MANGANESE IN THE FORM OF ITS INORGANIC COMPOUNDS
|
||||
MAY CAUSE MANGANISM.
|
||||
|
||||
TARGET ORGANS
|
||||
RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, BLOOD, KIDNEYS
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INGESTION, INHALATION
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG ACIDS,
|
||||
STRONG REDUCING AGENTS, NITRATES,
|
||||
COMBUSTIBLE MATERIALS, HYDROGEN PEROXIDE, AZIDES,
|
||||
CHLORINE, CHLORATES, CHLORINE TRIFLUORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. KEEP COMBUSTIBLES (WOOD, PAPER, OIL,
|
||||
ETC.) AWAY FROM SPILLED MATERIAL. WITH CLEAN SHOVEL, CAREFULLY PLACE
|
||||
MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH
|
||||
SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE
|
||||
AND COMBUSTIBLE MATERIALS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
215
textfiles.com/science/CHEMICALS/mek.txt
Normal file
215
textfiles.com/science/CHEMICALS/mek.txt
Normal file
@@ -0,0 +1,215 @@
|
||||
|
||||
MSDS - METHYL ETHYL KETONE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: METHYL ETHYL KETONE
|
||||
FORMULA: CH3COCH2CH3
|
||||
FORMULA WT: 72.11
|
||||
CAS NO.: 78-93-3
|
||||
NIOSH/RTECS NO.: EL6475000
|
||||
COMMON SYNONYMS: 2-BUTANONE; MEK; ETHYL METHYL KETONE; METHYLACETONE
|
||||
PRODUCT CODES: 9214,9323,9211,5385,9319,Q531
|
||||
EFFECTIVE: 08/27/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 2 MODERATE
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 2 MODERATE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
EXTREMELY FLAMMABLE
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF INHALED
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME.
|
||||
AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE.
|
||||
FLUSH SPILL AREA WITH WATER SPRAY.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
METHYL ETHYL KETONE 90-100 78-93-3
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 80 C ( 176 F) VAPOR PRESSURE(MM HG): 78
|
||||
|
||||
MELTING POINT: -87 C ( -125 F) VAPOR DENSITY(AIR=1): 2.5
|
||||
|
||||
SPECIFIC GRAVITY: 0.81 EVAPORATION RATE: 5.7
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: 100
|
||||
|
||||
APPEARANCE & ODOR: CLEAR COLORLESS, LIQUID WITH ACETONE-LIKE ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP -7 C ( 20 F) NFPA 704M RATING: 1-3-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 11.4 % LOWER - 1.8 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
(WATER MAY BE INEFFECTIVE.)
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK.
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG
|
||||
OXIDIZERS MAY CAUSE FIRE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 590 MG/M3 ( 200 PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 885 MG/M3 ( 300 PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 590 MG/M3 ( 200 PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 2737
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 616
|
||||
LD50 (SKN-RABBIT) (G/KG) - 13
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF VAPORS MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS,
|
||||
DROWSINESS, IRRITATION OF RESPIRATORY TRACT, AND LOSS OF CONSCIOUSNESS.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
PROLONGED EXPOSURE MAY CAUSE DERMATITIS.
|
||||
LIQUID MAY CAUSE PERMANENT EYE DAMAGE.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
NASAL SEPTUM, LUNGS
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, DO NOT INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG BASES, CAUSTICS,
|
||||
MINERAL ACIDS, AMINES AND AMMONIA, HALOGENS
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK
|
||||
IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP
|
||||
WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO
|
||||
CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
|
||||
|
||||
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED
|
||||
FOR SPILLS OF THIS PRODUCT.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: U159 (TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 1000 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH
|
||||
ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE
|
||||
THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS RECOMMENDED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. KEEP CONTAINER
|
||||
TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID
|
||||
STORAGE AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME METHYL ETHYL KETONE
|
||||
HAZARD CLASS FLAMMABLE LIQUID
|
||||
UN/NA UN1193
|
||||
LABELS FLAMMABLE LIQUID
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME METHYL ETHYL KETONE
|
||||
HAZARD CLASS 3.2
|
||||
UN/NA UN1193
|
||||
LABELS FLAMMABLE LIQUID
|
||||
|
||||
198
textfiles.com/science/CHEMICALS/mercuric_chloride.txt
Normal file
198
textfiles.com/science/CHEMICALS/mercuric_chloride.txt
Normal file
@@ -0,0 +1,198 @@
|
||||
|
||||
MSDS - MERCURIC CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MERCURIC CHLORIDE
|
||||
FORMULA: HGCL2
|
||||
FORMULA WT: 271.50
|
||||
CAS NO.: 07487-94-7
|
||||
NIOSH/RTECS NO.: OV9100000
|
||||
COMMON SYNONYMS: MERCURY(II)CHLORIDE; MERCURY BICHLORIDE
|
||||
PRODUCT CODES: 2594
|
||||
EFFECTIVE: 06/30/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 4 EXTREME (POISON)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 3 SEVERE (LIFE)
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN
|
||||
EXCEPTIONAL HEALTH AND CONTACT HAZARDS - READ MATERIAL SAFETY DATA SHEET
|
||||
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MERCURIC CHLORIDE 90-100 7487-94-7
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 302 C ( 576 F) VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 277 C ( 531 F) VAPOR DENSITY(AIR=1): 8.7
|
||||
|
||||
SPECIFIC GRAVITY: 5.44 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: CRYSTALS OR WHITE GRANULES OR POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN CHLORIDE, MERCURY FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.05 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 1
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 5
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST INHALATION MAY CAUSE TIGHTNESS AND PAIN IN CHEST, COUGHING, AND
|
||||
DIFFICULTY IN BREATHING.
|
||||
SKIN ABSORPTION MAY BE HARMFUL OR FATAL.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
INHALATION AND INGESTION ARE HARMFUL AND MAY BE FATAL.
|
||||
CHRONIC EFFECTS OF MERCURY POISONING INCLUDE A BUILDUP OF THE
|
||||
METAL IN THE BRAIN, LIVER AND KIDNEYS. SYMPTOMS INCLUDE HEADACHE,
|
||||
TREMORS, LOOSE TEETH, LOSS OF APPETITE, BLISTERS ON THE SKIN AND
|
||||
IMPAIRED MEMORY.
|
||||
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FRICTION, SHOCK, LIGHT
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS, AMMONIA, CARBONATES, METALLIC SALTS,
|
||||
ALKALIES, PHOSPHITES, PHOSPHATES, SULFITES, SULFATES,
|
||||
BROMIDES, ANTIMONY, ARSENIC
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, MERCURY FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D009 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE APPROPRIATE VENTILATION
|
||||
CONDITIONS EXIST. IF THE TLV IS EXCEEDED, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
KEEP PRODUCT OUT OF LIGHT.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURIC CHLORIDE, SOLID
|
||||
HAZARD CLASS POISON B
|
||||
UN/NA UN1624
|
||||
LABELS POISON
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURIC CHLORIDE
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1624
|
||||
LABELS POISON
|
||||
|
||||
415
textfiles.com/science/CHEMICALS/mercuric_oxycyanide.txt
Normal file
415
textfiles.com/science/CHEMICALS/mercuric_oxycyanide.txt
Normal file
@@ -0,0 +1,415 @@
|
||||
|
||||
Common Name: Mercuric Oxycyanide
|
||||
CAS Number: 1335-31-5
|
||||
DOT Number: UN 1642
|
||||
Date: September 28, 1987
|
||||
-----------------------------------------
|
||||
|
||||
HAZARD SUMMARY
|
||||
* Mercuric Oxycyanide can affect you when breathed and by
|
||||
passing through skin.
|
||||
* Overexposures can cause kidney damage.
|
||||
* Mercury poisoning can cause "shakes", irritability, sore gums,
|
||||
memory loss, increased saliva, personality change and even
|
||||
permanent brain damage.
|
||||
* Skin contact can cause irritation, skin allergy, or a gray
|
||||
skin color.
|
||||
* Eye contact causes irritation.
|
||||
* Heating or use near acid can release toxic Mercury and Cyanide
|
||||
vapors.
|
||||
* Health effects have been reported below NIOSH exposure levels.
|
||||
|
||||
IDENTIFICATION
|
||||
Mercuric Oxycyanide is a white crystalline powder (sugar or sand-
|
||||
like). It has been used in medicine as a topical antiseptic.
|
||||
|
||||
REASON FOR CITATION
|
||||
* Mercuric Oxycyanide is on the Hazardous Substance List because
|
||||
it is cited by NIOSH, ACGIH and DOT.
|
||||
|
||||
HOW TO DETERMINE IF YOU ARE BEING EXPOSED
|
||||
* Exposure to hazardous substances should be routinely
|
||||
evaluated. This may include collecting personal and area air
|
||||
samples. You can obtain copies of sampling results from your
|
||||
employer. You have a legal right to this information under
|
||||
OSHA 1910.20.
|
||||
* If you think you are experiencing any work-related health
|
||||
problems, see a doctor trained to recognize occupational
|
||||
diseases. Take this Fact Sheet with you.
|
||||
-----------------------------------------
|
||||
|
||||
WORKPLACE EXPOSURE LIMITS
|
||||
OSHA: The legal airborne permissible exposure limit (PEL) is
|
||||
0.1 mg/m3 for Mercury and inorganic compounds measured as
|
||||
Mercury, not to be exceeded at any time.
|
||||
NIOSH: The recommended airborne exposure limit is 0.05 mg/m3
|
||||
averaged over an 8 hour workshift for Mercury, inorganic,
|
||||
and measured as Mercury.
|
||||
ACGIH: The recommended airborne exposure limit is 0.1 mg/m3 for
|
||||
inorganic compounds and 0.05 mg/m3 of Mercury vapor
|
||||
averaged over an 8-hour workshift and measured as
|
||||
Mercury.
|
||||
|
||||
* The above exposure limits are for air levels only. When skin
|
||||
contact also occurs, you may be overexposed, even though air
|
||||
levels are less than the limits listed above.
|
||||
|
||||
WAYS OF REDUCING EXPOSURE
|
||||
* Where possible, enclose operations and use local exhaust
|
||||
ventilation at the site of chemical release. If local exhaust
|
||||
ventilation or enclosure is not used, respirators should be
|
||||
worn.
|
||||
* Wear protective work clothing.
|
||||
* Wash thoroughly immediately after exposure to Mercuric
|
||||
Oxycyanide and at the end of the workshift.
|
||||
* Post hazard and warning information in the work area. In
|
||||
addition, as part of an ongoing education and training effort,
|
||||
communicate all information on the health and safety hazards
|
||||
of Mercuric Oxycyanide to potentially exposed workers.
|
||||
|
||||
This Fact Sheet is a summary source of information of all potential
|
||||
and most severe health hazards that may result from exposure.
|
||||
Duration of exposure, concentration of the substance and other
|
||||
factors will affect your susceptibility to any of the potential
|
||||
effects described below.
|
||||
------------------------------------------
|
||||
|
||||
HEALTH HAZARD INFORMATION
|
||||
|
||||
Acute Health Effects
|
||||
The following acute (short-term) health effects may occur
|
||||
immediately or shortly after exposure to Mercuric Oxycyanide:
|
||||
|
||||
* Mercuric Oxycyanide can affect you when breathed in and by
|
||||
passing through your skin.
|
||||
* Direct contact causes eye irritation and possible damage and
|
||||
may irritate the skin.
|
||||
* Heating or contact with acid or acid mist causes release of
|
||||
toxic Mercury and Cyanide vapors and lung effects of
|
||||
bronchitis and phlegm and/or lung irritation. Overexposure to
|
||||
Cyanide can cause sudden death.
|
||||
* Breathing Mercuric Oxycyanide causes irritation of the throat
|
||||
and air passages.
|
||||
|
||||
Chronic Health Effects
|
||||
The following chronic (long-term) health effects can occur at some
|
||||
time after exposure to Mercuric Oxycyanide and can last for months
|
||||
or years:
|
||||
|
||||
Cancer Hazard
|
||||
* According to the information presently available to the New
|
||||
Jersey Department of Health, Mercuric Oxycyanide has not been
|
||||
tested for its ability to cause cancer in animals.
|
||||
|
||||
Reproductive Hazard
|
||||
* Mercuric Oxycyanide has not been tested for its ability to
|
||||
cause reproductive damage, but it should be HANDLED WITH
|
||||
CAUTION since some related Mercury compounds damage the
|
||||
developing fetus and decrease fertility in males and females.
|
||||
* Organic Mercury substances (organic substances are those which
|
||||
contain carbon) have been identified as human teratogens.
|
||||
While inorganic Mercury substances (those without carbon) such
|
||||
as Mercuric Oxycyanide have not been shown to be human
|
||||
teratogens, they still should be handled with caution as they
|
||||
may cause reproductive problems in males and females.
|
||||
|
||||
Other Long-Term Effects
|
||||
* High or repeated exposure can cause kidney damage or Mercury
|
||||
poisoning. Mercury poisoning causes sore gums, "shakes"
|
||||
(often with shaky handwriting), irritability and increased
|
||||
saliva. Other changes may include memory loss, extreme
|
||||
shyness, weakness, poor appetite and metallic taste. Serious
|
||||
personality changes and brain damage may occur, especially if
|
||||
exposure continues.
|
||||
* Repeated skin contact may make the skin turn gray.
|
||||
* Exposure can also cause brown staining in the eye and may
|
||||
affect peripheral vision (the ability to see to the side).
|
||||
* Skin allergy may also occur. If this happens, even small
|
||||
future exposures can cause rash.
|
||||
* Mercury can accumulate in the body with repeated exposure. It
|
||||
can take months or years for the body to get rid of excess
|
||||
Mercury.
|
||||
|
||||
MEDICAL
|
||||
|
||||
Medical Testing
|
||||
Before first exposure and every 6 to 12 months after, a complete
|
||||
medical history and exam is strongly recommended, with:
|
||||
|
||||
* Exam of the nervous system, including handwriting.
|
||||
* Routine urine test (UA).
|
||||
* Urine test for Mercury (should be less than 0.02 mg/liter).
|
||||
* Eye exam.
|
||||
|
||||
After suspected illness or overexposure, repeat the tests above AND
|
||||
get a blood test for Mercury.
|
||||
|
||||
Any evaluation should include a careful history of past and present
|
||||
symptoms with an exam. Medical tests that look for damage already
|
||||
done are not a substitute for controlling exposure. Request copies
|
||||
of your medical testing. You have a legal right to this
|
||||
information under OSHA 1910.20.
|
||||
|
||||
Mixed Exposures
|
||||
Creams to whiten or bleach skin may contain Mercury; if so, their
|
||||
use increases risk.
|
||||
|
||||
Conditions Made Worse By Exposure
|
||||
Persons allergic to Mercury may also react to Mercurochrome or
|
||||
Merthiolate, which contain Mercury.
|
||||
|
||||
WORKPLACE CONTROLS AND PRACTICES
|
||||
|
||||
Unless a less toxic chemical can be substituted for a hazardous
|
||||
substance, ENGINEERING CONTROLS are the most effective way of
|
||||
reducing exposure. The best protection is to enclose operations
|
||||
and/or provide local exhaust ventilation at the site of chemical
|
||||
release. Isolating operations can also reduce exposure. Using
|
||||
respirators or protective equipment is less effective than the
|
||||
controls mentioned above, but is sometimes necessary.
|
||||
|
||||
In evaluating the controls present in your workplace, consider: (1)
|
||||
how hazardous the substance is, (2) how much of the substance is
|
||||
released into the workplace and (3) whether harmful skin or eye
|
||||
contact could occur. Special controls should be in place for
|
||||
highly toxic chemicals or when significant skin, eye, or breathing
|
||||
exposures are possible.
|
||||
|
||||
In addition, the following controls are recommended:
|
||||
|
||||
* Vigorous, periodic cleaning of all work surfaces.
|
||||
* Where possible, automatically transfer Mercuric Oxycyanide
|
||||
from drums or other storage containers to process containers.
|
||||
* Specific engineering controls are recommended for this
|
||||
chemical by NIOSH. Refer to the NIOSH criteria document:
|
||||
Occupational Exposures to inorganic Mercury #73-11024 and
|
||||
Hydrogen Cyanide and Cyanide Salts #77-108.
|
||||
|
||||
Good WORK PRACTICES can help to reduce hazardous exposures. The
|
||||
following work practices are recommended:
|
||||
|
||||
* Workers whose clothing has been contaminated by Mercuric
|
||||
Oxycyanide should change into clean clothing promptly.
|
||||
* Do not take contaminated work clothes home. Family members
|
||||
could be exposed.
|
||||
* Contaminated work clothes should be laundered by individuals
|
||||
who have been informed of the hazards of exposure to Mercuric
|
||||
Oxycyanide.
|
||||
* Eye wash fountains should be provided in the immediate work
|
||||
area for emergency use.
|
||||
* On skin contact with Mercuric Oxycyanide, immediately wash or
|
||||
shower to remove the chemical. At the end of the workshift,
|
||||
wash any areas of the body that may have contacted Mercuric
|
||||
Oxycyanide, whether or not known skin contact has occurred.
|
||||
* Do not eat, smoke, or drink where Mercuric Oxycyanide is
|
||||
handled, processed, or stored, since the chemical can be
|
||||
swallowed. Wash hands carefully before eating or smoking.
|
||||
* For clean-up use a specialized charcoal-filtered vacuum or
|
||||
suction pump to avoid generating Mercury vapor. Care should
|
||||
be taken not to disturb spilled material.
|
||||
|
||||
PERSONAL PROTECTIVE EQUIPMENT
|
||||
|
||||
WORKPLACE CONTROLS ARE BETTER THAN PERSONAL PROTECTIVE EQUIPMENT.
|
||||
However, for some jobs (such as outside work, confined space entry,
|
||||
jobs done only once in a while, or jobs done while workplace
|
||||
controls are being installed), personal protective equipment may be
|
||||
appropriate.
|
||||
|
||||
The following recommendations are only guidelines and may not apply
|
||||
to every situation.
|
||||
|
||||
Clothing
|
||||
* Avoid skin contact with Mercuric Oxycyanide. Wear protective
|
||||
gloves and clothing. Safety equipment suppliers/ manufacturers
|
||||
can provide recommendations on the most protective glove/
|
||||
clothing material for your operation.
|
||||
* Non-absorbent materials are recommended.
|
||||
* All protective clothing (suits, gloves, footwear, headgear)
|
||||
should be clean, available each day and put on before work.
|
||||
|
||||
Eye Protection
|
||||
* Wear dust-proof goggles and face shield when working with
|
||||
powders or dust, unless full facepiece respiratory protection
|
||||
is worn.
|
||||
|
||||
Respiratory Protection
|
||||
IMPROPER USE OF RESPIRATORS IS DANGEROUS. Such equipment should
|
||||
only be used if the employer has a written program that takes into
|
||||
account workplace conditions, requirements for worker training,
|
||||
respirator fit testing and medical exams, as described in OSHA
|
||||
1910.134.
|
||||
|
||||
* Where the potential exists for exposures over 0.05 mg/m3 as
|
||||
Mercury, use a MSHA/NIOSH approved supplied-air respirator
|
||||
with a full facepiece operated in the positive pressure mode
|
||||
or with a full facepiece, hood, or helmet in the continuous
|
||||
flow mode, or use a MSHA/ NIOSH approved self-contained
|
||||
breathing apparatus with a full facepiece operated in
|
||||
pressure-demand or other positive pressure mode.
|
||||
|
||||
ADDITIONAL WORKPLACE EXPOSURE LIMITS for Cyanides measured as
|
||||
Cyanide.
|
||||
|
||||
OSHA: The legal airborne permissible exposure limit (PEL) is 5
|
||||
mg/m3 averaged over an 8-hour work-shift.
|
||||
NIOSH: The recommended airborne exposure limit is 5 mg/m3, which
|
||||
should not be exceeded during any 10 minute work period.
|
||||
ACGIH: The recommended airborne exposure limit is 5 mg/m3
|
||||
averaged over an 8-hour workshift.
|
||||
|
||||
Common Name: Mercuric Oxycyanide
|
||||
DOT Number: UN 1642
|
||||
DOT Emergency Guide code: 53
|
||||
CAS Number: 1335-31-5
|
||||
----------------------------------------
|
||||
NJ DOH Hazard rating
|
||||
FLAMMABILITY 1
|
||||
REACTIVITY 3
|
||||
-----------------------------------------
|
||||
CYANIDE GAS RELEASED IN FIRE
|
||||
EXPLOSIVE
|
||||
-----------------------------------------
|
||||
Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious;
|
||||
4=severe
|
||||
|
||||
FIRE HAZARDS
|
||||
|
||||
* Mercuric Oxycyanide may burn, but does not readily ignite.
|
||||
* Use dry chemical, CO2, water spray, or foam extinguishers.
|
||||
* POISONOUS GASES ARE PRODUCED IN FIRE, including Cyanide gas
|
||||
and Oxides of Nitrogen.
|
||||
* CONTAINERS MAY EXPLODE IN FIRE.
|
||||
* If employees are expected to fight fires, they must be trained
|
||||
and equipped as stated in OSHA 1910.156.
|
||||
|
||||
SPILLS AND EMERGENCIES
|
||||
|
||||
If Mercuric Oxycyanide is spilled, take the following steps:
|
||||
|
||||
* Restrict persons not wearing protective equipment from area of
|
||||
spill until clean-up is complete.
|
||||
* Remove all ignition sources.
|
||||
* Spills should be collected with special Mercury vapor
|
||||
suppressants or special vacuums. Kits specific for clean-up
|
||||
of Mercury spills are available.
|
||||
* It may be necessary to contain and dispose of Mercuric
|
||||
Oxycyanide as a HAZARDOUS WASTE. Contact the NJ Department of
|
||||
Environmental Protection (DEP) or your regional office of the
|
||||
federal Environmental Protection Agency (EPA) for specific
|
||||
recommendations.
|
||||
==========================================
|
||||
FOR LARGE SPILLS AND FIRES immediately call your fire department.
|
||||
==========================================
|
||||
|
||||
HANDLING AND STORAGE
|
||||
|
||||
* Prior to working with Mercuric Oxycyanide you should be
|
||||
trained on its proper handling and storage.
|
||||
* Mercuric Oxycyanide is self reactive. Friction, heat and
|
||||
rough handling may cause an explosion.
|
||||
* Store in tightly closed containers in a cool, well-ventilated
|
||||
area.
|
||||
|
||||
FIRST AID
|
||||
Eye Contact
|
||||
* Immediately flush with large amounts of water for at least 15
|
||||
minutes, occasionally lifting upper and lower lids. Seek
|
||||
medical attention promptly.
|
||||
|
||||
Skin Contact
|
||||
* Quickly remove contaminated clothing. Immediately wash
|
||||
contaminated skin with large amounts of water.
|
||||
|
||||
Breathing
|
||||
* Remove the person from exposure.
|
||||
* Transfer promptly to a medical facility.
|
||||
|
||||
PHYSICAL DATA
|
||||
|
||||
Water Solubility: Slightly soluble
|
||||
|
||||
OTHER COMMONLY USED NAMES
|
||||
|
||||
Chemical Name:
|
||||
Mercury Cyanide Oxide
|
||||
|
||||
Other Names and Formulations:
|
||||
Mercury Oxycyanide.
|
||||
------------------------------------------
|
||||
Not intended to be copied and sold for commercial purposes.
|
||||
------------------------------------------
|
||||
|
||||
NEW JERSEY DEPARTMENT OF HEALTH
|
||||
Right to Know Project
|
||||
CN 368, Trenton, NJ 08625-0368
|
||||
------------------------------------------
|
||||
------------------------------------------
|
||||
|
||||
ECOLOGICAL INFORMATION
|
||||
|
||||
Elemental mercury is a heavy and relatively inert liquid which is
|
||||
oxidized to inorganic mercury (II) under natural conditions.
|
||||
Mercury (II) may combine with an organic fraction to from
|
||||
methylmercury. Both mercury (II) and methylmercury are of
|
||||
environmental concern. Mercury (II) may enter the environment in
|
||||
industrial or municipal waste treatment discharges, from previously
|
||||
contaminated sediments, and from the weathering of natural rocks.
|
||||
Bacteria may then convert it into methylmercury. The concentration
|
||||
of mercury (II) in bodies of water may be elevated with acid rain
|
||||
due to the scouring of mercury from the air and increased
|
||||
partitioning from the sediment into the water.
|
||||
|
||||
ACUTE (SHORT TERM) ECOLOGICAL EFFECTS
|
||||
|
||||
Acute toxic effects may include the death of animals, birds, or
|
||||
fish, and death or low growth rate in plants. Acute effects are
|
||||
seen two to four days after animals or plants come in contact with
|
||||
a toxic chemical substance.
|
||||
|
||||
Mercury(II) and methylmercury has high acute toxicity to aquatic
|
||||
life. Insufficient data are available to evaluate or predict the
|
||||
short term effects of mercury (II) or methylmercury to plants,
|
||||
birds, or land animals.
|
||||
|
||||
CHRONIC (LONG-TERM) ECOLOGICAL EFFECTS
|
||||
|
||||
Chronic toxic effects may include shortened lifespan, reproductive
|
||||
problems, lower fertility, and changes in appearance or behavior.
|
||||
Chronic effects can be seen long after first exposure(s) to a
|
||||
toxic chemical.
|
||||
|
||||
Mercury (II) and methylmercury have high chronic toxicity to
|
||||
aquatic life. Eating fish contaminated with mercury residues has
|
||||
caused secondary poisoning in humans: birds or land animals
|
||||
similarly exposed to mercury and its compounds could also be
|
||||
subject to such effects. Insufficient data are available to
|
||||
evaluate or predict the long-term effects of mercury and its
|
||||
compounds to plants.
|
||||
|
||||
DISTRIBUTION AND PERSISTENCE IN THE ENVIRONMENT
|
||||
|
||||
Mercury is highly persistent in water, with a half-life greater
|
||||
than 200 days. The half-life of a pollutant is the amount of time
|
||||
it takes for one-half of the chemical to be degraded.
|
||||
|
||||
|
||||
BIOACCUMULATION IN AQUATIC ORGANISMS
|
||||
|
||||
Some substances increase in concentration, or bioaccumulate, in
|
||||
living organisms as they breathe contaminated air, drink
|
||||
contaminated water, or eat contaminated food. These chemicals can
|
||||
become concentrated in the tissues and internal organs of animals
|
||||
and humans.
|
||||
The concentration of mercury(II) and methylmercury found in fish
|
||||
tissues is expected to be considerably higher than the average
|
||||
concentration of mercury(II) or methylmercury in the water from
|
||||
which the fish was taken.
|
||||
|
||||
SUPPORT DOCUMENT: AQUIRE Database, ERL, Duluth, U.S.EPA,
|
||||
Phytotox.
|
||||
|
||||
|
||||
|
||||
...............................................................................
|
||||
.
|
||||
188
textfiles.com/science/CHEMICALS/mercuric_thiocyanate.txt
Normal file
188
textfiles.com/science/CHEMICALS/mercuric_thiocyanate.txt
Normal file
@@ -0,0 +1,188 @@
|
||||
|
||||
MSDS - MERCURIC THIOCYANATE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MERCURIC THIOCYANATE
|
||||
FORMULA: HG(SCN)2
|
||||
FORMULA WT: 316.78
|
||||
CAS NO.: 00592-85-8
|
||||
NIOSH/RTECS NO.: XL1550000
|
||||
COMMON SYNONYMS: MERCURY(II)THIOCYANATE; MERCURIC SULFOCYANATE; MERCURIC
|
||||
SULFOCYANIDE
|
||||
PRODUCT CODES: P651
|
||||
EFFECTIVE: 10/31/85
|
||||
REVISION #01
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (LIFE)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 3 SEVERE (LIFE)
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
EXCEPTIONAL HEALTH AND CONTACT HAZARDS - READ MATERIAL SAFETY DATA SHEET
|
||||
MAY BE FATAL IF SWALLOWED
|
||||
HARMFUL IF ABSORBED THROUGH SKIN
|
||||
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MERCURIC THIOCYANATE 90-100 592-85-8
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: N/A VAPOR DENSITY(AIR=1): 11
|
||||
|
||||
SPECIFIC GRAVITY: N/A EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE, ODORLESS POWDER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.1 MG/M3 ( PPM)
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
CHRONIC EFFECTS OF MERCURY POISONING INCLUDE A BUILDUP OF THE
|
||||
METAL IN THE BRAIN, LIVER AND KIDNEYS. SYMPTOMS INCLUDE HEADACHE,
|
||||
TREMORS, LOOSE TEETH, LOSS OF APPETITE, BLISTERS ON THE SKIN AND
|
||||
IMPAIRED MEMORY.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE CENTRAL NERVOUS SYSTEM
|
||||
DEPRESSION.
|
||||
SKIN ABSORPTION MAY BE HARMFUL OR FATAL.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, LIGHT, MOISTURE
|
||||
|
||||
INCOMPATIBLES: STRONG ACIDS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D009 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION
|
||||
EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURIC THIOCYANATE, SOLID
|
||||
HAZARD CLASS POISON B
|
||||
UN/NA UN1646
|
||||
LABELS POISON
|
||||
REPORTABLE QUANTITY 10 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURY THIOCYANATE
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1646
|
||||
LABELS POISON
|
||||
|
||||
208
textfiles.com/science/CHEMICALS/mercury_oxide_red.txt
Normal file
208
textfiles.com/science/CHEMICALS/mercury_oxide_red.txt
Normal file
@@ -0,0 +1,208 @@
|
||||
|
||||
MSDS - MERCURIC OXIDE, RED
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MERCURIC OXIDE, RED
|
||||
FORMULA: HGO
|
||||
FORMULA WT: 216.59
|
||||
CAS NO.: 21908-53-2
|
||||
NIOSH/RTECS NO.: OW8750000
|
||||
COMMON SYNONYMS: MERCURY(II)OXIDE, RED
|
||||
PRODUCT CODES: 2620,2622
|
||||
EFFECTIVE: 09/26/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 4 EXTREME (POISON)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 3 SEVERE (LIFE)
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
EXCEPTIONAL CONTACT HAZARD - READ MATERIAL SAFETY DATA SHEET
|
||||
MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN
|
||||
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MERCURIC OXIDE 90-100 21908-53-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 500 C ( 932 F) DECOMPOSES VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 11.14 EVAPORATION RATE: 0.6
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: BRIGHT RED OR ORANGE-RED HEAVY POWDER WITH NO ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
NOTE: DECOMPOSES AT MELTING POINT.
|
||||
CAN REACT VIOLENTLY WITH SHOCK, FRICTION OR HEAT.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE, MERCURY FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PEL LISTED DENOTES CEILING LIMIT.
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.1 MG/M3 ( PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 0.1 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 18
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
ACUTE POISONING VIA ALL ROUTES OF EXPOSURE MAY BE SEVERE ENOUGH TO BE
|
||||
FATAL.
|
||||
DUST INHALATION MAY CAUSE TIGHTNESS AND PAIN IN CHEST, COUGHING, AND
|
||||
DIFFICULTY IN BREATHING.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS. PROLONGED
|
||||
CONTACT MAY CAUSE SKIN SENSITIZATION. SUBSTANCE IS READILY ABSORBED
|
||||
THROUGH THE SKIN.
|
||||
PROLONGED EYE CONTACT MAY CAUSE PERMANENT DAMAGE TO THE CORNEA AND
|
||||
BLINDNESS MAY OCCUR.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, GASTROINTESTINAL IRRITATION, AND
|
||||
BURNS TO MOUTH AND THROAT.
|
||||
CHRONIC EFFECTS OF MERCURY POISONING INCLUDE A BUILDUP OF THE
|
||||
METAL IN THE BRAIN, LIVER AND KIDNEYS. SYMPTOMS INCLUDE HEADACHE,
|
||||
TREMORS, LOOSE TEETH, LOSS OF APPETITE, BLISTERS ON THE SKIN AND
|
||||
IMPAIRED MEMORY.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN, RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, KIDNEYS
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
ALLERGIES, CHRONIC RESPIRATORY DISEASE, NERVE SYSTEM DISORDERS,
|
||||
KIDNEY DISORDERS
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, ABSORPTION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
|
||||
WASH CLOTHING BEFORE RE-USE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: LIGHT, HEAT
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS, STRONG OXIDIZING AGENTS,
|
||||
AMINES, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS,
|
||||
PHENOL
|
||||
|
||||
DECOMPOSITION PRODUCTS: MERCURY FUMES, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D009 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE APPROPRIATE VENTILATION
|
||||
CONDITIONS EXIST. IF THE TLV IS EXCEEDED, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP PRODUCT OUT OF LIGHT.
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
STORE IN LIGHT-RESISTANT CONTAINERS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURIC OXIDE, SOLID
|
||||
HAZARD CLASS POISON B
|
||||
UN/NA UN1641
|
||||
LABELS POISON
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURIC OXIDE, SOLID
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1641
|
||||
LABELS POISON
|
||||
|
||||
200
textfiles.com/science/CHEMICALS/mercury_oxide_yel.txt
Normal file
200
textfiles.com/science/CHEMICALS/mercury_oxide_yel.txt
Normal file
@@ -0,0 +1,200 @@
|
||||
|
||||
MSDS - MERCURIC OXIDE, YELLOW
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: MERCURIC OXIDE, YELLOW,
|
||||
FORMULA: HGO
|
||||
FORMULA WT: 216.59
|
||||
CAS NO.: 21908-53-2
|
||||
NIOSH/RTECS NO.: OW8750000
|
||||
COMMON SYNONYMS: MERCURY(II)OXIDE, YELLOW
|
||||
PRODUCT CODES: 2630
|
||||
EFFECTIVE: 11/11/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 4 EXTREME (POISON)
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 3 SEVERE (LIFE)
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN
|
||||
EXCEPTIONAL HEALTH AND CONTACT HAZARDS - READ MATERIAL SAFETY DATA SHEET
|
||||
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
DO NOT BREATHE DUST. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
|
||||
VENTILATION. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
MERCURIC OXIDE 90-100 21908-53-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 500 C ( 932 F) DECOMPOSES VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 11.14 EVAPORATION RATE: 0.6
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: YELLOW TO ORANGE YELLOW, HEAVY POWDER WITH NO ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
NOTE: DECOMPOSES AT MELTING POINT.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE, MERCURY FUMES
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TLV LISTED DENOTES (TLV-SKIN).
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 0.1 MG/M3 ( PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 18
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION OF VAPORS MAY CAUSE COUGHING, CHEST PAINS, DIFFICULTY BREATHING,
|
||||
OR UNCONSCIOUSNESS.
|
||||
PROLONGED EYE CONTACT MAY CAUSE PERMANENT DAMAGE TO THE CORNEA AND
|
||||
BLINDNESS MAY OCCUR.
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
SUBSTANCE IS READILY ABSORBED THROUGH THE SKIN.
|
||||
INHALATION AND INGESTION ARE HARMFUL AND MAY BE FATAL.
|
||||
CHRONIC EFFECTS OF MERCURY POISONING INCLUDE A BUILDUP OF THE
|
||||
METAL IN THE BRAIN, LIVER AND KIDNEYS. SYMPTOMS INCLUDE HEADACHE,
|
||||
TREMORS, LOOSE TEETH, LOSS OF APPETITE, BLISTERS ON THE SKIN AND
|
||||
IMPAIRED MEMORY.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
|
||||
WASH CLOTHING BEFORE RE-USE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: LIGHT, HEAT
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS, STRONG OXIDIZING AGENTS,
|
||||
AMINES, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS,
|
||||
PHENOL
|
||||
|
||||
DECOMPOSITION PRODUCTS: MERCURY FUMES, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND
|
||||
COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D009 (EP TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE APPROPRIATE VENTILATION
|
||||
CONDITIONS EXIST. IF THE TLV IS EXCEEDED, A SELF-
|
||||
CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP PRODUCT OUT OF LIGHT.
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
STORE IN LIGHT-RESISTANT CONTAINERS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURIC OXIDE, SOLID
|
||||
HAZARD CLASS POISON B
|
||||
UN/NA UN1641
|
||||
LABELS POISON
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME MERCURIC OXIDE, SOLID
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1641
|
||||
LABELS POISON
|
||||
|
||||
225
textfiles.com/science/CHEMICALS/methyl_alcohol.txt
Normal file
225
textfiles.com/science/CHEMICALS/methyl_alcohol.txt
Normal file
@@ -0,0 +1,225 @@
|
||||
|
||||
MSDS - METHANOL
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: METHANOL
|
||||
FORMULA: CH3OH
|
||||
FORMULA WT: 32.04
|
||||
CAS NO.: 67-56-1
|
||||
NIOSH/RTECS NO.: PC1400000
|
||||
COMMON SYNONYMS: METHYL ALCOHOL; WOOD ALCOHOL; CARBINOL; METHYLOL; WOOD
|
||||
SPIRIT
|
||||
PRODUCT CODES: 9049,9072,9075,9076,9071,5217,5370,9074,P704,9093,5536,9068
|
||||
9073,9091,9263,9069,9070
|
||||
EFFECTIVE: 09/26/86
|
||||
REVISION #04
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (POISON)
|
||||
FLAMMABILITY - 3 SEVERE (FLAMMABLE)
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B
|
||||
EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
FLAMMABLE
|
||||
HARMFUL IF INHALED
|
||||
CANNOT BE MADE NON-POISONOUS
|
||||
MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE.
|
||||
FLUSH SPILL AREA WITH WATER SPRAY.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
METHANOL 90-100 67-56-1
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 65 C ( 149 F) VAPOR PRESSURE(MM HG): 96
|
||||
|
||||
MELTING POINT: -98 C ( -144 F) VAPOR DENSITY(AIR=1): 1.11
|
||||
|
||||
SPECIFIC GRAVITY: 0.79 EVAPORATION RATE: 4.6
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100
|
||||
|
||||
APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID WITH CHARACTERISTIC PUNGENT ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP 12 C ( 54 F) NFPA 704M RATING: 1-3-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 36.0 % LOWER - 6.0 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
(WATER MAY BE INEFFECTIVE.)
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK.
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG
|
||||
OXIDIZERS MAY CAUSE FIRE.
|
||||
BURNS WITH A CLEAR, ALMOST INVISIBLE FLAME.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
TLV LISTED DENOTES (TLV-SKIN).
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 260 MG/M3 ( 200 PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 310 MG/M3 ( 250 PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 260 MG/M3 ( 200 PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 5628
|
||||
LD50 (IPR-RAT)(MG/KG) - 9540
|
||||
LD50 (SCU-MOUSE)(MG/KG) - 9800
|
||||
LD50 (SKN-RABBIT) (G/KG) - 20
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION AND INGESTION ARE HARMFUL AND MAY BE FATAL.
|
||||
INHALATION MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS,
|
||||
SUFFOCATION, LOWER BLOOD PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION.
|
||||
LIQUID MAY BE IRRITATING TO SKIN AND EYES. PROLONGED SKIN CONTACT MAY
|
||||
RESULT IN DERMATITIS. EYE CONTACT MAY RESULT IN TEMPORARY CORNEAL DAMAGE.
|
||||
INGESTION MAY CAUSE BLINDNESS.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN, CENTRAL NERVOUS SYSTEM
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
|
||||
WASH CLOTHING BEFORE RE-USE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG ACIDS, ALUMINUM
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK
|
||||
IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP
|
||||
WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO
|
||||
CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
|
||||
|
||||
J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED
|
||||
FOR SPILLS OF THIS PRODUCT.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: U154 (TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS
|
||||
ABOVE 200 PPM, A SELF-CONTAINED BREATHING
|
||||
APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM,
|
||||
PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. KEEP CONTAINER
|
||||
TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID
|
||||
STORAGE AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME METHANOL
|
||||
HAZARD CLASS FLAMMABLE LIQUID
|
||||
UN/NA UN1230
|
||||
LABELS FLAMMABLE LIQUID
|
||||
REPORTABLE QUANTITY 5000 LBS.
|
||||
|
||||
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME METHANOL
|
||||
HAZARD CLASS 3.2, 6.1
|
||||
UN/NA UN1230
|
||||
LABELS FLAMMABLE LIQUID, POISON
|
||||
|
||||
168
textfiles.com/science/CHEMICALS/methylene_blue.txt
Normal file
168
textfiles.com/science/CHEMICALS/methylene_blue.txt
Normal file
@@ -0,0 +1,168 @@
|
||||
|
||||
MSDS - METHYLENE BLUE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: METHYLENE BLUE
|
||||
FORMULA: C16H18CLN3S 3H2O
|
||||
FORMULA WT: 373.91
|
||||
CAS NO.: 7220-79-3
|
||||
COMMON SYNONYMS: BASIC BLUE 9
|
||||
PRODUCT CODES: Q473,2702,Q475
|
||||
EFFECTIVE: 11/24/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 0 NONE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: 190 C ( 374 F) VAPOR DENSITY(AIR=1): 13
|
||||
|
||||
SPECIFIC GRAVITY: N/A EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: ODORLESS, DARK GREEN CRYSTALS WITH A BRONZE LUSTRE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
NITROGEN OXIDES, SULFUR DIOXIDE, CHLORINE, HYDROGEN CHLORIDE,
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
NO EFFECTS OF OVEREXPOSURE WERE DOCUMENTED.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
EYE CONTACT, SKIN CONTACT, INHALATION, INGESTION
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: NONE DOCUMENTED
|
||||
|
||||
INCOMPATIBLES: STRONG REDUCING AGENTS, CAUSTICS, ALKALIES,
|
||||
STRONG OXIDIZING AGENTS
|
||||
|
||||
DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN, OXIDES OF SULFUR,
|
||||
CHLORINE AND CHLORINE COMPOUNDS,
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
216
textfiles.com/science/CHEMICALS/methylene_chloride.txt
Normal file
216
textfiles.com/science/CHEMICALS/methylene_chloride.txt
Normal file
@@ -0,0 +1,216 @@
|
||||
|
||||
MSDS - METHYLENE CHLORIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: METHYLENE CHLORIDE
|
||||
FORMULA: CH2CL2
|
||||
FORMULA WT: 84.93
|
||||
CAS NO.: 75-09-2
|
||||
NIOSH/RTECS NO.: PA8050000
|
||||
COMMON SYNONYMS: DICHLOROMETHANE; METHYLENE DICHLORIDE; METHANE DICHLORIDE
|
||||
PRODUCT CODES: 9324,9341,Q480,9330,5378,5531,9315,9329,9264
|
||||
EFFECTIVE: 10/24/86
|
||||
REVISION #03
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (CANCER CAUSING)
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 1 SLIGHT
|
||||
CONTACT - 2 MODERATE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
POISON DANGER
|
||||
CAUSES IRRITATION
|
||||
HARMFUL IF ABSORBED THROUGH SKIN
|
||||
MAY BE FATAL IF SWALLOWED OR INHALED
|
||||
NOTE: REPORTED AS CAUSING CANCER IN LABORATORY ANIMALS. EXERCISE DUE CARE.
|
||||
AVOID CONTACT WITH EYES, SKIN, CLOTHING.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
METHYLENE CHLORIDE 90-100 75-09-2
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 40 C ( 104 F) VAPOR PRESSURE(MM HG): 350
|
||||
|
||||
MELTING POINT: -95 C ( -139 F) VAPOR DENSITY(AIR=1): 2.9
|
||||
|
||||
SPECIFIC GRAVITY: 1.32 EVAPORATION RATE: 27.5
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: 100
|
||||
|
||||
APPEARANCE & ODOR: COLORLESS,VOLATILE LIQUID WITH PENETRATING,ETHER-LIKE ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP N/A NFPA 704M RATING: 2-1-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 19 % LOWER - 12 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
HYDROGEN CHLORIDE, PHOSGENE, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
ACGIH DENOTES THAT THIS SUBSTANCE IS SUSPECT OF CARCINOGENIC POTENTIAL
|
||||
FOR MAN.
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 350 MG/M3 ( 100 PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 1740 MG/M3 ( 500 PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): MG/M3 ( 500 PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 2524
|
||||
LD50 (IPR-MOUSE)(MG/KG) - 1500
|
||||
LD50 (SCU-MOUSE)(MG/KG) - 6460
|
||||
LC50 (INHAL-RAT-)(G/M3) - 88
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
INHALATION AND INGESTION ARE HARMFUL AND MAY BE FATAL.
|
||||
INHALATION MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS,
|
||||
SUFFOCATION, LOWER BLOOD PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION.
|
||||
INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY SYSTEM.
|
||||
LIQUID MAY BE IRRITATING TO SKIN AND EYES. PROLONGED SKIN CONTACT MAY
|
||||
RESULT IN DERMATITIS. EYE CONTACT MAY RESULT IN TEMPORARY CORNEAL DAMAGE.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, GASTROINTESTINAL IRRITATION, AND
|
||||
BURNS TO MOUTH AND THROAT.
|
||||
|
||||
TARGET ORGANS
|
||||
SKIN, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM, EYES
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, SKIN CONTACT, EYE CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, DO NOT INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
ACCEPTABLE MAXIMUM PEAK ABOVE THE ACCEPTANCE CEILING CONCENTRATION FOR
|
||||
AN 8 HOUR SHIFT = 2000 PPM FOR 5 MINUTES IN ANY 2HOURS. (PEL) CEILING
|
||||
= 1000 PPM
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, MOISTURE
|
||||
|
||||
INCOMPATIBLES: ALKALI METALS, STRONG OXIDIZING AGENTS, STRONG BASES,
|
||||
OXIDES OF NITROGEN, ZINC, ALUMINUM, WATER, MAGNESIUM,
|
||||
AMINES
|
||||
|
||||
DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, PHOSGENE,
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS.
|
||||
TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE
|
||||
INTO CONTAINER FOR LATER DISPOSAL. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: U080 (TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS
|
||||
ABOVE 100 PPM, A SELF-CONTAINED BREATHING
|
||||
APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM,
|
||||
PROTECTIVE SUIT, POLYVINYL ALCOHOL GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA.
|
||||
KEEP CONTAINERS OUT OF SUN AND AWAY FROM HEAT.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME DICHLOROMETHANE (AIR ONLY)
|
||||
HAZARD CLASS ORM-A
|
||||
UN/NA UN1593
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 1000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME DICHLOROMETHANE
|
||||
HAZARD CLASS 6.1
|
||||
UN/NA UN1593
|
||||
LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS
|
||||
|
||||
195
textfiles.com/science/CHEMICALS/naphthalene.txt
Normal file
195
textfiles.com/science/CHEMICALS/naphthalene.txt
Normal file
@@ -0,0 +1,195 @@
|
||||
|
||||
MSDS - NAPHTHALENE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: NAPHTHALENE
|
||||
FORMULA: C10H8
|
||||
FORMULA WT: 128.18
|
||||
CAS NO.: 00091-20-3
|
||||
NIOSH/RTECS NO.: QJ0525000
|
||||
COMMON SYNONYMS: NAPHTHALIN, NAPHTHENE, CAMPHOR TAR, MOTH BALLS
|
||||
PRODUCT CODES: 2718
|
||||
EFFECTIVE: 09/03/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 1 SLIGHT
|
||||
FLAMMABILITY - 2 MODERATE
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 1 SLIGHT
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
CAUTION
|
||||
COMBUSTIBLE
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME.
|
||||
KEEP IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING. IN CASE
|
||||
OF FIRE, SOAK WITH WATER. IN CASE OF SPILL, SWEEP UP AND REMOVE. FLUSH SPILL
|
||||
AREA WITH WATER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NAPHTHALENE 90-100 91-20-3
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: 218 C ( 424 F) VAPOR PRESSURE(MM HG): 0.05
|
||||
|
||||
MELTING POINT: 80 C ( 176 F) VAPOR DENSITY(AIR=1): 4.42
|
||||
|
||||
SPECIFIC GRAVITY: 1.14 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE CRYSTALLINE VOLATILE SOLID WITH THE ODOR OF
|
||||
MOTH BALLS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP 88 C ( 190 F) NFPA 704M RATING: 2-2-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 5.9 % LOWER - 0.9 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
(POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE.
|
||||
MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
|
||||
USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE.
|
||||
CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 50 MG/M3 ( 10 PPM)
|
||||
|
||||
SHORT-TERM EXPOSURE LIMIT (STEL): 75 MG/M3 ( 15 PPM)
|
||||
|
||||
PERMISSIBLE EXPOSURE LIMIT (PEL): 50 MG/M3 ( 10 PPM)
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 1780
|
||||
LD50 (SCU-MOUSE)(MG/KG) - 969
|
||||
LD50 (IV-MOUSE) (MG/KG) - 100
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION.
|
||||
INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
|
||||
GASTROINTESTINAL IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
EYES, SKIN, BLOOD, LIVER, KIDNEYS, CENTRAL NERVOUS SYSTEM
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INHALATION, INGESTION, ABSORPTION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, DO NOT INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
|
||||
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
|
||||
SMOKING, OR FLAMES IN AREA. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
|
||||
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA
|
||||
WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: U165 (TOXIC WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET
|
||||
TLV REQUIREMENTS.
|
||||
|
||||
RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
|
||||
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP
|
||||
TO 500 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH
|
||||
ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE
|
||||
THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS
|
||||
IS RECOMMENDED.
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, RUBBER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA
|
||||
AWAY FROM HEAT, SPARKS, OR FLAME.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME NAPHTHALENE (AIR AND WATER ONLY)
|
||||
HAZARD CLASS ORM-A
|
||||
UN/NA UN1334
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 100 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME NAPHTHALENE, CRUDE OR REFINED
|
||||
HAZARD CLASS 4.1
|
||||
UN/NA UN1334
|
||||
LABELS FLAMMABLE SOLID
|
||||
|
||||
148
textfiles.com/science/CHEMICALS/nitro_laquer.txt
Normal file
148
textfiles.com/science/CHEMICALS/nitro_laquer.txt
Normal file
@@ -0,0 +1,148 @@
|
||||
KOPPERS COMPANY -- CELLULOSE NITRATE-GLOSS LACQUER - LACQUER.CELLULOSE NITRATE,GLOSS FOR AIRCRAF USE
|
||||
MATERIAL SAFETY DATA SHEET
|
||||
FSC: 8010
|
||||
NIIN: 005985933
|
||||
Manufacturer's CAGE: 80592
|
||||
Part No. Indicator: A
|
||||
Part Number/Trade Name: CELLULOSE NITRATE-GLOSS LACQUER
|
||||
===========================================================================
|
||||
General Information
|
||||
===========================================================================
|
||||
Item Name: LACQUER.CELLULOSE NITRATE,GLOSS FOR AIRCRAF USE
|
||||
Company's Name: KOPPERS COMPANY,INC.
|
||||
Company's Street: 3000 KOPPERS BLDG
|
||||
Company's City: PITTSBURGH
|
||||
Company's State: PA
|
||||
Company's Country: US
|
||||
Company's Zip Code: 15219-1818
|
||||
Record No. For Safety Entry: 007
|
||||
Tot Safety Entries This Stk#: 007
|
||||
Date MSDS Prepared: 01JAN85
|
||||
Safety Data Review Date: 26APR82
|
||||
Supply Item Manager: GSA
|
||||
MSDS Serial Number: BFHLG
|
||||
Specification Number: TT-L-32
|
||||
Hazard Characteristic Code: F1
|
||||
Unit Of Issue: GL
|
||||
Unit Of Issue Container Qty: 1 GALLON
|
||||
Type Of Container: CAN
|
||||
===========================================================================
|
||||
Ingredients/Identity Information
|
||||
===========================================================================
|
||||
Proprietary: NO
|
||||
Ingredient: ISOPROPYL ALCOHOL (SARA III)
|
||||
Ingredient Sequence Number: 01
|
||||
NIOSH (RTECS) Number: NT8050000
|
||||
CAS Number: 67-63-0
|
||||
OSHA PEL: 400 PPM/500 STEL
|
||||
ACGIH TLV: 400 PPM/500STEL;9192
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: METHYL ISOBUTYL CARBINOL
|
||||
Ingredient Sequence Number: 02
|
||||
NIOSH (RTECS) Number: PO5776000
|
||||
ACGIH TLV: 25PPM
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: N-BUTYL ACETATE (SARA III)
|
||||
Ingredient Sequence Number: 03
|
||||
NIOSH (RTECS) Number: AF7350000
|
||||
CAS Number: 123-86-4
|
||||
OSHA PEL: 150 PPM
|
||||
ACGIH TLV: 150 PPM/200STEL;9394
|
||||
Other Recommended Limit: NONE RECOMMENDED
|
||||
-------------------------------------
|
||||
Proprietary: NO
|
||||
Ingredient: BUTYL CELLOSOLVE
|
||||
Ingredient Sequence Number: 04
|
||||
NIOSH (RTECS) Number: EP3600000
|
||||
===========================================================================
|
||||
Physical/Chemical Characteristics
|
||||
===========================================================================
|
||||
Appearance And Odor: BLUE VISCOUS LIQUID WITH TYPICAL SOLVENT ODOR.
|
||||
Vapor Density (Air=1): HEAV
|
||||
Specific Gravity: 7.8 LB
|
||||
Evaporation Rate And Ref: N BUTYL ACET FASTE
|
||||
===========================================================================
|
||||
Fire and Explosion Hazard Data
|
||||
===========================================================================
|
||||
Flash Point: 23F TCC -5.0C
|
||||
Extinguishing Media: FOAM,DRY CHEMICAL,WATER SPRAY FOG OR CO2.
|
||||
Special Fire Fighting Proc: USE AIR SUPPLIED EQUIPMENT FOR ENCLOSURED
|
||||
AREAS.COOL EXPOSED
|
||||
Unusual Fire And Expl Hazrds: KEEP AWAY FROM HEAT,SPARKS AND FLAME.
|
||||
===========================================================================
|
||||
Reactivity Data
|
||||
===========================================================================
|
||||
Stability: YES
|
||||
Hazardous Poly Occur: NO
|
||||
===========================================================================
|
||||
Health Hazard Data
|
||||
===========================================================================
|
||||
Signs/Symptoms Of Overexp: SYSTEMIC TOXIC EFFECTS MAY ALSO RESULT FROM
|
||||
SKIN ABSORPTION:IRRITATION TO EYES,NOSE AND THROAT NEAR.
|
||||
Emergency/First Aid Proc: IF INHALED,MOVE TO FRESH AIR.IF NOT
|
||||
BREATHING,GIVE ARTIFICIAL RESPIRATION,PREFERABLY MOUTH TO MOUTH.CALL A
|
||||
PHYSICIAN.IN CASE OF SKIN CONTACT,WASH THOROUGHLY WITH SOAP AND WATER;FOR
|
||||
EYES FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR 15 MIN. AND CONTACT
|
||||
===========================================================================
|
||||
Precautions for Safe Handling and Use
|
||||
===========================================================================
|
||||
Steps If Matl Released/Spill: REMOVE ALL SOURCES OF IGNITION (FLAME,
|
||||
ELECTRICAL,STATIC OR FRICTION SPARKS; HOT SURFACES,ETC.). AVOID BREATHING
|
||||
VAPORS.VENTILATE AREA. CONTAIN AND SCOOP UP SPILL WITH NON-SPARKING TOOLS,
|
||||
RAGS,ETC.USE INERT ABSORBENT MATERIALS ON SMALL SPILLS OR ON RE
|
||||
Waste Disposal Method: DISPOSE IN ACCORDANCE WITH LOCAL APPLICABLE
|
||||
REGULATIONS.
|
||||
Precautions-Handling/Storing: KEEP CONTAINERS CLOSED AND UPRIGHT TO
|
||||
PREVENT LEAKAGE.AVOID FLAMES, WELDING,SMOKING,SPARKS,OPEN LIGHTS,ETC.AVOID
|
||||
BREATHING OF VAPORS OR SPRAY MIST.AVO
|
||||
Other Precautions: MAINTAIN GOOD PERSONAL HYGIENE.DO NOT USE IN CONFINED
|
||||
AREAS,TANK OR PIT WITHOUT ADEQUATE VENTILATION.
|
||||
===========================================================================
|
||||
Control Measures
|
||||
===========================================================================
|
||||
Respiratory Protection: ORGANIC VAPOR CANISTER WHERE OXYGEN CONTENT IS
|
||||
ADEQUATE AND VAPOR CO
|
||||
Ventilation: LOCAL EXHAUST
|
||||
Protective Gloves: RUBBER GLOVES
|
||||
Eye Protection: GOGGLES
|
||||
Suppl. Safety & Health Data: METHYL ISOBUTYL KETONE PO6125000;TLV 50 PPM;
|
||||
BUTYL ALCOHOL EO2000000;TLV 50PPM; VM AND P NAPTHA SE7555000; TLV 300PPM
|
||||
===========================================================================
|
||||
Transportation Data
|
||||
===========================================================================
|
||||
Trans Data Review Date: 82116
|
||||
DOT PSN Code: LFD
|
||||
DOT Proper Shipping Name: PAINT
|
||||
DOT Class: 3
|
||||
DOT ID Number: UN1263
|
||||
DOT Pack Group: II
|
||||
DOT Label: FLAMMABLE LIQUID
|
||||
IMO PSN Code: LCP
|
||||
IMO Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL
|
||||
IMO Regulations Page Number: 3268
|
||||
IMO UN Number: 1263
|
||||
IMO UN Class: 3.2
|
||||
IMO Subsidiary Risk Label: -
|
||||
===========================================================================
|
||||
Disposal Data
|
||||
===========================================================================
|
||||
===========================================================================
|
||||
Label Data
|
||||
===========================================================================
|
||||
Label Required: YES
|
||||
Label Status: F
|
||||
Special Hazard Precautions: MAY BE POISONOUS IF INHALED OR ABSORBED
|
||||
THROUGH SKIN. VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. CONTACT MAY
|
||||
IRRITATE OR BURN SKIN AND EYES. FIRE MAY PRODUCE IRRITATING OR POISONOUS
|
||||
GASES. RUNOFF FROM FIRE CONTROL OR DILUTION WATER MAY CAUSE POLLUTION.
|
||||
Label Name: KOPPERS CO INC
|
||||
Label Street: 3000 KOPPERS BLDG
|
||||
Label City: PITTSBURGH
|
||||
Label State: PA
|
||||
Label Zip Code: 15219-1818
|
||||
Label Country: US
|
||||
=======================================================================
|
||||
URL for this msds http://hazard.com. If you wish to change, add to, or
|
||||
delete information in this archive please sent updates to dan@hazard.com.
|
||||
113
textfiles.com/science/CHEMICALS/oxalic_acid.txt
Normal file
113
textfiles.com/science/CHEMICALS/oxalic_acid.txt
Normal file
@@ -0,0 +1,113 @@
|
||||
|
||||
|
||||
|
||||
|
||||
M A T E R I A L S A F E T Y D A T A S H E E T
|
||||
OXALIC ACID, CRYSTALS
|
||||
|
||||
================================================================================
|
||||
SECTION I - Product Identification
|
||||
================================================================================
|
||||
PRODUCT NAME: OXALIC ACID, CRYSTALS
|
||||
FORMULA: HO2CCO2H.2H2O
|
||||
FORMULA WT: 126.07
|
||||
CAS NO.:
|
||||
COMMON SYNONYMS: ETHANEDIOIC ACID
|
||||
|
||||
================================================================================
|
||||
Precautionary Labeling
|
||||
================================================================================
|
||||
HEALTH - 2
|
||||
FLAMMABILITY - 1
|
||||
REACTIVITY - 0
|
||||
================================================================================
|
||||
SECTION II - Hazardous Components
|
||||
================================================================================
|
||||
N/A
|
||||
================================================================================
|
||||
SECTION III - Physical Data
|
||||
================================================================================
|
||||
BOILING POINT: N/A VAPOR PRESSURE @ 20C (MM HG): N/A
|
||||
MELTING POINT: 101C DEC VAPOR DENSITY (AIR=1): N/A
|
||||
SPECIFIC GRAVITY: 1.65 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
SOLUBILITY(H2O): 12 PERCENT VOLATILES BY VOLUME: N/A
|
||||
APPEARANCE & ODOR: WHITE CRYSTALS
|
||||
================================================================================
|
||||
SECTION IV - Fire and Explosion Hazard Data
|
||||
================================================================================
|
||||
FLASH POINT: NONE
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
DRY CHEMICAL, "ALCOHOL" FOAM, CO2 (WATER MAY CAUSE FROTHING)
|
||||
WATER SPRAY TO COOL EXPOSED CONTAINERS, DISPERSE VAPORS
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND GOGGLES
|
||||
UNUSUAL FIRE AND EXPLOSION HAZARDS
|
||||
EMITS HIGHLY TOXIC, IRRITATING FUMES IN FIRE CONDITIONS
|
||||
================================================================================
|
||||
SECTION V - Health Hazard Data
|
||||
================================================================================
|
||||
THRESHOLD LIMIT VALUE (TLV/TWA): 1 MG/M3
|
||||
TOXICITY: ORL-HMN LDLO: 71 MG/KG
|
||||
ORL-RAT LD50: 375 MG/KG
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
HIGHLY TOXIC: CAN BE FATAL IF INGESTED OR INHALED. SEVERE BURNS ON
|
||||
CONTACT. DUST IS IRRITATING TO MUCOUS MEMBRANES AND EYES.
|
||||
INHALATION CAN CAUSE SERIOUS CORROSION OF MOUTH, THROAT, STOMACH.
|
||||
INGESTION CAUSES NAUSEA, SHOCK CONVULSIONS AND DEATH AT 5 GM
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
SKIN: REMOVE CONTAMINATED CLOTHING AT ONCE (AND LAUNDER BEFORE REUSE)
|
||||
WASH SKIN WITH SOAP AND WATER
|
||||
EYES: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES
|
||||
INHALATION: REMOVE TO FRESH AIR
|
||||
INGESTION: DO NOT INDUCE VOMITING; GIVE DILUTE MILK OF MAGNESIA, LIME
|
||||
WATER, OR MILK IF CONSCIOUS
|
||||
GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE
|
||||
================================================================================
|
||||
SECTION VI - Reactivity Data
|
||||
================================================================================
|
||||
STABILITY: STABLE
|
||||
CONDITIONS TO AVOID: EXTREME HEAT - SUBMIMES AND DECOMPOSES ABOVE MELTING
|
||||
POINT EMITTING TOXIC FUMES
|
||||
INCOMPATIBILES: OXIDIZERS, ALKALIES, SILVER, CHLORITES AND
|
||||
HYPOCHLORITES, FURFURYL ALCOHOL
|
||||
DECOMPOSITION PRODUCTS: TOXIC FUMES INCLUDING COX AND FORMIC ACID
|
||||
================================================================================
|
||||
SECTION VII - Spill and Disposal Procedures
|
||||
================================================================================
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
TAKE UP & CONTAINERIZE FOR DISPOSAL
|
||||
================================================================================
|
||||
SECTION VIII - Protective Equipment
|
||||
================================================================================
|
||||
PROVIDE ADEQUATE GENERAL MECHANICAL AND LOCAL EXHAUST VENTILATION
|
||||
PROTECT EYES AND SKIN WITH SAFETY GOGGLES AND GLOVES
|
||||
WEAR CARTRIDGE RESPIRATOR, APRON AND LONG SLEEVES
|
||||
USE ONLY WITH ADEQUATE VENTILATION AND DO NOT INHALE DUST OR VAPORS
|
||||
USE IN FUME HOOD
|
||||
================================================================================
|
||||
SECTION IX - Storage and Handling Precautions
|
||||
================================================================================
|
||||
KEEP CONTAINER TIGHTLY CLOSED.
|
||||
PROTECT AGAINST PHYSICAL DAMAGE.
|
||||
STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM OXIDIZERS
|
||||
WASH GLOVES THOROUGHLY BEFORE REMOVING
|
||||
WASH FACE AND HANDS AFTER FILLING CLEAN AREA THOROUGHLY AFTER USE
|
||||
================================================================================
|
||||
SECTION X - Transportation Data and Additional Information
|
||||
================================================================================
|
||||
THE ABOVE NFPA CODE IS APPLICABLE TO FIRE SITUATION ONLY
|
||||
|
||||
--------------------------------------------------------------------------------
|
||||
(TM) and (R) : Registered Trademarks
|
||||
N/A = Not Applicable OR Not Available
|
||||
The information published in this Material Safety Data Sheet has been compiled
|
||||
from our experience and data presented in various technical publications. It is
|
||||
the user's responsibility to determine the suitability of this information for
|
||||
adoption of necessary safety precautions. We reserve the right to revise
|
||||
Material Safety Data Sheets periodically as new information becomes available.
|
||||
Copyright by Manufacturer
|
||||
LICENSE GRANTED TO MAKE UNLIMITED COPIES FOR INTERNAL USE ONLY
|
||||
by OREGON STATE UNIVERSITY
|
||||
.
|
||||
167
textfiles.com/science/CHEMICALS/paraffin_oil.txt
Normal file
167
textfiles.com/science/CHEMICALS/paraffin_oil.txt
Normal file
@@ -0,0 +1,167 @@
|
||||
|
||||
MSDS - PARAFFIN OIL
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: PARAFFIN OIL
|
||||
FORMULA:
|
||||
FORMULA WT: .00
|
||||
CAS NO.: 08012-95-1
|
||||
NIOSH/RTECS NO.: PY8030000
|
||||
COMMON SYNONYMS: MINERAL OIL
|
||||
PRODUCT CODES: S894,9388
|
||||
EFFECTIVE: 05/06/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 0 NONE
|
||||
FLAMMABILITY - 1 SLIGHT
|
||||
REACTIVITY - 0 NONE
|
||||
CONTACT - 0 NONE
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
SAFETY GLASSES; LAB COAT
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER
|
||||
HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
NOT APPLICABLE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A
|
||||
|
||||
MELTING POINT: -18 C ( 0 F) VAPOR DENSITY(AIR=1): N/A
|
||||
|
||||
SPECIFIC GRAVITY: 0.88 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: 0
|
||||
|
||||
APPEARANCE & ODOR: WATER WHITE VISCOUS LIQUID WITH NO ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP 215 C ( 420 F) NFPA 704M RATING: 0-1-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
PROLONGED CONTACT MAY CAUSE SKIN IRRITATION.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
NONE INDICATED
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE
|
||||
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION.
|
||||
INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED
|
||||
PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
|
||||
EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
|
||||
MINUTES. GET MEDICAL ATTENTION.
|
||||
SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST
|
||||
15 MINUTES.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, CHLORINE
|
||||
|
||||
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SUITABLE PROTECTIVE CLOTHING. TAKE UP WITH SAND OR OTHER NONCOM-
|
||||
BUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL.
|
||||
FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP VAPOR AND MIST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE
|
||||
RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
DO NOT STORE NEAR OXIDIZING MATERIALS.
|
||||
KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
|
||||
AREA.
|
||||
PRODUCT MAY SOLIDIFY AT ROOM TEMPERATURE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED)
|
||||
|
||||
205
textfiles.com/science/CHEMICALS/paraform.txt
Normal file
205
textfiles.com/science/CHEMICALS/paraform.txt
Normal file
@@ -0,0 +1,205 @@
|
||||
|
||||
MSDS - PARAFORMALDEHYDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
1 - PRODUCT IDENTIFICATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
PRODUCT NAME: PARAFORMALDEHYDE
|
||||
FORMULA: (CH2O)N
|
||||
FORMULA WT: .00
|
||||
CAS NO.: 30525-89-4
|
||||
NIOSH/RTECS NO.: RV0540000
|
||||
COMMON SYNONYMS: PARAFORM; POLYOXYMETHYLENE
|
||||
PRODUCT CODES: S898
|
||||
EFFECTIVE: 09/08/86
|
||||
REVISION #02
|
||||
|
||||
PRECAUTIONARY LABELLING
|
||||
BAKER SAF-T-DATA(TM) SYSTEM
|
||||
|
||||
HEALTH - 3 SEVERE (CANCER CAUSING)
|
||||
FLAMMABILITY - 2 MODERATE
|
||||
REACTIVITY - 2 MODERATE
|
||||
CONTACT - 3 SEVERE (CORROSIVE)
|
||||
HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD).
|
||||
|
||||
LABORATORY PROTECTIVE EQUIPMENT
|
||||
|
||||
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
|
||||
|
||||
PRECAUTIONARY LABEL STATEMENTS
|
||||
|
||||
WARNING
|
||||
CAUSES EYE BURNS AND MAY IRRITATE SKIN.
|
||||
DUST MAY FORM FLAMMABLE OR EXPLOSIVE MIXTURE WITH AIR.
|
||||
NOTE: REPORTED AS CAUSING CANCER IN LABORATORY ANIMALS. EXERCISE DUE CARE.
|
||||
KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
|
||||
AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH
|
||||
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE,
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE.
|
||||
FLUSH SPILL AREA WITH WATER SPRAY.
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
2 - HAZARDOUS COMPONENTS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
COMPONENT % CAS NO.
|
||||
|
||||
PARAFORMALDEHYDE 90-100 30525-89-4
|
||||
FORMALDEHYDE >0.10 50-00-0
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
3 - PHYSICAL DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
BOILING POINT: N/A VAPOR PRESSURE(MM HG): <2
|
||||
|
||||
MELTING POINT: 120 C ( 248 F) VAPOR DENSITY(AIR=1): 1.03
|
||||
|
||||
SPECIFIC GRAVITY: 1.40 EVAPORATION RATE: N/A
|
||||
(H2O=1) (BUTYL ACETATE=1)
|
||||
|
||||
SOLUBILITY(H2O): APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME: N/A
|
||||
|
||||
APPEARANCE & ODOR: WHITE POWDER WITH FORMALDEHYDE-LIKE ODOR.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
4 - FIRE AND EXPLOSION HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
FLASH POINT (CLOSED CUP 70 C ( 158 F) NFPA 704M RATING: 2-2-0
|
||||
|
||||
FLAMMABLE LIMITS: UPPER - 73.0 % LOWER - 7.0 %
|
||||
|
||||
FIRE EXTINGUISHING MEDIA
|
||||
USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
|
||||
(WATER MAY BE INEFFECTIVE.)
|
||||
|
||||
SPECIAL FIRE-FIGHTING PROCEDURES
|
||||
FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED
|
||||
BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
|
||||
MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER
|
||||
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
|
||||
|
||||
UNUSUAL FIRE & EXPLOSION HAZARDS
|
||||
CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED.
|
||||
|
||||
TOXIC GASES PRODUCED
|
||||
FORMALDEHYDE, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
5 - HEALTH HAZARD DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SOME EXPERIMENTS WITH TEST ANIMALS INDICATED THAT THIS SUBSTANCE MAY BE
|
||||
ANTICIPATED TO BE A CARCINOGEN.
|
||||
|
||||
TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 800
|
||||
|
||||
CARCINOGENICITY: NTP: YES IARC: NO Z LIST: NO OSHA REG: NO
|
||||
|
||||
EFFECTS OF OVEREXPOSURE
|
||||
DUST MAY BE IRRITATING TO EYES, NOSE, THROAT, OR LUNGS.
|
||||
DUST MAY CAUSE HEADACHE, COUGHING, DIZZINESS OR DIFFICULT BREATHING.
|
||||
CONTACT WITH SKIN MAY CAUSE IRRITATION.
|
||||
CONTACT WITH EYES MAY CAUSE BURNS.
|
||||
INGESTION MAY CAUSE NAUSEA AND VOMITING.
|
||||
INGESTION MAY CAUSE SEVERE BURNING OF MOUTH AND STOMACH.
|
||||
|
||||
TARGET ORGANS
|
||||
NONE IDENTIFIED
|
||||
|
||||
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
|
||||
NONE IDENTIFIED
|
||||
|
||||
ROUTES OF ENTRY
|
||||
INGESTION, INHALATION, EYE CONTACT, SKIN CONTACT
|
||||
|
||||
EMERGENCY AND FIRST AID PROCEDURES
|
||||
CALL A PHYSICIAN.
|
||||
IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING.
|
||||
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
|
||||
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
|
||||
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR
|
||||
AT LEAST 15 MINUTES.
|
||||
|
||||
TOXICITY TEST RESULTS AND SAFETY AND HEALTH EFFECTS ARE LISTED FOR
|
||||
FORMALDEHYDE.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
6 - REACTIVITY DATA
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
|
||||
|
||||
CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION
|
||||
|
||||
INCOMPATIBLES: STRONG OXIDIZING AGENTS, ORGANIC ACIDS, OXIDES,
|
||||
ALKALIES, STRONG ACIDS, STRONG BASES, AMINES
|
||||
|
||||
DECOMPOSITION PRODUCTS: FORMALDEHYDE, CARBON MONOXIDE, CARBON DIOXIDE
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
7 - SPILL AND DISPOSAL PROCEDURES
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE
|
||||
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
|
||||
SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING, OR FLAMES IN AREA. WITH
|
||||
CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER;
|
||||
REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER.
|
||||
|
||||
DISPOSAL PROCEDURE
|
||||
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
|
||||
ENVIRONMENTAL REGULATIONS.
|
||||
|
||||
EPA HAZARDOUS WASTE NUMBER: D002 (CORROSIVE WASTE)
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
8 - PROTECTIVE EQUIPMENT
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION
|
||||
TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE.
|
||||
|
||||
RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION
|
||||
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS
|
||||
HIGH, A DUST/MIST RESPIRATOR IS RECOMMENDED.
|
||||
IF CONCENTRATION EXCEEDS CAPACITY OF RESPIRATOR,
|
||||
A SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
|
||||
|
||||
EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, NEOPRENE GLOVES
|
||||
ARE RECOMMENDED.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
9 - STORAGE AND HANDLING PRECAUTIONS
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE)
|
||||
|
||||
SPECIAL PRECAUTIONS
|
||||
KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED,
|
||||
FLAMMABLE LIQUID STORAGE AREA OR CABINET.
|
||||
|
||||
------------------------------------------------------------------------------
|
||||
10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION
|
||||
------------------------------------------------------------------------------
|
||||
|
||||
DOMESTIC (D.O.T.)
|
||||
|
||||
PROPER SHIPPING NAME PARAFORMALDEHYDE (AIR AND WATER ONLY)
|
||||
HAZARD CLASS ORM-A
|
||||
UN/NA UN2213
|
||||
LABELS NONE
|
||||
REPORTABLE QUANTITY 1000 LBS.
|
||||
|
||||
INTERNATIONAL (I.M.O.)
|
||||
|
||||
PROPER SHIPPING NAME PARAFORMALDEHYDE
|
||||
HAZARD CLASS 4.1
|
||||
UN/NA UN2213
|
||||
LABELS NO LABEL REQUIRED PACKAGE TO BE MARKED: CLASS 4.1
|
||||
|
||||
Some files were not shown because too many files have changed in this diff Show More
Reference in New Issue
Block a user